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Home My WebLink AboutBuckeye ECO Multipurpose Glass Cleaner E13 Safety Data Sheet Issue Date: 14-Jan-2013 Revision Date: 10-Feb-2015 Version 1 _____________________________________________________________________________________________ Page 1 / 8 1. IDENTIFICATION Product Identifier Product Name Buckeye Eco Multi-Purpose Glass Cleaner Other means of identification SDS # BE-6013 Product Code E6013 UN/ID No UN3271 Recommended use of the chemical and restrictions on use Recommended Use Concentrated Glass Cleaner, Water Based. Details of the supplier of the safety data sheet Supplier Address Buckeye International, Inc. 2700 Wagner Place Maryland Heights, MO 63043 USA Emergency Telephone Number Company Phone Number 1-651-632-8956 (International) 1-800-303-0441 (North America) Emergency Telephone (24 hr) INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance Clear blue liquid Physical State Liquid Odor None No fragrance added Classification Specific target organ toxicity (single exposure) Category 3 Flammable Liquids Category 3 Signal Word Warning Hazard Statements May cause drowsiness or dizziness Flammable liquid and vapor BE-6013 - Buckeye Eco Multi-Purpose Glass Cleaner Revision Date: 10-Feb-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 8 Precautionary Statements - Prevention Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Keep away from heat/sparks/open flames/hot surfaces. — No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof equipment Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower If skin irritation occurs: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a poison center or doctor/physician if you feel unwell IN CASE OF FIRE: Use CO2, dry chemical, or foam for extinction Precautionary Statements - Storage Store locked up Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Propylene glycol monomethyl ether 107-98-2 <60 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST-AID MEASURES First Aid Measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention if irritation develops or persists. Skin Contact Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Get medical attention if irritation develops or persists. Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a physician if you feel unwell. Ingestion Give two large glasses of water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention. Most important symptoms and effects Symptoms May be irritating to skin and eyes. May cause drowsiness or dizziness. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. BE-6013 - Buckeye Eco Multi-Purpose Glass Cleaner Revision Date: 10-Feb-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 8 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Flammable liquid and vapor. Combustion products may be toxic. Hazardous Combustion Products Carbon oxides. Sulfur oxides. Sensitivity to Static Discharge Take precautionary measures against static discharge. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protection recommended in Section 8. Environmental Precautions Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clear water and allow floor to dry before allowing traffic. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Use personal protection recommended in Section 8. Avoid contact with skin, eyes or clothing. Wash thoroughly with soap and water after handling. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Keep away from heat/sparks/open flames/hot surfaces. — No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion proof equipment. Use only non-sparking tools. Take precautionary measures against static discharges. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed and store in a cool, dry and well-ventilated place. Store at room temperature. Store locked up. Incompatible Materials Chlorine bleach. BE-6013 - Buckeye Eco Multi-Purpose Glass Cleaner Revision Date: 10-Feb-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 8 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Propylene glycol monomethyl ether 107-98-2 STEL: 150 ppm TWA: 100 ppm (vacated) TWA: 100 ppm (vacated) TWA: 360 mg/m3 (vacated) STEL: 150 ppm (vacated) STEL: 540 mg/m3 TWA: 100 ppm TWA: 360 mg/m3 STEL: 150 ppm STEL: 540 mg/m3 Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers. Individual protection measures, such as personal protective equipment Eye/Face Protection Risk of contact: Wear approved safety goggles. Skin and Body Protection Wear rubber gloves or other impervious gloves. Respiratory Protection Use in well-ventilated area. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Liquid Appearance Clear blue liquid Odor None No fragrance added Color Blue Odor Threshold Not determined Property Values Remarks • Method pH 8.20 ± 0.5 (conc) 5.98 ± 0.5 (1:42 dilution) Melting Point/Freezing Point Not determined Boiling Point/Boiling Range 100 °C / 212 °F Flash Point <54 °C / <130 °F Tag Closed Cup Evaporation Rate 1.0 (Water = 1) Flammability (Solid, Gas) Liquid-Not applicable Upper Flammability Limits Not applicable Lower Flammability Limit Not applicable Vapor Pressure Not determined Vapor Density Not determined Specific Gravity 0.978 (1=Water) Water Solubility Infinite Solubility in other solvents Not determined Partition Coefficient Not determined Auto-ignition Temperature Not applicable Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined BE-6013 - Buckeye Eco Multi-Purpose Glass Cleaner Revision Date: 10-Feb-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 8 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid Keep separated from incompatible substances. Keep out of reach of children. Incompatible Materials Chlorine bleach. Hazardous Decomposition Products Carbon oxides. Sulfur oxides. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Avoid contact with eyes. Skin Contact Avoid contact with skin. Inhalation May cause drowsiness or dizziness. Ingestion Do not ingest. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Propylene glycol monomethyl ether 107-98-2 = 5200 mg/kg ( Rat ) = 13000 mg/kg ( Rabbit ) = 54.6 mg/L ( Rat ) 4 h > 24 mg/L ( Rat ) 1 h Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. STOT - single exposure May cause drowsiness or dizziness. Numerical measures of toxicity Not determined BE-6013 - Buckeye Eco Multi-Purpose Glass Cleaner Revision Date: 10-Feb-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 8 12. ECOLOGICAL INFORMATION Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Component Information Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Crustacea Propylene glycol monomethyl ether 107-98-2 20.8: 96 h Pimephales promelas g/L LC50 static 4600 - 10000: 96 h Leuciscus idus mg/L LC50 static 23300: 48 h Daphnia magna mg/L EC50 Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Partition Coefficient Propylene glycol monomethyl ether 107-98-2 -0.437 Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT UN/ID No UN3271 Proper Shipping Name Ethers, n.o.s. (Propylene glycol methyl ether) Hazard Class 3 Packing Group III IATA UN/ID No UN3271 Proper Shipping Name Ethers, n.o.s. (Propylene glycol methyl ether) Hazard Class 3 Packing Group III IMDG UN/ID No UN3271 Proper Shipping Name Ethers, n.o.s. (Propylene glycol methyl ether) Hazard Class 3 Packing Group III BE-6013 - Buckeye Eco Multi-Purpose Glass Cleaner Revision Date: 10-Feb-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 8 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS Propylene glycol monomethyl ether Present X Present Present X Present X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Propylene glycol monomethyl ether 107-98-2 X X X BE-6013 - Buckeye Eco Multi-Purpose Glass Cleaner Revision Date: 10-Feb-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 8 16. OTHER INFORMATION NFPA Health Hazards 0 Flammability 2 Instability 0 Special Hazards Not determined HMIS Health Hazards Not determined Flammability Not determined Physical Hazards Not determined Personal Protection Not determined Issue Date: 14-Jan-2013 Revision Date: 10-Feb-2015 Revision Note: New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet