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HomeMy WebLinkAboutBetco Dust Mop Treatment (Aerosol)Dust Mop Treatment Not available. Aerosol. Chemtrec 800-424-9300 (24 Hour) SAFETY DATA SHEET GHS product identifier Other means of identification Product type Emergency telephone number (with hours of operation) Section 1. Identification : : : : Supplier's details :Betco Corporation 1001 Brown Avenue Toledo, OH 43607 www.betco.com 888-462-3826 Dust Mop Treatment Relevant identified uses of the substance or mixture and uses advised against Not applicable. Section 2. Hazards identification FLAMMABLE AEROSOLS - Category 1 ASPIRATION HAZARD - Category 1 Classification of the substance or mixture : Signal word :Danger Hazard statements :Extremely flammable aerosol. May be fatal if swallowed and enters airways. Hazard pictograms : Precautionary statements Prevention :Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Pressurized container: Do not pierce or burn, even after use. Do not spray on an open flame or other ignition source. Response :IF SWALLOWED: Immediately call a POISON CENTER or physician. Do NOT induce vomiting. Storage :Store locked up. Protect from sunlight. Do not expose to temperatures exceeding 50 °C/122 °F. Disposal :Dispose of contents and container in accordance with all local, regional, national and international regulations. GHS label elements OSHA/HCS status :This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). Hazards not otherwise classified :None known. Date of issue/Date of revision :4/8/2015.Date of previous issue :4/8/2015.Version :3 1/12 Dust Mop Treatment Section 3. Composition/information on ingredients Distillates (petroleum), hydrotreated light ≥10 - <25 64742-47-8 Solvent naphtha (petroleum), light aliph.≥5 - <10 64742-89-8 propane ≥1 - <3 74-98-6 Ingredient name CAS number% There are no additional ingredients present which, within the current knowledge of the supplier and in the concentrations applicable, are classified as hazardous to health or the environment and hence require reporting in this section. Other means of identification :Not available. CAS number :Not applicable. Substance/mixture Product code :035 CAS number/other identifiers : Occupational exposure limits, if available, are listed in Section 8. Mixture Any concentration shown as a range is to protect confidentiality or is due to batch variation. Get medical attention immediately. Call a poison center or physician. Wash out mouth with water. Remove dentures if any. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If material has been swallowed and the exposed person is conscious, give small quantities of water to drink. Stop if the exposed person feels sick as vomiting may be dangerous. Aspiration hazard if swallowed. Can enter lungs and cause damage. Do not induce vomiting. If vomiting occurs, the head should be kept low so that vomit does not enter the lungs. Never give anything by mouth to an unconscious person. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Immediately flush eyes with plenty of water, occasionally lifting the upper and lower eyelids. Check for and remove any contact lenses. Continue to rinse for at least 10 minutes. Get medical attention if irritation occurs. Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Get medical attention if symptoms occur. Wash clothing before reuse. Clean shoes thoroughly before reuse. Remove victim to fresh air and keep at rest in a position comfortable for breathing. If not breathing, if breathing is irregular or if respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Get medical attention if adverse health effects persist or are severe. If unconscious, place in recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. Section 4. First aid measures Eye contact Skin contact Inhalation Ingestion : : : : Description of necessary first aid measures Most important symptoms/effects, acute and delayed Inhalation :No known significant effects or critical hazards. May be fatal if swallowed and enters airways.:Ingestion Skin contact :No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact Over-exposure signs/symptoms Eye contact :Adverse symptoms may include the following: irritation redness Potential acute health effects Date of issue/Date of revision :4/8/2015.Date of previous issue :4/8/2015.Version :3 2/12 Dust Mop Treatment Section 4. First aid measures Protection of first-aiders :No action shall be taken involving any personal risk or without suitable training. It may be dangerous to the person providing aid to give mouth-to-mouth resuscitation. Notes to physician :Treat symptomatically. Contact poison treatment specialist immediately if large quantities have been ingested or inhaled. Specific treatments :No specific treatment. Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing Adverse symptoms may include the following: nausea or vomiting No specific data. : : : See toxicological information (Section 11) Indication of immediate medical attention and special treatment needed, if necessary Section 5. Fire-fighting measures Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool. Hazardous thermal decomposition products Specific hazards arising from the chemical Decomposition products may include the following materials: carbon dioxide carbon monoxide Extremely flammable aerosol. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. Gas may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back, causing fire or explosion. Bursting aerosol containers may be propelled from a fire at high speed. Runoff to sewer may create fire or explosion hazard. Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure mode. Special protective equipment for fire-fighters Use an extinguishing agent suitable for the surrounding fire. Extinguishing media : : : None known. Suitable extinguishing media : Unsuitable extinguishing media : Special protective actions for fire-fighters : Section 6. Accidental release measures Personal precautions, protective equipment and emergency procedures :No action shall be taken involving any personal risk or without suitable training. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. In the case of aerosols being ruptured, care should be taken due to the rapid escape of the pressurized contents and propellant. If a large number of containers are ruptured, treat as a bulk material spillage according to the instructions in the clean-up section. Do not touch or walk through spilled material. Shut off all ignition sources. No flares, smoking or flames in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put on appropriate personal protective equipment. For non-emergency personnel For emergency responders :If specialised clothing is required to deal with the spillage, take note of any information in Section 8 on suitable and unsuitable materials. See also the information in "For non- emergency personnel". Date of issue/Date of revision :4/8/2015.Date of previous issue :4/8/2015.Version :3 3/12 Dust Mop Treatment Section 6. Accidental release measures Environmental precautions Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Approach release from upwind. Prevent entry into sewers, water courses, basements or confined areas. Wash spillages into an effluent treatment plant or proceed as follows. Contain and collect spillage with non-combustible, absorbent material e.g. sand, earth, vermiculite or diatomaceous earth and place in container for disposal according to local regulations (see Section 13). Dispose of via a licensed waste disposal contractor. Contaminated absorbent material may pose the same hazard as the spilled product. Note: see Section 1 for emergency contact information and Section 13 for waste disposal. :Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air). Large spill : Stop leak if without risk. Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Dilute with water and mop up if water-soluble. Alternatively, or if water-insoluble, absorb with an inert dry material and place in an appropriate waste disposal container. Dispose of via a licensed waste disposal contractor. Small spill : Methods and materials for containment and cleaning up Section 7. Handling and storage Advice on general occupational hygiene Conditions for safe storage, including any incompatibilities Eating, drinking and smoking should be prohibited in areas where this material is handled, stored and processed. Workers should wash hands and face before eating, drinking and smoking. Remove contaminated clothing and protective equipment before entering eating areas. See also Section 8 for additional information on hygiene measures. Store in accordance with local regulations. Store away from direct sunlight in a dry, cool and well-ventilated area, away from incompatible materials (see Section 10) and food and drink. Store locked up. Eliminate all ignition sources. Use appropriate containment to avoid environmental contamination. : : Protective measures Put on appropriate personal protective equipment (see Section 8). Pressurized container: protect from sunlight and do not expose to temperatures exceeding 50°C. Do not pierce or burn, even after use. Do not swallow. Avoid contact with eyes, skin and clothing. Avoid breathing gas. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Store and use away from heat, sparks, open flame or any other ignition source. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Use only non-sparking tools. Empty containers retain product residue and can be hazardous. : Precautions for safe handling Distillates (petroleum), hydrotreated light ACGIH TLV (United States, 4/2014). Absorbed through skin. TWA: 200 mg/m³, (as total hydrocarbon vapor) 8 hours. propane OSHA PEL 1989 (United States, 3/1989). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours. NIOSH REL (United States, 10/2013). TWA: 1000 ppm 10 hours. TWA: 1800 mg/m³ 10 hours. OSHA PEL (United States, 2/2013). TWA: 1000 ppm 8 hours. TWA: 1800 mg/m³ 8 hours. Section 8. Exposure controls/personal protection Ingredient name Exposure limits Control parameters Occupational exposure limits Date of issue/Date of revision :4/8/2015.Date of previous issue :4/8/2015.Version :3 4/12 Dust Mop Treatment Section 8. Exposure controls/personal protection Hand protection Use a properly fitted, air-purifying or air-fed respirator complying with an approved standard if a risk assessment indicates this is necessary. Respirator selection must be based on known or anticipated exposure levels, the hazards of the product and the safe working limits of the selected respirator. Chemical-resistant, impervious gloves complying with an approved standard should be worn at all times when handling chemical products if a risk assessment indicates this is necessary. Considering the parameters specified by the glove manufacturer, check during use that the gloves are still retaining their protective properties. It should be noted that the time to breakthrough for any glove material may be different for different glove manufacturers. In the case of mixtures, consisting of several substances, the protection time of the gloves cannot be accurately estimated. < 1 hour (breakthrough time): disposable vinyl Safety eyewear complying with an approved standard should be used when a risk assessment indicates this is necessary to avoid exposure to liquid splashes, mists, gases or dusts. If contact is possible, the following protection should be worn, unless the assessment indicates a higher degree of protection: safety glasses with side- shields. Recommended: safety glasses with side-shields Eye/face protection Respiratory protection : : : Body protection Personal protective equipment for the body should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. When there is a risk of ignition from static electricity, wear anti- static protective clothing. For the greatest protection from static discharges, clothing should include anti-static overalls, boots and gloves. : Environmental exposure controls :Emissions from ventilation or work process equipment should be checked to ensure they comply with the requirements of environmental protection legislation. In some cases, fume scrubbers, filters or engineering modifications to the process equipment will be necessary to reduce emissions to acceptable levels. Appropriate engineering controls :Use only with adequate ventilation. If user operations generate dust, fumes, gas, vapor or mist, use process enclosures, local exhaust ventilation or other engineering controls to keep worker exposure to airborne contaminants below any recommended or statutory limits. The engineering controls also need to keep gas, vapor or dust concentrations below any lower explosive limits. Use explosion-proof ventilation equipment. Wash hands, forearms and face thoroughly after handling chemical products, before eating, smoking and using the lavatory and at the end of the working period. Appropriate techniques should be used to remove potentially contaminated clothing. Wash contaminated clothing before reusing. Ensure that eyewash stations and safety showers are close to the workstation location. Hygiene measures : Individual protection measures Skin protection Other skin protection :Appropriate footwear and any additional skin protection measures should be selected based on the task being performed and the risks involved and should be approved by a specialist before handling this product. Section 9. Physical and chemical properties Physical state Melting point Liquid. [Aerosol. Compressed gas. Emulsion.] Not available. Fruity.Odor pH White.Color Evaporation rate Not available. Flash point Closed cup: -104.4°C (-155.9°F) [Product does not sustain combustion.] Not available. Not available.Odor threshold : : : : : : : : Appearance Boiling point :Not available. Flammability (solid, gas):Not available. Date of issue/Date of revision :4/8/2015.Date of previous issue :4/8/2015.Version :3 5/12 Dust Mop Treatment Section 9. Physical and chemical properties Vapor pressure Relative density Vapor density Solubility 0.889 Not available. Not available. Not available. Auto-ignition temperature Not available. Not available. Viscosity Not available. Partition coefficient: n- octanol/water : : : : : : : Lower and upper explosive (flammable) limits :Not available. Decomposition temperature :Not available. Type of aerosol :Spray Heat of combustion :4.205 kJ/g Aerosol product Section 10. Stability and reactivity Hazardous decomposition products Conditions to avoid Avoid all possible sources of ignition (spark or flame). Under normal conditions of storage and use, hazardous decomposition products should not be produced. The product is stable.Chemical stability No specific data. : : : Incompatible materials : Possibility of hazardous reactions :Under normal conditions of storage and use, hazardous reactions will not occur. Reactivity :No specific test data related to reactivity available for this product or its ingredients. Section 11. Toxicological information Acute toxicity Not available. Carcinogenicity Not available. Mutagenicity Not available. Teratogenicity Not available. Reproductive toxicity Not available. Irritation/Corrosion Not available. Sensitization Not available. Specific target organ toxicity (single exposure) Information on toxicological effects Date of issue/Date of revision :4/8/2015.Date of previous issue :4/8/2015.Version :3 6/12 Dust Mop Treatment Section 11. Toxicological information Not available. Information on the likely routes of exposure Inhalation :No known significant effects or critical hazards. May be fatal if swallowed and enters airways.:Ingestion Skin contact :No known significant effects or critical hazards. No known significant effects or critical hazards.:Eye contact No known significant effects or critical hazards.General : No known significant effects or critical hazards.Carcinogenicity : No known significant effects or critical hazards.Mutagenicity : No known significant effects or critical hazards.Teratogenicity : Developmental effects :No known significant effects or critical hazards. Fertility effects :No known significant effects or critical hazards. Symptoms related to the physical, chemical and toxicological characteristics Skin contact Ingestion Inhalation Adverse symptoms may include the following: respiratory tract irritation coughing Adverse symptoms may include the following: nausea or vomiting No specific data. : : : Eye contact :Adverse symptoms may include the following: irritation redness Potential chronic health effects Delayed and immediate effects and also chronic effects from short and long term exposure Specific target organ toxicity (repeated exposure) Distillates (petroleum), hydrotreated light Category 3 Not applicable.Narcotic effects propane Category 3 Not applicable.Respiratory tract irritation Name Category Not available. Numerical measures of toxicity Aspiration hazard Name Result Distillates (petroleum), hydrotreated light ASPIRATION HAZARD - Category 1 Solvent naphtha (petroleum), light aliph.ASPIRATION HAZARD - Category 1 Route of exposure Target organs :Routes of entry anticipated: Dermal, Inhalation. Potential acute health effects Potential immediate effects :Not available. Short term exposure Potential delayed effects :Not available. Potential immediate effects :Not available. Long term exposure Potential delayed effects :Not available. Date of issue/Date of revision :4/8/2015.Date of previous issue :4/8/2015.Version :3 7/12 Dust Mop Treatment Section 11. Toxicological information Not available. Acute toxicity estimates Section 12. Ecological information LogPow BCF Potential Bioaccumulative potential Other adverse effects :No known significant effects or critical hazards. Product/ingredient name Solvent naphtha (petroleum), light aliph. -10 to 2500 high propane 1.09 -low Toxicity Distillates (petroleum), hydrotreated light Acute LC50 2200 µg/l Fresh water Fish - Lepomis macrochirus 4 days Solvent naphtha (petroleum), light aliph. Acute LC50 >100000 ppm Fresh water Fish - Oncorhynchus mykiss 96 hours Product/ingredient name SpeciesResult Exposure Persistence and degradability Soil/water partition coefficient (KOC) :Not available. Mobility in soil Not available. Section 13. Disposal considerations The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-products should at all times comply with the requirements of environmental protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non-recyclable products via a licensed waste disposal contractor. Waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging should be recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Empty containers or liners may retain some product residues. Do not puncture or incinerate container. :Disposal methods Section 14. Transport information Aerosols 2.1 Aerosols 2.1 Not available. 2.1 1950 1950 DOT Classification IMDG IATA UN number UN proper shipping name Transport hazard class(es) TDG Classification 1950 Aerosols 2.1 ADR/RID 1950 Aerosols 2 Mexico Classification 1950 Aerosols 2.1 Date of issue/Date of revision :4/8/2015.Date of previous issue :4/8/2015.Version :3 8/12 Dust Mop Treatment Section 14. Transport information --- Reportable quantity 18181.8 lbs / 8254.5 kg [2452.9 gal / 9285.2 L] Package sizes shipped in quantities less than the product reportable quantity are not subject to the RQ (reportable quantity) transportation requirements. Limited quantity Yes. -- Packing group Additional information Environmental hazards Special precautions for user Transport in bulk according to Annex II of MARPOL 73/78 and the IBC Code No.No.No. Transport within user’s premises: always transport in closed containers that are upright and secure. Ensure that persons transporting the product know what to do in the event of an accident or spillage. :Not available. : - No. Explosive Limit and Limited Quantity Index 1 - No. Tunnel code (D) - No. - Section 15. Regulatory information U.S. Federal regulations Clean Water Act (CWA) 307: toluene; benzene; ethylbenzene Clean Water Act (CWA) 311: toluene; benzene; ethylbenzene Clean Air Act (CAA) 112 regulated flammable substances: butane; propane : Clean Air Act Section 112 (b) Hazardous Air Pollutants (HAPs) :Not listed Clean Air Act Section 602 Class I Substances :Not listed Clean Air Act Section 602 Class II Substances :Not listed DEA List I Chemicals (Precursor Chemicals) :Not listed DEA List II Chemicals (Essential Chemicals) :Not listed TSCA 8(a) PAIR: heptane TSCA 8(a) CDR Exempt/Partial exemption: Not determined All components are listed or exempted. SARA 302/304 Date of issue/Date of revision :4/8/2015.Date of previous issue :4/8/2015.Version :3 9/12 Dust Mop Treatment Section 15. Regulatory information The following components are listed: BUTANE; PROPANE WARNING: This product contains less than 0.1% of a chemical known to the State of California to cause cancer. WARNING: This product contains less than 1% of a chemical known to the State of California to cause birth defects or other reproductive harm. Massachusetts : toluene No.Yes.No.7000 µg/day (ingestion) benzene Yes.Yes.6.4 µg/day (ingestion) 24 µg/day (ingestion) 13 µg/day (inhalation) 49 µg/day (inhalation) ethylbenzene Yes.No.41 µg/day (ingestion)No. 54 µg/day (inhalation) Ingredient name Cancer Reproductive No significant risk level Maximum acceptable dosage level California Prop. 65 New York :None of the components are listed. New Jersey :The following components are listed: BUTANE; PROPANE Pennsylvania :The following components are listed: BUTANE; PROPANE State regulations SARA 304 RQ :Not applicable. No products were found. Composition/information on ingredients SARA 311/312 Classification :Fire hazard Distillates (petroleum), hydrotreated light ≥10 - <25 No.No.No.Yes.No. Solvent naphtha (petroleum), light aliph. ≥5 - <10 No.No.No.No.Yes. propane ≥1 - <3 Yes.Yes.No.Yes.No. Name %Fire hazard Sudden release of pressure Reactive Immediate (acute) health hazard Delayed (chronic) health hazard Composition/information on ingredients International regulations Chemical Weapon Convention List Schedules I, II & III Chemicals Montreal Protocol (Annexes A, B, C, E) Not listed. Stockholm Convention on Persistent Organic Pollutants Not listed. Rotterdam Convention on Prior Inform Consent (PIC) Not listed. Not listed. UNECE Aarhus Protocol on POPs and Heavy Metals Not listed. International lists National inventory Date of issue/Date of revision :4/8/2015.Date of previous issue :4/8/2015.Version :3 10/12 Dust Mop Treatment Section 15. Regulatory information Australia :All components are listed or exempted. Canada :All components are listed or exempted. China :All components are listed or exempted. Europe :All components are listed or exempted. Japan :Not determined. Republic of Korea :All components are listed or exempted. Malaysia :Not determined. New Zealand :All components are listed or exempted. Philippines :All components are listed or exempted. Taiwan :All components are listed or exempted. Section 16. Other information 4/8/2015. History Date of printing Date of issue/Date of revision Version Date of previous issue : : : : 4/8/2015. 4/8/2015. 3 Hazardous Material Information System (U.S.A.) 1 4 0 0 4 1 * National Fire Protection Association (U.S.A.) Health Special Instability/Reactivity Flammability Health Flammability Physical hazards Caution: HMIS® ratings are based on a 0-4 rating scale, with 0 representing minimal hazards or risks, and 4 representing significant hazards or risks Although HMIS® ratings are not required on SDSs under 29 CFR 1910. 1200, the preparer may choose to provide them. HMIS® ratings are to be used with a fully implemented HMIS® program. HMIS® is a registered mark of the National Paint & Coatings Association (NPCA). HMIS® materials may be purchased exclusively from J. J. Keller (800) 327-6868. The customer is responsible for determining the PPE code for this material. Reprinted with permission from NFPA 704-2001, Identification of the Hazards of Materials for Emergency Response Copyright ©1997, National Fire Protection Association, Quincy, MA 02269. This reprinted material is not the complete and official position of the National Fire Protection Association, on the referenced subject which is represented only by the standard in its entirety. Copyright ©2001, National Fire Protection Association, Quincy, MA 02269. This warning system is intended to be interpreted and applied only by properly trained individuals to identify fire, health and reactivity hazards of chemicals. The user is referred to certain limited number of chemicals with recommended classifications in NFPA 49 and NFPA 325, which would be used as a guideline only. Whether the chemicals are classified by NFPA or not, anyone using the 704 systems to classify chemicals does so at their own risk. Procedure used to derive the classification Classification Justification Flam. Aerosol 1, H222 Expert judgment Asp. Tox. 1, H304 Expert judgment Date of issue/Date of revision :4/8/2015.Date of previous issue :4/8/2015.Version :3 11/12 Dust Mop Treatment Section 16. Other information To the best of our knowledge, the information contained herein is accurate. However, neither the above-named supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. Notice to reader Indicates information that has changed from previously issued version. References :Not available. Key to abbreviations :ATE = Acute Toxicity Estimate BCF = Bioconcentration Factor GHS = Globally Harmonized System of Classification and Labelling of Chemicals IATA = International Air Transport Association IBC = Intermediate Bulk Container IMDG = International Maritime Dangerous Goods LogPow = logarithm of the octanol/water partition coefficient MARPOL 73/78 = International Convention for the Prevention of Pollution From Ships, 1973 as modified by the Protocol of 1978. ("Marpol" = marine pollution) UN = United Nations Date of issue/Date of revision :4/8/2015.Date of previous issue :4/8/2015.Version :3 12/12