HomeMy WebLinkAboutBuckeye ECO Hydro Peroxide E15
Safety Data Sheet
Issue Date: 07-Apr-2014
Revision Date: 04-Feb-2015
Version 1
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1. IDENTIFICATION
Product Identifier
Product Name Buckeye Eco Hydrogen Peroxide Cleaner
Other means of identification
SDS # BE-6015
Product Code E 6015
Recommended use of the chemical and restrictions on use
Recommended Use All Purpose Cleaner, Water Based.
Details of the supplier of the safety data sheet
Supplier Address
Buckeye International, Inc.
2700 Wagner Place
Maryland Heights, MO 63043 USA
Emergency Telephone Number
Company Phone Number 1-651-632-8956 (International)
1-800-303-0441 (North America)
Emergency Telephone (24 hr) INFOTRAC 1-352-323-3500 (International)
1-800-535-5053 (North America)
2. HAZARDS IDENTIFICATION
Appearance Clear liquid
Physical State Liquid
Odor Orange blossom
Classification
Skin corrosion/irritation Category 2
Serious eye damage/eye irritation Category 2
Signal Word
Warning
Hazard Statements
Causes skin irritation
Causes serious eye irritation
BE-6015 - Buckeye Eco Hydrogen Peroxide Cleaner
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Precautionary Statements - Prevention
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Precautionary Statements - Prevention
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
If eye irritation persists: Get medical advice/attention IF ON SKIN: Wash with plenty of soap and water
Take off contaminated clothing and wash it before reuse
If skin irritation occurs: Get medical advice/attention
Other Hazards
Toxic to aquatic life with long lasting effects
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-%
Hydrogen Peroxide 7722-84-1 <12
Sodium xylenesulfonate 1300-72-7 <2
Alkylpolyglycoside C8-10 68515-73-1 <5
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage
of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES
First Aid Measures
Eye Contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Skin Contact Wash skin with soap and water. Take off contaminated clothing and wash it before reuse. If
skin irritation occurs: Get medical advice/ attention.
Inhalation Remove to fresh air.
Ingestion Drink 2-3 large glasses of water. Do not induce vomiting. Call a physician. Never give
anything by mouth to an unconscious person.
Most important symptoms and effects
Symptoms Causes serious eye irritation. Causes skin irritation. Can cause defatting of skin tissue.
Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically. Dermatitis or other pre-existing skin conditions may be aggravated
by overexposure to this product.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable Extinguishing Media Not determined.
Specific Hazards Arising from the Chemical
Combustion products may be toxic.
Hazardous Combustion Products Carbon oxides. Nitrogen oxides (NOx).
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Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions Use personal protection recommended in Section 8.
Environmental Precautions Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See
Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clear water and allow
floor to dry before allowing traffic.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Use personal
protection recommended in Section 8. Avoid contact with skin, eyes or clothing. Wash face,
hands, and any exposed skin thoroughly after handling. Keep containers closed when not in
use.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep container tightly closed and store in a cool, dry and well-ventilated place. Store at
room temperature.
Incompatible Materials Chlorine bleach.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Hydrogen Peroxide
7722-84-1
TWA: 1 ppm TWA: 1 ppm
TWA: 1.4 mg/m3
(vacated) TWA: 1 ppm
(vacated) TWA: 1.4 mg/m3
IDLH: 75 ppm
TWA: 1 ppm
TWA: 1.4 mg/m3
Appropriate engineering controls
Engineering Controls Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers.
Individual protection measures, such as personal protective equipment
Eye/Face Protection Use safety glasses or chemical splash goggles.
Skin and Body Protection Wear rubber gloves or other impervious gloves.
Respiratory Protection No protection is ordinarily required under normal conditions of use and with adequate
ventilation.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice.
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9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical State Liquid
Appearance Clear liquid
Odor Orange blossom
Color Not determined
Odor Threshold Not determined
Property Values
Remarks • Method
pH 4.0 - 4.4 (conc.)
5.1 - 6.1 (1:64 dilution)
Melting Point/Freezing Point Not determined
Boiling Point/Boiling Range 100 °C / 212 °F
Flash Point None Tag Closed Cup
Evaporation Rate 1.0
(Water = 1)
Flammability (Solid, Gas) Liquid-Not applicable
Upper Flammability Limits Not applicable
Lower Flammability Limit Not applicable
Vapor Pressure Not determined
Vapor Density Not determined
Specific Gravity 1.025
(1=Water)
Water Solubility Infinite
Solubility in other solvents Not determined
Partition Coefficient Not determined
Auto-ignition Temperature Not applicable
Decomposition Temperature Not determined
Kinematic Viscosity Not determined
Dynamic Viscosity Not determined
Explosive Properties Not determined
Oxidizing Properties Not determined
10. STABILITY AND REACTIVITY
Reactivity
Not reactive under normal conditions.
Chemical Stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous Polymerization Hazardous polymerization does not occur.
Conditions to Avoid
Keep separated from incompatible substances. Keep out of reach of children.
Incompatible Materials
Chlorine bleach.
Hazardous Decomposition Products
Carbon oxides. Nitrogen oxides (NOx).
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11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Eye Contact Causes serious eye irritation.
Skin Contact Causes skin irritation.
Inhalation Avoid breathing vapors or mists.
Ingestion Do not ingest.
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Hydrogen Peroxide
7722-84-1
= 801 mg/kg ( Rat ) = 4060 mg/kg ( Rat ) = 2000 mg/kg
( Rabbit )
= 2 mg/L ( Rat ) 4 h
Sodium xylenesulfonate
1300-72-7
= 7200 mg/kg ( Rat ) - -
Information on physical, chemical and toxicological effects
Symptoms Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity Group 3 IARC components are "not classifiable as human carcinogens".
Chemical Name ACGIH IARC NTP OSHA
Hydrogen Peroxide 7722-84-1 A3 Group 3
Legend ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 3 IARC components are "not classifiable as human carcinogens"
Numerical measures of toxicity
Not determined
12. ECOLOGICAL INFORMATION
Ecotoxicity
Toxic to aquatic life with long lasting effects.
Component Information
Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Crustacea
Hydrogen Peroxide
7722-84-1
2.5: 72 h Chlorella vulgaris
mg/L EC50
16.4: 96 h Pimephales
promelas mg/L LC50 18 - 56:
96 h Lepomis macrochirus
mg/L LC50 static 10.0 - 32.0:
96 h Oncorhynchus mykiss
mg/L LC50 static
7.7: 24 h Daphnia magna
mg/L EC50 18 - 32: 48 h
Daphnia magna mg/L EC50
Static
Persistence/Degradability
Not determined.
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Bioaccumulation
Not determined.
Mobility
Not determined
Other Adverse Effects
Not determined
13. DISPOSAL CONSIDERATIONS
Waste Treatment Methods
Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and
regulations.
California Hazardous Waste Status
Chemical Name California Hazardous Waste Status
Hydrogen Peroxide
7722-84-1
Toxic
Corrosive
Ignitable
Reactive
14. TRANSPORT INFORMATION
Note Please see current shipping paper for most up to date shipping information, including
exemptions and special circumstances.
DOT Not regulated
IATA Not regulated
IMDG Not regulated
15. REGULATORY INFORMATION
International Inventories
Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS
Hydrogen Peroxide Present X Present Present X Present X X
Sodium xylenesulfonate Present X Present Present X Present X X
Alkylpolyglycoside C8-10 Present X X Present X X
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
BE-6015 - Buckeye Eco Hydrogen Peroxide Cleaner
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US Federal Regulations
CERCLA
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
Hydrogen Peroxide
7722-84-1
1000 lb
SARA 313
Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any
chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372
CWA (Clean Water Act)
This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40
CFR 122.42)
US State Regulations
California Proposition 65
This product does not contain any Proposition 65 chemicals.
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
Hydrogen Peroxide
7722-84-1
X X X
16. OTHER INFORMATION
NFPA
Health Hazards
1
Flammability
0
Instability
0
Special Hazards
Not determined
HMIS Health Hazards
Not determined
Flammability
Not determined
Physical Hazards
Not determined
Personal Protection
Not determined
Issue Date: 07-Apr-2014
Revision Date: 04-Feb-2015
Revision Note: New format
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet