HomeMy WebLinkAboutBuckeye ECO Neutral Disinfectant E23
Safety Data Sheet
Issue Date: 27-Dec-2011 Revision Date: 09-Jul-2015 Version 2
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1. IDENTIFICATION
Product Identifier
Product Name Buckeye Eco Neutral Disinfectant
Other means of identification
SDS # BE-6023
Product Code 6023
UN/ID No UN1760
Recommended use of the chemical and restrictions on use
Recommended Use Cleaner. Disinfectant. Waterbased.
Details of the supplier of the safety data sheet
Supplier Address
Buckeye International, Inc.
2700 Wagner Place
Maryland Heights, MO 63043 USA
Emergency Telephone Number
Company Phone Number 1-651-632-8956 (International)
1-800-303-0441 (North America)
Emergency Telephone (24 hr) INFOTRAC 1-352-323-3500 (International)
1-800-535-5053 (North America)
2. HAZARDS IDENTIFICATION
Appearance Clear green liquid Physical State Liquid Odor Clean and fresh fragrance
Classification
Skin corrosion/irritation Category 1 Sub-category C
Serious eye damage/eye irritation Category 1
Hazards Not Otherwise Classified (HNOC)
May be harmful if swallowed
Signal Word
Danger
Hazard Statements
Causes severe skin burns and eye damage
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Precautionary Statements - Prevention
Do not breathe dust/fume/gas/mist/vapors/spray
Wash face, hands and any exposed skin thoroughly after handling
Wear protective gloves/protective clothing/eye protection/face protection
Precautionary Statements - Response
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing
Immediately call a poison center or doctor/physician
IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower
Wash contaminated clothing before reuse
IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting
Precautionary Statements - Storage
Store locked up
Precautionary Statements - Disposal
Dispose of contents/container to an approved waste disposal plant
Other Hazards
Harmful to aquatic life with long lasting effects
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-%
Water 7732-18-5 >61.1
N,N-DIMETHYLOCTYLAMINE-N-OXIDE 2605-78-9 <10
Didecyldimethylammonium chloride 7173-51-5 10.14
Alkyl dimethyl benzyl ammonium chloride (C12-16) 68424-85-1 6.76
Tetrasodium EDTA 64-02-8 <5
Ethyl Alcohol 64-17-5 <4
Sodium hydroxide 1310-73-2 <2
**If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage
of composition has been withheld as a trade secret.**
4. FIRST-AID MEASURES
First Aid Measures
General Advice Call a poison center or doctor immediately for treatment advice.
Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Seek
immediate medical attention/advice.
Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Take off contaminated
clothing. Wash contaminated clothing before reuse.
Inhalation Remove to fresh air. If not breathing, give artificial respiration.
Ingestion Have person sip a glass of water if able to swallow. Do not induce vomiting without medical
advice. Never give anything by mouth to an unconscious person.
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Most important symptoms and effects
Symptoms Contact may cause irritation and redness. Direct eye contact may cause stinging, tearing
and redness. May cause redness, pain, and severe skin burns. May cause irritation to the
mucous membranes and upper respiratory tract. Ingestion may cause nausea and
headache.
Indication of any immediate medical attention and special treatment needed
Notes to Physician Treat symptomatically. If the product is ingested, probable mucosal damage may
contraindicate the use of gastric lavage. Measures against circulatory shock, respiratory
depression, and convulsions may be needed.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media
Water spray (fog). Dry powder. Foam.
Unsuitable Extinguishing Media Not determined.
Specific Hazards Arising from the Chemical
Toxic fumes may be given off when material is exposed to fire.
Hazardous Combustion Products Carbon oxides. Nitrogen oxides (NOx). Hydrogen chloride.
Protective equipment and precautions for firefighters
As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full
protective gear.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions, protective equipment and emergency procedures
Personal Precautions Use personal protective equipment as required.
Environmental Precautions Collect spillage.
Methods and material for containment and cleaning up
Methods for Containment Prevent further leakage or spillage if safe to do so.
Methods for Clean-Up Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clear water and allow
floor to dry before allowing traffic.
7. HANDLING AND STORAGE
Precautions for safe handling
Advice on Safe Handling Keep out of the reach of children. Use personal protection recommended in Section 8. Do
not breathe dust/fume/gas/mist/vapors/spray. Avoid release to the environment.
Conditions for safe storage, including any incompatibilities
Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Store at room
temperature. Keep container closed when not in use. Do not contaminate water, food, or
feed by storage or disposal.
Packaging Materials Rinse container before discarding.
Incompatible Materials Chlorine bleach. Anionic detergents. Strong oxidizing agents. Strong reducing agents.
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8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Exposure Guidelines
Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH
Ethyl Alcohol
64-17-5
STEL: 1000 ppm TWA: 1000 ppm
TWA: 1900 mg/m3
(vacated) TWA: 1000 ppm
(vacated) TWA: 1900 mg/m3
IDLH: 3300 ppm
TWA: 1000 ppm
TWA: 1900 mg/m3
Sodium hydroxide
1310-73-2
Ceiling: 2 mg/m3 TWA: 2 mg/m3
(vacated) Ceiling: 2 mg/m3
IDLH: 10 mg/m3
Ceiling: 2 mg/m3
Appropriate engineering controls
Engineering Controls Apply technical measures to comply with the occupational exposure limits.
Individual protection measures, such as personal protective equipment
Eye/Face Protection Splash goggles or safety glasses.
Skin and Body Protection Rubber gloves. Normal work clothing (long sleeved shirts and long pants) is recommended.
Respiratory Protection Refer to 29 CFR 1910.134 for respiratory protection requirements.
General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Wash hands
thoroughly after handling. Wash contaminated clothing before reuse.
9. PHYSICAL AND CHEMICAL PROPERTIES
Information on basic physical and chemical properties
Physical State Liquid
Appearance Clear green liquid Odor Clean and fresh fragrance
Color Green Odor Threshold Not determined
Property Values Remarks • Method
pH 7.6 ± 0.2 (conc)
7.0 ± 0.2 (1:256 dilution)
Melting Point/Freezing Point Not determined
Boiling Point/Boiling Range 100 °C / 212 °F
Flash Point ~ 93.3 °C / ~ 200 °F Tag Closed Cup
Evaporation Rate 1.0 (Water = 1)
Flammability (Solid, Gas) n/a-liquid
Upper Flammability Limits Not applicable
Lower Flammability Limit Not applicable
Vapor Pressure Not determined
Vapor Density Not determined
Specific Gravity 1.00
Water Solubility Infinite
Solubility in other solvents Not determined
Partition Coefficient Not determined
Auto-ignition Temperature Not determined
Decomposition Temperature Not determined Kinematic Viscosity Not determined
Dynamic Viscosity Not determined
Explosive Properties Not determined
Oxidizing Properties Not determined
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10. STABILITY AND REACTIVITY
Reactivity
Not reactive under normal conditions.
Chemical Stability
Stable under recommended storage conditions.
Possibility of Hazardous Reactions
None under normal processing.
Hazardous Polymerization Hazardous polymerization does not occur.
Conditions to Avoid
Keep out of reach of children.
Incompatible Materials
Chlorine bleach. Anionic detergents. Strong oxidizing agents. Strong reducing agents.
Hazardous Decomposition Products
Thermal decomposition can lead to release of irritating gases or vapors.
11. TOXICOLOGICAL INFORMATION
Information on likely routes of exposure
Product Information
Eye Contact Causes severe eye damage.
Skin Contact Causes severe skin burns.
Inhalation Avoid breathing vapors or mists.
Ingestion May be harmful if swallowed.
Component Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
Didecyldimethylammonium chloride
7173-51-5
= 84 mg/kg ( Rat ) - -
Alkyl dimethyl benzyl ammonium
chloride (C12-16)
68424-85-1
= 426 mg/kg ( Rat ) - -
Tetrasodium EDTA
64-02-8
= 1658 mg/kg ( Rat ) = 10 g/kg (
Rat )
- -
Ethyl Alcohol 64-17-5 = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h
Sodium hydroxide
1310-73-2
- = 1350 mg/kg ( Rabbit ) -
Information on physical, chemical and toxicological effects
Symptoms Please see section 4 of this SDS for symptoms.
Delayed and immediate effects as well as chronic effects from short and long-term exposure
Carcinogenicity Ethanol has been shown to be carcinogenic in long-term studies only when consumed as
an alcoholic beverage.
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Chemical Name ACGIH IARC NTP OSHA
Ethyl Alcohol
64-17-5
A3 Group 1 Known X
Legend ACGIH (American Conference of Governmental Industrial Hygienists)
A3 - Animal Carcinogen
IARC (International Agency for Research on Cancer)
Group 1 - Carcinogenic to Humans
NTP (National Toxicology Program)
Known - Known Carcinogen
OSHA (Occupational Safety and Health Administration of the US Department of Labor)
X - Present
Numerical measures of toxicity
Not determined
12. ECOLOGICAL INFORMATION
Ecotoxicity
Harmful to aquatic life with long lasting effects.
Chemical Name Algae/aquatic plants Fish Toxicity to
microorganisms
Crustacea
Tetrasodium EDTA
64-02-8
1.01: 72 h Desmodesmus
subspicatus mg/L EC50
41: 96 h Lepomis
macrochirus mg/L LC50
static 59.8: 96 h Pimephales
promelas mg/L LC50 static
610: 24 h Daphnia magna
mg/L EC50
Ethyl Alcohol
64-17-5 12.0 - 16.0: 96 h
Oncorhynchus mykiss mL/L
LC50 static 13400 - 15100:
96 h Pimephales promelas
mg/L LC50 flow-through 100:
96 h Pimephales promelas
mg/L LC50 static
9268 - 14221: 48 h Daphnia
magna mg/L LC50 2: 48 h
Daphnia magna mg/L EC50
Static 10800: 24 h Daphnia
magna mg/L EC50
Sodium hydroxide
1310-73-2 45.4: 96 h Oncorhynchus
mykiss mg/L LC50 static
Persistence/Degradability
Not determined.
Bioaccumulation
Not determined.
Mobility
Chemical Name Partition Coefficient
Ethyl Alcohol
64-17-5
-0.32
Other Adverse Effects
Not determined
13. DISPOSAL CONSIDERATIONS
Waste Treatment Methods
Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and
regulations.
Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and
regulations.
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California Hazardous Waste Status
Chemical Name California Hazardous Waste Status
Ethyl Alcohol
64-17-5
Toxic
Ignitable
Sodium hydroxide
1310-73-2
Toxic
Corrosive
14. TRANSPORT INFORMATION
Note Please see current shipping paper for most up to date shipping information, including
exemptions and special circumstances.
DOT
UN/ID No UN1760
Proper Shipping Name Corrosive liquid, n.o.s. (Dimethyl benzyl ammonium chloride, Sodium hydroxide)
Hazard Class 8
Packing Group III
IATA
UN/ID No UN1760
Proper Shipping Name Corrosive liquid, n.o.s. (Dimethyl benzyl ammonium chloride, Sodium hydroxide)
Hazard Class 8
Packing Group III
IMDG
UN/ID No UN1760
Proper Shipping Name Corrosive liquid, n.o.s. (Dimethyl benzyl ammonium chloride, Sodium hydroxide)
Hazard Class 8
Packing Group III
Marine Pollutant This material may meet the definition of a marine pollutant
15. REGULATORY INFORMATION
International Inventories
Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS
Water Present X Present X Present X X
N,N-
DIMETHYLOCTYLAMINE-N-
OXIDE
Present X Present X X
Didecyldimethylammonium chloride Present X Present Present X Present X X
Alkyl dimethyl benzyl
ammonium chloride (C12-16)
Present X Present Present X Present X X
Tetrasodium EDTA Present X Present Present X Present X X
Ethyl Alcohol Present X Present Present X Present X X
Sodium hydroxide Present X Present Present X Present X X
Legend:
TSCA - United States Toxic Substances Control Act Section 8(b) Inventory
DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List
EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances
ENCS - Japan Existing and New Chemical Substances
IECSC - China Inventory of Existing Chemical Substances
KECL - Korean Existing and Evaluated Chemical Substances
PICCS - Philippines Inventory of Chemicals and Chemical Substances
AICS - Australian Inventory of Chemical Substances
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US Federal Regulations
CERCLA
Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ)
Sodium hydroxide
1310-73-2
1000 lb RQ 1000 lb final RQ
RQ 454 kg final RQ
SARA 311/312 Hazard Categories
Acute Health Hazard Yes
SARA 313
Not determined
CWA (Clean Water Act)
Chemical Name CWA - Reportable
Quantities
CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous
Substances
Sodium hydroxide 1000 lb X
US State Regulations
California Proposition 65
This product contains the following Proposition 65 chemicals.
Chemical Name California Proposition 65
Ethyl Alcohol - 64-17-5 Carcinogen Developmental
U.S. State Right-to-Know Regulations
Chemical Name New Jersey Massachusetts Pennsylvania
Ethyl Alcohol
64-17-5
X X X
Sodium hydroxide
1310-73-2
X X X
16. OTHER INFORMATION
NFPA Health Hazards
3
Flammability
1
Instability
0
Special Hazards
Not determined
HMIS Health Hazards
Not determined
Flammability
Not determined
Physical Hazards
Not determined
Personal Protection
Not determined
Issue Date: 27-Dec-2011
Revision Date: 09-Jul-2015
Revision Note: New format
Disclaimer
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,
transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
End of Safety Data Sheet