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Home My WebLink AboutBuckeye Blue 5001 All Purpose Cleaner Safety Data Sheet Issue Date: 27-Dec-2011 Revision Date: 19-Aug-2014 Version 1 _____________________________________________________________________________________________ Page 1 / 8 1. IDENTIFICATION Product Identifier Product Name Buckeye Blue Other means of identification SDS # BE-5001 Product Code 5001 Recommended use of the chemical and restrictions on use Recommended Use All Purpose Cleaner, Water Based. Details of the supplier of the safety data sheet Supplier Address Buckeye International, Inc. 2700 Wagner Place Maryland Heights, MO 63043 USA Emergency Telephone Number Company Phone Number 1-651-632-8956 (International) 1-800-303-0441 (North America) Emergency Telephone (24 hr) INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance Clear blue liquid Physical State Liquid Odor Citrus fragrance Classification Serious eye damage/eye irritation Category 2 Carcinogenicity Category 1B Signal Word Danger Hazard Statements Causes serious eye irritation May cause cancer BE-5001 - Buckeye Blue Revision Date: 19-Aug-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 8 Precautionary Statements - Prevention Obtain special instructions before use Do not handle until all safety precautions have been read and understood Use personal protective equipment as required Wash face, hands and any exposed skin thoroughly after handling Precautionary Statements - Response If exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing If eye irritation persists: Get medical advice/attention Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other Hazards Toxic to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% EDTA 60-00-4 <15 Sodium Nitrite 7632-00-0 <1 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST-AID MEASURES First Aid Measures General Advice If exposed or concerned: Get medical advice/attention. Eye Contact IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Get medical attention if irritation develops or persists. Inhalation Remove to fresh air. Ingestion Drink 2-3 large glasses of water. Do not induce vomiting. Call a physician. Never give anything by mouth to an unconscious person. Most important symptoms and effects Symptoms Causes serious eye irritation. Can cause defatting of skin tissue. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. BE-5001 - Buckeye Blue Revision Date: 19-Aug-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 8 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Combustion products may be toxic. Hazardous Combustion Products Carbon oxides. Nitrogen oxides (NOx). Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental Precautions Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clear water and allow floor to dry before allowing traffic. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes or clothing. Use personal protection recommended in Section 8. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Wash face, hands, and any exposed skin thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed and store in a cool, dry and well-ventilated place. Keep container closed when not in use. Store at room temperature. Store locked up. Incompatible Materials Chlorine bleach. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Triethanolamine 102-71-6 TWA: 5 mg/m3 - - Phosphoric Acid 7664-38-2 STEL: 3 mg/m3 TWA: 1 mg/m3 TWA: 1 mg/m3 (vacated) TWA: 1 mg/m3 (vacated) STEL: 3 mg/m3 IDLH: 1000 mg/m3 TWA: 1 mg/m3 STEL: 3 mg/m3 BE-5001 - Buckeye Blue Revision Date: 19-Aug-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 8 Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers. Individual protection measures, such as personal protective equipment Eye/Face Protection Splash goggles or safety glasses. Skin and Body Protection Rubber gloves. Suitable protective clothing. Respiratory Protection Ensure adequate ventilation, especially in confined areas. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Liquid Appearance Clear blue liquid Odor Citrus fragrance Color Clear blue Odor Threshold Not determined Property Values Remarks • Method pH 11.0-11.4 (conc.) 10.3-10.7 (1:16 dilution) Melting Point/Freezing Point Not determined Boiling Point/Boiling Range 100 °C / 212 °F Flash Point None Tag Closed Cup Evaporation Rate 1.0 (Water = 1) Flammability (Solid, Gas) Liquid-Not Applicable Upper Flammability Limits Not Applicable Lower Flammability Limit Not Applicable Vapor Pressure Not determined Vapor Density Not determined Specific Gravity 1.04 Water Solubility Infinite Solubility in other solvents Not determined Partition Coefficient Not determined Auto-ignition Temperature Not determined Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. BE-5001 - Buckeye Blue Revision Date: 19-Aug-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 8 Conditions to Avoid Keep separated from incompatible substances. Keep out of reach of children. Incompatible Materials Chlorine bleach. Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information The information below is for repeated and prolonged contact in an occupational setting. It does not apply to normal product use Eye Contact Causes serious eye irritation. Skin Contact Avoid contact with skin. Inhalation Avoid breathing vapors or mists. Ingestion Do not ingest. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 EDTA 60-00-4 = 1700 mg/kg ( Rat ) - - Sodium Nitrite 7632-00-0 = 85 mg/kg ( Rat ) - = 5.5 mg/L ( Rat ) 4 h Triethanolamine 102-71-6 = 4190 mg/kg ( Rat ) > 2000 mg/kg ( Rabbit ) > 16 mL/kg ( Rat ) - Phosphoric Acid 7664-38-2 = 1530 mg/kg ( Rat ) = 2730 mg/kg ( Rabbit ) > 850 mg/m3 ( Rat ) 1 h Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Nitrate or nitrite (ingested) under conditions that result in endogenous nitrosation are considered IARC group 2A carcinogens. Chemical Name ACGIH IARC NTP OSHA Sodium Nitrite 7632-00-0 Group 2A X Legend IARC (International Agency for Research on Cancer) Group 2A - Probably Carcinogenic to Humans OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Numerical measures of toxicity Not determined BE-5001 - Buckeye Blue Revision Date: 19-Aug-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 8 12. ECOLOGICAL INFORMATION Ecotoxicity Toxic to aquatic life with long lasting effects. Component Information Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Crustacea EDTA 60-00-4 1.01: 72 h Desmodesmus subspicatus mg/L EC50 34 - 62: 96 h Lepomis macrochirus mg/L LC50 static 44.2 - 76.5: 96 h Pimephales promelas mg/L LC50 static 113: 48 h Daphnia magna mg/L EC50 Static Sodium Nitrite 7632-00-0 0.19: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 0.092 - 0.13: 96 h Oncorhynchus mykiss mg/L LC50 flow-through 0.4 -0.6: 96 h Oncorhynchus mykiss mg/L LC50 semi-static 0.65 - 1: 96 h Oncorhynchus mykiss mg/L LC50 static 2.3: 96 h Pimephales promelas mg/L LC50 flow-through 20: 96 h Pimephales promelas mg/L LC50 static Triethanolamine 102-71-6 216: 72 h Desmodesmus subspicatus mg/L EC50 169: 96 h Desmodesmus subspicatus mg/L EC50 10600 - 13000: 96 h Pimephales promelas mg/L LC50 flow-through 1000: 96 h Pimephales promelas mg/L LC50 static 450 - 1000: 96 h Lepomis macrochirus mg/L LC50 static 1386: 24 h Daphnia magna mg/L EC50 Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Partition Coefficient Sodium Nitrite 7632-00-0 -3.7 Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. BE-5001 - Buckeye Blue Revision Date: 19-Aug-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 8 US EPA Waste Number Chemical Name RCRA RCRA - Basis for Listing RCRA - D Series Wastes RCRA - U Series Wastes Octylphenozypolyethoxyetha nol 9036-19-5 Included in waste stream: K060 California Hazardous Waste Status Chemical Name California Hazardous Waste Status Sodium Nitrite 7632-00-0 Toxic Ignitable Reactive 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT Not regulated IATA Not regulated IMDG Not regulated 15. REGULATORY INFORMATION International Inventories TSCA Listed Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory US Federal Regulations CERCLA Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) EDTA 60-00-4 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ Sodium Nitrite 7632-00-0 100 lb RQ 100 lb final RQ RQ 45.4 kg final RQ SARA 313 Chemical Name CAS No Weight-% SARA 313 - Threshold Values % Sodium Nitrite - 7632-00-0 7632-00-0 <1 1.0 CWA (Clean Water Act) Component CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances EDTA 60-00-4 ( <15 ) 5000 lb X Sodium Nitrite 7632-00-0 ( <1 ) 100 lb X BE-5001 - Buckeye Blue Revision Date: 19-Aug-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 8 US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania EDTA 60-00-4 X X X Sodium Nitrite 7632-00-0 X X X Triethanolamine 102-71-6 X X X Phosphoric Acid 7664-38-2 X X X 16. OTHER INFORMATION NFPA Health Hazards 1 Flammability 0 Instability 0 Special Hazards Not determined HMIS Health Hazards Not determined Flammability Not determined Physical Hazards Not determined Personal Protection Not determined Issue Date: 27-Dec-2011 Revision Date: 19-Aug-2014 Revision Note: New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet