HomeMy WebLinkAboutBuckeye ECO Acid Cleaner E16
Safety Data Sheet
Issue Date: 30-Sep-2014
Revision Date: 29-Jul-2015
Version 1
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1. IDENTIFICATION
Product Identifier
Product Name Buckeye Eco Acid Cleaner
Other means of identification
SDS # BE-6016
Product Code 6016
Recommended use of the chemical and restrictions on use
Recommended Use Waterbased. Foaming acid cleaner.
Details of the supplier of the safety data sheet
Supplier Address
Buckeye International, Inc. 2700 Wagner Place
Maryland Heights, MO 63043 USA
Emergency Telephone Number 1-651-632-8956 (International)
1-800-303-0441 (North America) Emergency Telephone (24 hr) INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America)
2. HAZARDS IDENTIFICATION
Appearance Green liquid
Physical State Liquid
Odor Citrus Floral
Classification
This chemical does not meet the hazardous criteria set forth by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). However, this Safety Data Sheet (SDS) contains valuable information critical to the safe handling and proper use of
this product. This SDS should be retained and available for employees and other users of this product.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-%
Citric Acid 77-92-9 10-15
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES
First Aid Measures General Advice Provide this SDS to medical personnel for treatment.
BE-6016 - Buckeye Eco Acid Cleaner
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Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek medical advice. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. If skin irritation persists, call a physician. Inhalation Remove to fresh air. Ingestion Drink 2-3 large glasses of water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a physician immediately.
Most important symptoms and effects Symptoms Direct eye contact may cause stinging, tearing and redness. May cause redness of skin or a warming sensation. May cause nose and throat irritation.
Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined.
Specific Hazards Arising from the Chemical Not determined. Hazardous Combustion Products Oxides of carbon. Oxides of sulfur. Oxides of nitrogen. Phosphorus oxides.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental Precautions See Section 12 for additional Ecological Information.
Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Dilute with large amounts of water. Pick up with mops into a plastic bucket. Wash area with an alkaline detergent, followed by a clear water rinse. Allow floor to dry before allowing traffic.
7. HANDLING AND STORAGE
Precautions for safe handling Advice on Safe Handling Keep out of the reach of children. Avoid release to the environment.
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Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep container closed when not in use. Store at room temperature. Store on low shelves. Store away from caustics and strong alkali. Packaging Materials Rinse container before discarding. Incompatible Materials Chlorine bleach. Caustics. Alkali. Aluminium. Metals. Formica.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Citric Acid 77-92-9 - 15 mg / m3 (Total) -
Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers.
Individual protection measures, such as personal protective equipment Eye/Face Protection Splash goggles or safety glasses. Refer to 29 CFR 1910.133 for eye and face protection regulations. Skin and Body Protection Refer to 29 CFR 1910.138 for appropriate skin and body protection. Respiratory Protection Refer to 29 CFR 1910.134 for respiratory protection requirements. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Wash hands
thoroughly after handling. Wash contaminated clothing before reuse.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical State Liquid Appearance Green liquid Odor Citrus Floral Color Green
Odor Threshold Not determined
Property Values
Remarks • Method
pH 2.3 ± 0.2 (conc)
2.8 ± 0.2 (1:16 dilution/pH 7 DI Water)
Melting Point/Freezing Point Not determined Boiling Point/Boiling Range 100 °C / 212 °F
Flash Point None Tag Closed Cup Evaporation Rate 1.0
(Water = 1)
Flammability (Solid, Gas) n/a-liquid
Upper Flammability Limits Not applicable
Lower Flammability Limit Not applicable
Vapor Pressure Not determined
Vapor Density Not determined Specific Gravity 1.025
(1=Water)
Water Solubility Infinite Solubility in other solvents Not determined Partition Coefficient Not determined
Auto-ignition Temperature Not applicable
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Decomposition Temperature Not determined Kinematic Viscosity Not determined
Dynamic Viscosity Not determined
Explosive Properties Not determined Oxidizing Properties Not determined
10. STABILITY AND REACTIVITY
Reactivity
Not reactive under normal conditions.
Chemical Stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur.
Conditions to Avoid Keep out of reach of children.
Incompatible Materials
Chlorine bleach. Caustics. Alkali. Aluminium. Metals. Formica.
Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). Sulfur oxides. Phosphorous oxides.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure Product Information Eye Contact Avoid contact with eyes. Skin Contact Avoid contact with skin. Inhalation Avoid breathing vapors or mists. Ingestion Do not ingest.
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Citric Acid 77-92-9 = 3000 mg/kg ( Rat ) - -
Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Carcinogenic potential is unknown.
Numerical measures of toxicity Not determined
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12. ECOLOGICAL INFORMATION
Ecotoxicity
The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Component Information
Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Crustacea
Citric Acid 77-92-9 1516: 96 h Lepomis macrochirus mg/L LC50
static
120: 72 h Daphnia magna mg/L EC50
Persistence/Degradability Not determined.
Bioaccumulation Not determined.
Mobility
Chemical Name Partition Coefficient
Citric Acid 77-92-9 -1.72
Other Adverse Effects Not determined
13. DISPOSAL CONSIDERATIONS
Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and
regulations.
14. TRANSPORT INFORMATION
Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances.
DOT Not regulated
IATA Not regulated
IMDG Not regulated
15. REGULATORY INFORMATION
International Inventories
Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS
Citric Acid Present X Present Present X Present X X
Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
BE-6016 - Buckeye Eco Acid Cleaner
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DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances
US Federal Regulations
CERCLA
This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and
Reauthorization Act (SARA) (40 CFR 355).
SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations This product does not contain any substances regulated under applicable state right-to-know regulations
16. OTHER INFORMATION
NFPA Health Hazards 2
Flammability 0
Instability 0
Special Hazards Not determined
HMIS
Health Hazards
Not determined
Flammability
Not determined
Physical Hazards
Not determined
Personal Protection
Not determined
Issue Date: 30-Sep-2014 Revision Date: 29-Jul-2015 Revision Note: New format
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet