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Home My WebLink AboutBuckeye RipSaw 5025 Stripper Safety Data Sheet Issue Date: 27-Dec-2011 Revision Date: 28-May-2013 Version 1 _____________________________________________________________________________________________ Page 1 / 9 1. IDENTIFICATION Product Identifier Product Name Buckeye Ripsaw Other means of identification SDS # BE-002 Product Code 5025 UN/ID No UN1760 Recommended use of the chemical and restrictions on use Recommended Use Floor finish stripper, water based. Details of the supplier of the safety data sheet Supplier Address Buckeye International, Inc. 2700 Wagner Place Maryland Heights, MO 63043 USA Emergency Telephone Number Company Phone Number 314-291-1900 24 Hr Medical Emergency Phone: 1-800-303-0441 651-632-8956 Emergency Telephone (24 hr) INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance Water clear liquid Physical State Liquid Odor Mild No fragrance added Classification Skin corrosion/irritation Category 1 Sub-category B Serious eye damage/eye irritation Category 1 Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed Signal Word Danger Hazard Statements Causes severe skin burns and eye damage BE-002 - Buckeye Ripsaw Revision Date: 28-May-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 9 Precautionary Statements - Prevention Do not breathe dust/fume/gas/mist/vapors/spray Wash face, hands and any exposed skin thoroughly after handling Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower Wash contaminated clothing before reuse IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Immediately call a poison center or doctor/physician IF SWALLOWED: rinse mouth. Do NOT induce vomiting Precautionary Statements - Storage Store locked up Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other Hazards Harmful to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Water 7732-18-5 >56.9 Benzyl alcohol 100-51-6 <15.0 Ethylene glycol monophenyl ether 122-99-6 <10.0 Ethanolamine 141-43-5 5 Octanoic Acid 124-07-2 <5.0 Sodium xylenesulfonate 1300-72-7 <4.0 Sodium metasilicate 6834-92-0 2 Sodium hydroxide 1310-73-2 1.1 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST-AID MEASURES First Aid Measures Eye Contact Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Seek immediate medical attention/advice. Skin Contact Wash off immediately with plenty of water for at least 15 minutes. Take off contaminated clothing. Wash contaminated clothing before reuse. Get medical attention if irritation develops or persists. BE-002 - Buckeye Ripsaw Revision Date: 28-May-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 9 Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention immediately. Ingestion Drink 1 or 2 glasses of water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a physician or poison control center immediately. Most important symptoms and effects Symptoms May cause redness, pain, and severe skin burns. Nausea. Headache. May cause skin irritation and defatting of skin with repeated/prolonged contact. Eye contact may cause redness or burning sensation. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. Dermatitis or other pre-existing skin conditions may be aggravated by overexposure to this product. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Toxic products of combustion. Hazardous Combustion Products Oxides of sulfur. Carbon oxides. Nitrogen oxides (NOx). Silicon oxides. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protective equipment as required. Environmental Precautions See Section 12 for additional Ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Pick up with mop, wet/dry vac, or absorbent material. Rinse area with clear water and allow floor to dry before allowing traffic. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Do not breathe dust/fume/gas/mist/vapors/spray. Wash face, hands, and any exposed skin thoroughly after handling. Use personal protection recommended in Section 8. Keep out of the reach of children. BE-002 - Buckeye Ripsaw Revision Date: 28-May-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 9 Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Store locked up. Store at room temperature. Store away from incompatible materials. Store on low shelves. Incompatible Materials Chlorine bleach. Acids. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Ethanolamine 141-43-5 STEL: 6 ppm TWA: 3 ppm TWA: 3 ppm TWA: 6 mg/m3 (vacated) TWA: 3 ppm (vacated) TWA: 8 mg/m3 (vacated) STEL: 6 ppm (vacated) STEL: 15 mg/m3 IDLH: 30 ppm TWA: 3 ppm TWA: 8 mg/m3 STEL: 6 ppm STEL: 15 mg/m3 Sodium metasilicate 6834-92-0 2 mg/m3 2 mg/m3 - Sodium hydroxide 1310-73-2 Ceiling: 2 mg/m3 TWA: 2 mg/m3 (vacated) Ceiling: 2 mg/m3 IDLH: 10 mg/m3 Ceiling: 2 mg/m3 Appropriate engineering controls Engineering Controls Apply technical measures to comply with the occupational exposure limits. Individual protection measures, such as personal protective equipment Eye/Face Protection Risk of contact: Wear approved safety goggles. Skin and Body Protection Rubber gloves or other impervious gloves. Normal work clothing (long sleeved shirts and long pants) is recommended. Wear water or chemical resistant footwear when scrubbing floors. Respiratory Protection No protection is ordinarily required under normal conditions of use and with adequate ventilation. General Hygiene Considerations Wash contaminated clothing before reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Liquid Appearance Water clear liquid Odor Mild No fragrance added Color Water clear Odor Threshold Not determined Property Values Remarks • Method pH 12.6±0.3 1:4 dilution with DI water 12.3±0.2 Melting Point/Freezing Point Not determined Boiling Point/Boiling Range 100 °C / 212 °F Flash Point None Evaporation Rate 1.0 (Water = 1) Flammability (Solid, Gas) n/a-liquid Upper Flammability Limits Not applicable Lower Flammability Limit Not applicable Vapor Pressure Not determined Vapor Density Not determined Specific Gravity 1.06 Water Solubility Infinite BE-002 - Buckeye Ripsaw Revision Date: 28-May-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 9 Solubility in other solvents Not determined Partition Coefficient Not determined Auto-ignition Temperature Not determined Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid Contact with incompatible materials. Incompatible Materials Chlorine bleach. Acids. Hazardous Decomposition Products None known. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Causes severe eye damage. Skin Contact Causes severe skin burns. Inhalation Avoid breathing vapors or mists. Ingestion May be harmful if swallowed. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Benzyl alcohol 100-51-6 = 1230 mg/kg ( Rat ) = 2000 mg/kg ( Rabbit ) = 8.8 mg/L ( Rat ) 4 h Ethylene glycol monophenyl ether 122-99-6 = 1260 mg/kg ( Rat ) = 5 mL/kg ( Rabbit ) = 14422 mg/kg ( Rat ) - Ethanolamine 141-43-5 = 1720 mg/kg ( Rat ) = 1 mL/kg ( Rabbit ) = 1025 mg/kg ( Rabbit ) - Octanoic Acid 124-07-2 = 10080 mg/kg ( Rat ) > 5 g/kg ( Rabbit ) - Sodium xylenesulfonate 1300-72-7 = 7200 mg/kg ( Rat ) - - Sodium metasilicate 6834-92-0 = 600 mg/kg ( Rat ) - - BE-002 - Buckeye Ripsaw Revision Date: 28-May-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 9 Sodium hydroxide 1310-73-2 - = 1350 mg/kg ( Rabbit ) - Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Numerical measures of toxicity Not determined 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects. Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Crustacea Benzyl alcohol 100-51-6 35: 3 h Anabaena variabilis mg/L EC50 460: 96 h Pimephales promelas mg/L LC50 static 10: 96 h Lepomis macrochirus mg/L LC50 static EC50 = 50 mg/L 5 min EC50 = 63.7 mg/L 15 min EC50 = 63.7 mg/L 5 min EC50 = 71.4 mg/L 30 min 23: 48 h water flea mg/L EC50 Ethylene glycol monophenyl ether 122-99-6 500: 72 h Desmodesmus subspicatus mg/L EC50 337 - 352: 96 h Pimephales promelas mg/L LC50 flow-through 366: 96 h Pimephales promelas mg/L LC50 static 220 - 460: 96 h Leuciscus idus mg/L LC50 static EC50 = 32.4 mg/L 5 min EC50 = 880 mg/L 17 h 500: 48 h Daphnia magna mg/L EC50 Ethanolamine 141-43-5 15: 72 h Desmodesmus subspicatus mg/L EC50 227: 96 h Pimephales promelas mg/L LC50 flow-through 3684: 96 h Brachydanio rerio mg/L LC50 static 300 - 1000: 96 h Lepomis macrochirus mg/L LC50 static 114 - 196: 96 h Oncorhynchus mykiss mg/L LC50 static 200: 96 h Oncorhynchus mykiss mg/L LC50 flow-through EC50 = 110 mg/L 17 h EC50 = 12200 mg/L 2 h EC50 = 13.7 mg/L 30 min 65: 48 h Daphnia magna mg/L EC50 Octanoic Acid 124-07-2 310: 96 h Oryzias latipes mg/L LC50 semi-static 110: 96 h Brachydanio rerio mg/L LC50 semi-static 170: 24 h Daphnia magna mg/L EC50 Sodium metasilicate 6834-92-0 210: 96 h Brachydanio rerio mg/L LC50 semi-static 210: 96 h Brachydanio rerio mg/L LC50 216: 96 h Daphnia magna mg/L EC50 Sodium hydroxide 1310-73-2 45.4: 96 h Oncorhynchus mykiss mg/L LC50 static Persistence/Degradability Not determined. Bioaccumulation Not determined. BE-002 - Buckeye Ripsaw Revision Date: 28-May-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 9 Mobility Chemical Name Partition Coefficient Benzyl alcohol 100-51-6 1.1 Ethylene glycol monophenyl ether 122-99-6 1.13 Ethanolamine 141-43-5 -1.91 Octanoic Acid 124-07-2 2.92 Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status This product contains one or more substances that are listed with the State of California as a hazardous waste Chemical Name California Hazardous Waste Status Sodium hydroxide 1310-73-2 Toxic Corrosive 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (Ethanolamine, Sodium hydroxide) Hazard Class 8 Packing Group II IATA UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (Ethanolamine, Sodium hydroxide) Hazard Class 8 Packing Group II IMDG UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (Ethanolamine, Sodium hydroxide) Hazard Class 8 Packing Group II BE-002 - Buckeye Ripsaw Revision Date: 28-May-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 9 15. REGULATORY INFORMATION International Inventories Not determined Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Sodium hydroxide 1310-73-2 1000 lb RQ 1000 lb final RQ RQ 454 kg final RQ SARA 313 Chemical Name CAS No Weight-% SARA 313 - Threshold Values % Ethylene glycol monophenyl ether - 122-99-6 122-99-6 <10.0 1.0 CWA (Clean Water Act) Component CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Sodium hydroxide 1310-73-2 ( 1.1 ) 1000 lb X US State Regulations U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Benzyl alcohol 100-51-6 X X Ethylene glycol monophenyl ether 122-99-6 X X Ethanolamine 141-43-5 X X X Sodium hydroxide 1310-73-2 X X X BE-002 - Buckeye Ripsaw Revision Date: 28-May-2013 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 9 / 9 16. OTHER INFORMATION NFPA Health Hazards 3 Flammability 0 Instability 0 Special Hazards Not determined HMIS Health Hazards Not determined Flammability Not determined Physical Hazards Not determined Personal Protection Not determined Issue Date: 27-Dec-2011 Revision Date: 28-May-2013 Revision Note: New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet