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HomeMy WebLinkAboutDymon_Liquid_Alive_Enzyme_Producing_Bacteria_Bulk_US_EnglishSAFETY DATA SHEET 1. Identification Liquid Alive® Enzyme Producing BacteriaProduct identifier Other means of identification 23301, 23305, 23332, 23335, 23355, 23394, 23395Part Number EnzymesRecommended use None known.Recommended restrictions Manufacturer/Importer/Supplier/Distributor information Manufacturer ITW Pro BrandsCompany name 805 E. Old 56 HighwayAddress Olathe, KS 66061 (U.S.A.)Country Tel: +1 800-443-9536 1-800-535-5053 (Infotrac)In Case of Emergency 2. Hazard(s) identification Not classified.Physical hazards Category 2ASerious eye damage/eye irritationHealth hazards Category 1Sensitization, skin Not classified.Environmental hazards Not classified.OSHA defined hazards Label elements Signal word Warning Hazard statement Causes serious eye irritation. May cause an allergic skin reaction. Precautionary statement Prevention Avoid breathing mist or vapor. Wash thoroughly after handling. Contaminated work clothing must not be allowed out of the workplace. Wear eye protection/face protection. Wear protective gloves. Response If on skin: Wash with plenty of water. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Wash contaminated clothing before reuse. Storage Store away from incompatible materials. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s) not otherwise classified (HNOC) None known. Supplemental information None. 3. Composition/information on ingredients Mixtures CAS number %Chemical name Common name and synonyms 68081-81-2Benzenesulfonic Acid, C10-16-alkyl Derivatives, Sodium Salts 1 - 5 689374-66-6Alcohols, C6-12, Ethoxylated Propoxylated 1 - 2 104-55-2Cinnamic Aldehyde 0.1 - 0.2 1 / 7 Material name: Liquid Alive® Enzyme Producing Bacteria 23301, 23305, 23332, 23335, 23355, 23394, 23395 Version #: 01 Issue date: 01-26-2018 SDS US CAS number %Chemical name Common name and synonyms 111-76-2Ethylene Glycol Monobutyl Ether 0.1 - 0.2 64-02-8Tetrasodium EDTA 0.1 - 0.2 4. First-aid measures Move to fresh air. Call a physician if symptoms develop or persist.Inhalation Remove contaminated clothing immediately and wash skin with soap and water. In case of eczema or other skin disorders: Seek medical attention and take along these instructions. Skin contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Eye contact Rinse mouth. Get medical attention if symptoms occur.Ingestion Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause an allergic skin reaction. Dermatitis. Rash. Most important symptoms/effects, acute and delayed Provide general supportive measures and treat symptomatically. Keep victim under observation. Symptoms may be delayed. Indication of immediate medical attention and special treatment needed Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves. Wash contaminated clothing before reuse. General information 5. Fire-fighting measures Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media Do not use water jet as an extinguisher, as this will spread the fire.Unsuitable extinguishing media During fire, gases hazardous to health may be formed.Specific hazards arising from the chemical Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment and precautions for firefighters Move containers from fire area if you can do so without risk.Fire fighting equipment/instructions Use standard firefighting procedures and consider the hazards of other involved materials.Specific methods No unusual fire or explosion hazards noted.General fire hazards 6. Accidental release measures Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear appropriate protective equipment and clothing during clean-up. Avoid breathing mist or vapor. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation. Local authorities should be advised if significant spillages cannot be contained. For personal protection, see section 8 of the SDS. Personal precautions, protective equipment and emergency procedures Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is possible. Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery, flush area with water. Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to remove residual contamination. Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS. Methods and materials for containment and cleaning up Avoid discharge into drains, water courses or onto the ground.Environmental precautions 7. Handling and storage Avoid breathing mist or vapor. Avoid contact with eyes, skin, and clothing. Avoid prolonged exposure. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Precautions for safe handling Store in original tightly closed container. Store away from incompatible materials (see Section 10 of the SDS). Conditions for safe storage, including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time, the other constituents have no known exposure limits. 2 / 7 Material name: Liquid Alive® Enzyme Producing Bacteria 23301, 23305, 23332, 23335, 23355, 23394, 23395 Version #: 01 Issue date: 01-26-2018 SDS US US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) ValueComponents Type PEL 240 mg/m3Ethylene glycol monobutyl ether (CAS 111-76-2) 50 ppm US. ACGIH Threshold Limit Values ValueComponents Type TWA 20 ppmEthylene glycol monobutyl ether (CAS 111-76-2) US. NIOSH: Pocket Guide to Chemical Hazards ValueComponents Type TWA 24 mg/m3Ethylene glycol monobutyl ether (CAS 111-76-2) 5 ppm Biological limit values ACGIH Biological Exposure Indices ValueComponents Determinant Specimen Sampling Time 200 mg/g Butoxyacetic acid (BAA), with hydrolysis Creatinine in urine *Ethylene glycol monobutyl ether (CAS 111-76-2) * - For sampling details, please see the source document. Exposure guidelines US - California OELs: Skin designation Ethylene Glycol Monobutyl Ether (CAS 111-76-2) Can be absorbed through the skin. US - Minnesota Haz Subs: Skin designation applies Ethylene Glycol Monobutyl Ether (CAS 111-76-2) Skin designation applies. US - Tennessee OELs: Skin designation Ethylene Glycol Monobutyl Ether (CAS 111-76-2) Can be absorbed through the skin. US NIOSH Pocket Guide to Chemical Hazards: Skin designation Ethylene Glycol Monobutyl Ether (CAS 111-76-2) Can be absorbed through the skin. US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) Ethylene Glycol Monobutyl Ether (CAS 111-76-2) Can be absorbed through the skin. Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Provide eyewash station. Appropriate engineering controls Individual protection measures, such as personal protective equipment Wear safety glasses with side shields (or goggles).Eye/face protection Skin protection Wear appropriate chemical resistant gloves.Hand protection Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended.Other In case of insufficient ventilation, wear suitable respiratory equipment.Respiratory protection Wear appropriate thermal protective clothing, when necessary.Thermal hazards Always observe good personal hygiene measures, such as washing after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Contaminated work clothing should not be allowed out of the workplace. General hygiene considerations 9. Physical and chemical properties Appearance Liquid.Physical state Liquid.Form White.Color Neutra GammaOdor 3 / 7 Material name: Liquid Alive® Enzyme Producing Bacteria 23301, 23305, 23332, 23335, 23355, 23394, 23395 Version #: 01 Issue date: 01-26-2018 SDS US Odor threshold Not available. pH 7.7 Melting point/freezing point Not available. Initial boiling point and boiling range 212 °F (100 °C) Flash point Not available. Evaporation rate Not available. Not applicable.Flammability (solid, gas) Upper/lower flammability or explosive limits Flammability limit - lower (%) Not available. Flammability limit - upper (%) Not available. Explosive limit - lower (%)Not available. Explosive limit - upper (%)Not available. Vapor pressure Not available. Vapor density > 1 (air = 1) Relative density Not available. Solubility(ies) Solubility (water)Completely soluble Partition coefficient (n-octanol/water) Not available. Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity Not available. Other information Not explosive.Explosive properties Not oxidizing.Oxidizing properties Specific gravity 1.002 10. Stability and reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity Material is stable under normal conditions.Chemical stability No dangerous reaction known under conditions of normal use.Possibility of hazardous reactions Contact with incompatible materials.Conditions to avoid Strong oxidizing agents.Incompatible materials Carbon oxides.Hazardous decomposition products 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact May cause an allergic skin reaction. Eye contact Causes serious eye irritation. Ingestion Expected to be a low ingestion hazard. Symptoms related to the physical, chemical and toxicological characteristics Severe eye irritation. Symptoms may include stinging, tearing, redness, swelling, and blurred vision. May cause an allergic skin reaction. Dermatitis. Rash. Information on toxicological effects Acute toxicity Not known. 4 / 7 Material name: Liquid Alive® Enzyme Producing Bacteria 23301, 23305, 23332, 23335, 23355, 23394, 23395 Version #: 01 Issue date: 01-26-2018 SDS US Test ResultsComponents Species Cinnamic Aldehyde (CAS 104-55-2) Dermal Acute LD50 Rabbit 620 mg/kg Ethylene Glycol Monobutyl Ether (CAS 111-76-2) Dermal Acute LD50 Rabbit 400 mg/kg Oral LD50 Rat 530 - 2800 mg/kg Tetrasodium EDTA (CAS 64-02-8) Oral Acute LD50 Rat 1658 mg/kg Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation Causes serious eye irritation.Serious eye damage/eye irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. May cause an allergic skin reaction.Skin sensitization No data available to indicate product or any components present at greater than 0.1% are mutagenic or genotoxic. Germ cell mutagenicity Carcinogenicity Not classifiable as to carcinogenicity to humans. ACGIH Carcinogens Ethylene Glycol Monobutyl Ether (CAS 111-76-2) A3 Confirmed animal carcinogen with unknown relevance to humans. IARC Monographs. Overall Evaluation of Carcinogenicity Ethylene Glycol Monobutyl Ether (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. US. National Toxicology Program (NTP) Report on Carcinogens Not listed. This product is not expected to cause reproductive or developmental effects.Reproductive toxicity Specific target organ toxicity - single exposure Not classified. Specific target organ toxicity - repeated exposure Not classified. Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. 12. Ecological information The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Ecotoxicity Components Test ResultsSpecies Ethylene Glycol Monobutyl Ether (CAS 111-76-2) Aquatic LC50Fish 1250 mg/l, 96 hoursInland silverside (Menidia beryllina) Tetrasodium EDTA (CAS 64-02-8) Aquatic LC50Fish 472 - 500 mg/l, 96 hoursBluegill (Lepomis macrochirus) No data is available on the degradability of any ingredients in the mixture. Persistence and degradability Bioaccumulative potential 5 / 7 Material name: Liquid Alive® Enzyme Producing Bacteria 23301, 23305, 23332, 23335, 23355, 23394, 23395 Version #: 01 Issue date: 01-26-2018 SDS US Partition coefficient n-octanol / water (log Kow) Ethylene Glycol Monobutyl Ether 0.83 No data available.Mobility in soil Other adverse effects None known. 13. Disposal considerations Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of contents/container in accordance with local/regional/national/international regulations. Disposal instructions Dispose in accordance with all applicable regulations.Local disposal regulations The waste code should be assigned in discussion between the user, the producer and the waste disposal company. Hazardous waste code Dispose of in accordance with local regulations. Empty containers or liners may retain some product residues. This material and its container must be disposed of in a safe manner (see: Disposal instructions). Waste from residues / unused products Since emptied containers may retain product residue, follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Contaminated packaging 14. Transport information DOT Not regulated as dangerous goods. IATA Not regulated as dangerous goods. IMDG Not regulated as dangerous goods. Not established.Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. US federal regulations TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D) Not regulated. CERCLA Hazardous Substance List (40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1052) Not regulated. SARA 302 Extremely hazardous substance Superfund Amendments and Reauthorization Act of 1986 (SARA) Not listed. YesSARA 311/312 Hazardous chemical Serious eye damage or eye irritation Respiratory or skin sensitization Classified hazard categories SARA 313 (TRI reporting) Not regulated. Other federal regulations Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List Not regulated. Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130) Not regulated. Not regulated.Safe Drinking Water Act (SDWA) 6 / 7 Material name: Liquid Alive® Enzyme Producing Bacteria 23301, 23305, 23332, 23335, 23355, 23394, 23395 Version #: 01 Issue date: 01-26-2018 SDS US FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace Cinnamic Aldehyde (CAS 104-55-2) Low priority US state regulations US. New Jersey Worker and Community Right-to-Know Act Ethylene Glycol Monobutyl Ether (CAS 111-76-2) California Proposition 65 California Safe Drinking Water and Toxic Enforcement Act of 2016 (Proposition 65): This material is not known to contain any chemicals currently listed as carcinogens or reproductive toxins. For more information go to www.P65Warnings.ca.gov. WARNING: US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd. (a)) Ethylene Glycol Monobutyl Ether (CAS 111-76-2) International Inventories Country(s) or region Inventory name On inventory (yes/no)* NoAustralia Australian Inventory of Chemical Substances (AICS) NoCanada Domestic Substances List (DSL) NoCanada Non-Domestic Substances List (NDSL) NoChina Inventory of Existing Chemical Substances in China (IECSC) NoEurope European Inventory of Existing Commercial Chemical Substances (EINECS) NoEurope European List of Notified Chemical Substances (ELINCS) NoJapan Inventory of Existing and New Chemical Substances (ENCS) NoKorea Existing Chemicals List (ECL) NoNew Zealand New Zealand Inventory NoPhilippines Philippine Inventory of Chemicals and Chemical Substances (PICCS) NoTaiwan Taiwan Toxic Chemical Substances (TCS) YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory *A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision 01-26-2018Issue date Version #01 ITW Pro Brands cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user’s responsibility to ensure safe conditions for handling, storage and disposal of the product, and to assume liability for loss, injury, damage or expense due to improper use. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Disclaimer 7 / 7 Material name: Liquid Alive® Enzyme Producing Bacteria 23301, 23305, 23332, 23335, 23355, 23394, 23395 Version #: 01 Issue date: 01-26-2018 SDS US