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HomeMy WebLinkAboutBuckeye ECO Sanitizer E62 Safety Data Sheet Issue Date: 18-Aug-2014 Revision Date: 22-Sep-2015 Version 1 _____________________________________________________________________________________________ Page 1 / 8 1. IDENTIFICATION Product Identifier Product Name Buckeye ECO Sanitizer #6062 Other means of identification SDS # BE-6062 Product Code 6062 UN/ID No UN1903 Recommended use of the chemical and restrictions on use Recommended Use Disinfectant. Sanitizer. Details of the supplier of the safety data sheet Emergency Telephone Number Emergency Telephone (24 hr) INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance Clear liquid Physical State Liquid Odor Mild scent No fragrance added Classification Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Signal Word Danger Hazard Statements Causes skin irritation Causes serious eye damage Precautionary Statements - Prevention Wash face, hands and any exposed skin thoroughly after handling Wear eye/face protection Wear protective gloves BE-6062 - Buckeye ECO Sanitizer #6062 Revision Date: 22-Sep-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 8 Precautionary Statements - Response If exposed or concerned: Get medical advice/attention IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN: Wash with plenty of soap and water If skin irritation occurs: Get medical advice/attention Take off contaminated clothing and wash it before reuse Other Hazards Toxic to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Alkyl dimethyl benzyl ammonium chloride (C12-16) 68424-85-1 4.0 Octyl decyl dimethyl ammonium chloride 32426-11-2 3.0 Didecyldimethylammonium chloride 7173-51-5 1.8 Dioctyl dimethyl ammonium chloride 5538-94-3 1.2 Ethyl Alcohol 64-17-5 <2 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST-AID MEASURES First Aid Measures General Advice Call a poison center or doctor immediately for treatment advice. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Get medical attention immediately. Skin Contact Take off contaminated clothing. Wash off immediately with plenty of water for at least 15 minutes. If redness or irritation occurs and persists, seek medical attention. Inhalation Remove to fresh air. If breathing is difficult, give oxygen. If not breathing, give artificial respiration. Seek medical attention for further treatment. Ingestion Have person sip a glass of water if able to swallow. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. Get medical attention to assess further treatment. Most important symptoms and effects Symptoms May cause eye burns and permanent eye damage. Nausea. Headache. Direct contact with skin can cause irritation or redness. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. If the product is ingested, probable mucosal damage may contraindicate the use of gastric lavage. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Foam. Water spray (fog). Dry chemical. Unsuitable Extinguishing Media Not determined. BE-6062 - Buckeye ECO Sanitizer #6062 Revision Date: 22-Sep-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 8 Specific Hazards Arising from the Chemical Combustion products may be toxic. Thermal decomposition can lead to release of irritating and toxic gases and vapors. Hazardous Combustion Products Carbon oxides. Nitrogen oxides (NOx). Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental Precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clear water and allow floor to dry before allowing traffic. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Wear eye/face protection. Wear protective gloves. Wash face, hands, and any exposed skin thoroughly after handling. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep container closed when not in use. Store at room temperature. Protect from direct sunlight. Protect from extreme temperatures. Packaging Materials Rinse container before discarding. Incompatible Materials Chlorine bleach. Anionic detergents. Strong oxidizing agents. Strong reducing agents. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Ethyl Alcohol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm TWA: 1000 ppm TWA: 1900 mg/m3 Appropriate engineering controls Engineering Controls Apply technical measures to comply with the occupational exposure limits. Showers. Eyewash stations. Ventilation systems. BE-6062 - Buckeye ECO Sanitizer #6062 Revision Date: 22-Sep-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 8 Individual protection measures, such as personal protective equipment Eye/Face Protection Refer to 29 CFR 1910.133 for eye and face protection regulations. Wear safety glasses or goggles to protect against exposure. Skin and Body Protection Refer to 29 CFR 1910.138 for appropriate skin and body protection. Wear rubber gloves or other impervious gloves. Respiratory Protection Refer to 29 CFR 1910.134 for respiratory protection requirements. No protective equipment is needed under normal use conditions. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Wash hands thoroughly after handling. Wash contaminated clothing before reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Liquid Appearance Clear liquid Odor Mild scent No fragrance added Color Clear Odor Threshold Not determined Property Values Remarks • Method pH 7.0 ± 0.5 (conc) 7.0 ± 0.5 (1:128 dilution) Melting Point/Freezing Point Not determined Boiling Point/Boiling Range 100 °C / 212 °F Flash Point > 65 °C / > 149 °F Pensky-Martens Closed Cup (PMCC) Evaporation Rate 1.0 (Water = 1) Flammability (Solid, Gas) n/a-liquid Upper Flammability Limits Not applicable Lower Flammability Limit Not applicable Vapor Pressure Not determined Vapor Density Not determined Specific Gravity 0.99 Water Solubility Infinite Solubility in other solvents Not determined Partition Coefficient Not determined Auto-ignition Temperature Not determined Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. BE-6062 - Buckeye ECO Sanitizer #6062 Revision Date: 22-Sep-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 8 Conditions to Avoid See Sec. 7 Handling & Storage. Incompatible Materials Chlorine bleach. Anionic detergents. Strong oxidizing agents. Strong reducing agents. Hazardous Decomposition Products Carbon oxides. Nitrogen oxides (NOx). Thermal decomposition can lead to release of irritating and toxic gases and vapors. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Causes serious eye damage. Skin Contact Causes skin irritation. Inhalation Do not inhale. Ingestion Do not ingest. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Alkyl dimethyl benzyl ammonium chloride (C12-16) 68424-85-1 = 426 mg/kg ( Rat ) - - Ethyl Alcohol 64-17-5 = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye irritation Causes serious eye damage. Carcinogenicity Ethanol has been shown to be carcinogenic in long-term studies only when consumed as an alcoholic beverage. Chemical Name ACGIH IARC NTP OSHA Ethyl Alcohol 64-17-5 A3 Group 1 Known X Legend ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Numerical measures of toxicity Not determined BE-6062 - Buckeye ECO Sanitizer #6062 Revision Date: 22-Sep-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 8 12. ECOLOGICAL INFORMATION Ecotoxicity Toxic to aquatic life with long lasting effects. Component Information Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Crustacea Ethyl Alcohol 64-17-5 12.0 - 16.0: 96 h Oncorhynchus mykiss mL/L LC50 static 13400 - 15100: 96 h Pimephales promelas mg/L LC50 flow-through 100: 96 h Pimephales promelas mg/L LC50 static EC50 = 34634 mg/L 30 min EC50 = 35470 mg/L 5 min 9268 - 14221: 48 h Daphnia magna mg/L LC50 2: 48 h Daphnia magna mg/L EC50 Static 10800: 24 h Daphnia magna mg/L EC50 Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Chemical Name Partition Coefficient Ethyl Alcohol 64-17-5 -0.32 Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status Chemical Name California Hazardous Waste Status Ethyl Alcohol 64-17-5 Toxic Ignitable 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT UN/ID No UN1903 Proper Shipping Name Disinfectant, liquid, corrosive, n.o.s. (Dialkyldimethylammonium chloride) Hazard Class 8 Packing Group III BE-6062 - Buckeye ECO Sanitizer #6062 Revision Date: 22-Sep-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 8 IATA UN/ID No UN1903 Proper Shipping Name Disinfectant, liquid, corrosive, n.o.s. (Dialkyldimethylammonium chloride) Hazard Class 8 Packing Group III IMDG UN/ID No UN1903 Proper Shipping Name Disinfectant, liquid, corrosive, n.o.s. (Dialkyldimethylammonium chloride) Hazard Class 8 Packing Group III 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS Alkyl dimethyl benzyl ammonium chloride (C12-16) Present X Present Present X Present X X Ethyl Alcohol Present X Present Present X Present X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) US State Regulations California Proposition 65 Ethyl alcohol is only considered a Proposition 65 developmental hazard when it is ingested as an alcoholic beverage. Chemical Name California Proposition 65 Ethyl Alcohol - 64-17-5 Carcinogen Developmental BE-6062 - Buckeye ECO Sanitizer #6062 Revision Date: 22-Sep-2015 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 8 U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Ethyl Alcohol 64-17-5 X X X 16. OTHER INFORMATION NFPA Health Hazards 3 Flammability 2 Instability 0 Special Hazards Not determined HMIS Health Hazards Not determined Flammability Not determined Physical Hazards Not determined Personal Protection Not determined Issue Date: 18-Aug-2014 Revision Date: 22-Sep-2015 Revision Note: New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet