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Home My WebLink AboutBuckeye ECO Muscle Cleaner E14 Safety Data Sheet Issue Date: 12-Nov-2012 Revision Date: 10-Feb-2015 Version 1 _____________________________________________________________________________________________ Page 1 / 8 1. IDENTIFICATION Product Identifier Product Name Buckeye Eco Muscle Cleaner Other means of identification SDS # BE-6014 Product Code E6014 UN/ID No UN1760 Recommended use of the chemical and restrictions on use Recommended Use Concentrated Spray and Wipe Cleaner, Water Based. Details of the supplier of the safety data sheet Supplier Address Buckeye International, Inc. 2700 Wagner Place Maryland Heights, MO 63043 USA Emergency Telephone Number Company Phone Number 1-651-632-8956 (International) 1-800-303-0441 (North America) Emergency Telephone (24 hr) INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance Orange/red solution Physical State Liquid Odor None No fragrance added Classification Skin corrosion/irritation Category 1 Sub-category C Serious eye damage/eye irritation Category 1 Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed Signal Word Danger Hazard Statements Causes severe skin burns and eye damage BE-6014 - Buckeye Eco Muscle Cleaner Revision Date: 10-Feb-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 8 Precautionary Statements - Prevention Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse If skin irritation occurs: Get medical advice/attention IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a poison center or doctor/physician IF SWALLOWED: Call a poison center or doctor/physician Rinse mouth Do not induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other Hazards Harmful to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Phenoxyethanol 122-99-6 <20 Benzyl alcohol 100-51-6 <20 Octanoic Acid 124-07-2 <10 Dodecyl benzene sulfonic acid 27176-87-0 <4 Sodium hydroxide 1310-73-2 <3 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST-AID MEASURES First Aid Measures Eye Contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. Skin Contact Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wash contaminated clothing before reuse. Get medical attention if irritation develops or persists. Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor/physician. Ingestion Give two large glasses of water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Get medical attention. BE-6014 - Buckeye Eco Muscle Cleaner Revision Date: 10-Feb-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 8 Most important symptoms and effects Symptoms Causes severe skin burns and eye damage. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Combustion products may be toxic. Hazardous Combustion Products Carbon oxides. Nitrogen oxides (NOx). Sulfur oxides. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protection recommended in Section 8. Environmental Precautions Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clear water and allow floor to dry before allowing traffic. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Use personal protection recommended in Section 8. Avoid contact with skin, eyes or clothing. Wash face, hands, and any exposed skin thoroughly after handling. Do not breathe dust/fume/gas/mist/vapors/spray. Keep containers closed when not in use. Conditions for safe storage, including any incompatibilities Storage Conditions Keep container tightly closed and store in a cool, dry and well-ventilated place. Store at room temperature. Store locked up. Packaging Materials May damage some plastics. Incompatible Materials Chlorine bleach. BE-6014 - Buckeye Eco Muscle Cleaner Revision Date: 10-Feb-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 8 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Sodium hydroxide 1310-73-2 Ceiling: 2 mg/m3 TWA: 2 mg/m3 (vacated) Ceiling: 2 mg/m3 IDLH: 10 mg/m3 Ceiling: 2 mg/m3 Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers. Individual protection measures, such as personal protective equipment Eye/Face Protection Use safety glasses or chemical splash goggles. Skin and Body Protection Wear rubber gloves or other impervious gloves. Respiratory Protection No protection is ordinarily required under normal conditions of use and with adequate ventilation. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Liquid Appearance Orange/red solution Odor None No fragrance added Color Red-orange Odor Threshold Not determined Property Values Remarks • Method pH 10.4 ± 0.2 (conc) 10.2 ± 0.2 (1:6 dilution) Melting Point/Freezing Point Not determined Boiling Point/Boiling Range 100 °C / 212 °F Flash Point None Tag Closed Cup Evaporation Rate 1.0 (Water = 1) Flammability (Solid, Gas) Liquid-Not applicable Upper Flammability Limits Not applicable Lower Flammability Limit Not applicable Vapor Pressure Not determined Vapor Density Not determined Specific Gravity 1.058 (1=Water) Water Solubility Infinite Solubility in other solvents Not determined Partition Coefficient Not determined Auto-ignition Temperature Not applicable Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined BE-6014 - Buckeye Eco Muscle Cleaner Revision Date: 10-Feb-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 8 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid Keep separated from incompatible substances. Keep out of reach of children. Incompatible Materials Chlorine bleach. Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). Sulfur oxides. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Causes severe eye damage. Skin Contact Causes severe skin burns. Inhalation Avoid breathing vapors or mists. Ingestion May be harmful if swallowed. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Benzyl alcohol 100-51-6 = 1230 mg/kg ( Rat ) = 2000 mg/kg ( Rabbit ) = 8.8 mg/L ( Rat ) 4 h Phenoxyethanol 122-99-6 = 1260 mg/kg ( Rat ) = 5 mL/kg ( Rabbit ) = 14422 mg/kg ( Rat ) - Octanoic Acid 124-07-2 = 10080 mg/kg ( Rat ) > 5 g/kg ( Rabbit ) - Dodecyl benzene sulfonic acid 27176-87-0 = 500 mg/kg ( Rat ) - - Sodium hydroxide 1310-73-2 - = 1350 mg/kg ( Rabbit ) - Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity Based on the information provided, this product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Numerical measures of toxicity Not determined BE-6014 - Buckeye Eco Muscle Cleaner Revision Date: 10-Feb-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 8 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects. Component Information Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Crustacea Benzyl alcohol 100-51-6 35: 3 h Anabaena variabilis mg/L EC50 460: 96 h Pimephales promelas mg/L LC50 static 10: 96 h Lepomis macrochirus mg/L LC50 static EC50 = 50 mg/L 5 min EC50 = 63.7 mg/L 15 min EC50 = 63.7 mg/L 5 min EC50 = 71.4 mg/L 30 min 23: 48 h water flea mg/L EC50 Phenoxyethanol 122-99-6 500: 72 h Desmodesmus subspicatus mg/L EC50 337 - 352: 96 h Pimephales promelas mg/L LC50 flow- through 366: 96 h Pimephales promelas mg/L LC50 static 220 - 460: 96 h Leuciscus idus mg/L LC50 static EC50 = 32.4 mg/L 5 min EC50 = 880 mg/L 17 h 500: 48 h Daphnia magna mg/L EC50 Octanoic Acid 124-07-2 310: 96 h Oryzias latipes mg/L LC50 semi-static 110: 96 h Brachydanio rerio mg/L LC50 semi-static 170: 24 h Daphnia magna mg/L EC50 Dodecyl benzene sulfonic acid 27176-87-0 29: 96 h Pseudokirchneriella subcapitata mg/L EC50 10.8: 96 h Oncorhynchus mykiss mg/L LC50 static 3.5 - 10: 96 h Brachydanio rerio mg/L LC50 static 5.88: 48 h Daphnia magna mg/L EC50 Sodium hydroxide 1310-73-2 45.4: 96 h Oncorhynchus mykiss mg/L LC50 static Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Partition Coefficient Benzyl alcohol 100-51-6 1.1 Phenoxyethanol 122-99-6 1.13 Octanoic Acid 124-07-2 2.92 Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. BE-6014 - Buckeye Eco Muscle Cleaner Revision Date: 10-Feb-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 8 California Hazardous Waste Status Chemical Name California Hazardous Waste Status Sodium hydroxide 1310-73-2 Toxic Corrosive 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (Octanoic acid, Sodium hydroxide) Hazard Class 8 Packing Group III IATA UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (Octanoic acid, Sodium hydroxide) Hazard Class 8 Packing Group III IMDG UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (Octanoic acid, Sodium hydroxide) Hazard Class 8 Packing Group III 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS Phenoxyethanol Present X Present Present X Present X X Benzyl alcohol Present X Present Present X Present X X Octanoic Acid Present X Present Present X Present X X Dodecyl benzene sulfonic acid Present X Present Present X Present X X Sodium hydroxide Present X Present Present X Present X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances BE-6014 - Buckeye Eco Muscle Cleaner Revision Date: 10-Feb-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 8 US Federal Regulations CERCLA Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Dodecyl benzene sulfonic acid 27176-87-0 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ Sodium hydroxide 1310-73-2 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ SARA 313 Chemical Name CAS No Weight-% SARA 313 - Threshold Values % Phenoxyethanol - 122-99-6 122-99-6 20 1.0 CWA (Clean Water Act) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Dodecyl benzene sulfonic acid 1000 lb X Sodium hydroxide 1000 lb X US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Benzyl alcohol 100-51-6 X X Phenoxyethanol 122-99-6 X X Dodecyl benzene sulfonic acid 27176-87-0 X X X Sodium hydroxide 1310-73-2 X X X 16. OTHER INFORMATION NFPA Health Hazards 2 Flammability 0 Instability 0 Special Hazards Not determined HMIS Health Hazards Not determined Flammability Not determined Physical Hazards Not determined Personal Protection Not determined Issue Date: 12-Nov-2012 Revision Date: 10-Feb-2015 Revision Note: New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet