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Home My WebLink AboutBuckeye Sparkle Safety Data Sheet Issue Date: 27-Dec-2011 Revision Date: 26-Nov-2014 Version 1 _____________________________________________________________________________________________ Page 1 / 8 1. IDENTIFICATION Product Identifier Product Name Buckeye Sparkle Other means of identification SDS # BE-5260 Product Code 5260 UN/ID No UN1760 Recommended use of the chemical and restrictions on use Recommended Use General Purpose Acid Cleaner, Water Based. Details of the supplier of the safety data sheet Supplier Address Buckeye International, Inc. 2700 Wagner Place Maryland Heights, MO 63043 USA Emergency Telephone Number Company Phone Number 1-651-632-8956 (International) 1-800-303-0441 (North America) Emergency Telephone (24 hr) INFOTRAC 1-352-323-3500 (International) 1-800-535-5053 (North America) 2. HAZARDS IDENTIFICATION Appearance Clear purple solution Physical State Liquid Odor Floral Classification Per 29 CFR 1910.1200, this product has received further evaluation from the manufacturer. The test results provided are reflected in the classification below. Acute toxicity - Inhalation (Dusts/Mists) Category 4 Serious eye damage/eye irritation Category 1 Hazards Not Otherwise Classified (HNOC) May be harmful if swallowed Signal Word Danger Hazard Statements Harmful if inhaled Causes serious eye damage BE-5260 - Buckeye Sparkle Revision Date: 26-Nov-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 8 Precautionary Statements - Prevention Avoid breathing dust/fume/gas/mist/vapors/spray Use only outdoors or in a well-ventilated area Wear protective gloves/protective clothing/eye protection/face protection Precautionary Statements - Response IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing Immediately call a poison center or doctor/physician IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing Call a poison center or doctor/physician if you feel unwell Other Hazards Toxic to aquatic life with long lasting effects 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No Weight-% Phosphoric acid 7664-38-2 36.3 **If Chemical Name/CAS No is "proprietary" and/or Weight-% is listed as a range, the specific chemical identity and/or percentage of composition has been withheld as a trade secret.** 4. FIRST-AID MEASURES First Aid Measures Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Call a physician immediately. Skin Contact Wash area with soap and water. If skin irritation persists, call a physician. Inhalation IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Get medical attention if you feel unwell. Ingestion Drink 2-3 large glasses of water. Do not induce vomiting. Call a physician. Never give anything by mouth to an unconscious person. Most important symptoms and effects Symptoms Contact will cause irritation and redness to exposed areas. May cause redness, pain, and severe skin burns. May cause severe irritation with redness, pain, and blurred vision. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. BE-5260 - Buckeye Sparkle Revision Date: 26-Nov-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 8 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media Not determined. Specific Hazards Arising from the Chemical Combustion products may be toxic. Hazardous Combustion Products Carbon oxides. Phosphorus oxides. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Use personal protection recommended in Section 8. Environmental Precautions Prevent from entering into soil, ditches, sewers, waterways and/or groundwater. See Section 12, Ecological Information. See Section 13: DISPOSAL CONSIDERATIONS. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Clean-Up Dilute with large amounts of water. Pick up with mops into a plastic bucket. Wash area with an alkaline detergent, followed by a clear water rinse. Allow floor to dry before allowing traffic. 7. HANDLING AND STORAGE Precautions for safe handling Advice on Safe Handling Handle in accordance with good industrial hygiene and safety practice. Use personal protection recommended in Section 8. Avoid contact with skin, eyes or clothing. Wash face, hands, and any exposed skin thoroughly after handling. Do not breathe dust/fume/gas/mist/vapors/spray. Use only in well-ventilated areas. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep container closed when not in use. Store on low shelves. Store away from incompatible materials. Store at room temperature. Packaging Materials Rinse container before discarding. Incompatible Materials Chlorine bleach. Caustics. Alkalis. BE-5260 - Buckeye Sparkle Revision Date: 26-Nov-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 8 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Phosphoric acid 7664-38-2 STEL: 3 mg/m3 TWA: 1 mg/m3 TWA: 1 mg/m3 (vacated) TWA: 1 mg/m3 (vacated) STEL: 3 mg/m3 IDLH: 1000 mg/m3 TWA: 1 mg/m3 STEL: 3 mg/m3 Appropriate engineering controls Engineering Controls Ensure adequate ventilation, especially in confined areas. Eyewash stations. Showers. Individual protection measures, such as personal protective equipment Eye/Face Protection Splash goggles or safety glasses. Skin and Body Protection Wear suitable protective clothing. Respiratory Protection Ensure adequate ventilation, especially in confined areas. General Hygiene Considerations Handle in accordance with good industrial hygiene and safety practice. Wash hands thoroughly after handling. Wash contaminated clothing before reuse. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical State Liquid Appearance Clear purple solution Odor Floral Color Clear purple Odor Threshold Not determined Property Values Remarks • Method pH <1.0 (conc) 1.9 ± 0.2 (1:128 dilution) Melting Point/Freezing Point Not determined Boiling Point/Boiling Range 100 °C / 212 °F Flash Point None Tag Closed Cup Evaporation Rate 1.0 (Water = 1) Flammability (Solid, Gas) Liquid-Not applicable Upper Flammability Limits Not applicable Lower Flammability Limit Not applicable Vapor Pressure Not determined Vapor Density Not determined Specific Gravity 1.23 Water Solubility Infinite Solubility in other solvents Not determined Partition Coefficient Not determined Auto-ignition Temperature Not determined Decomposition Temperature Not determined Kinematic Viscosity Not determined Dynamic Viscosity Not determined Explosive Properties Not determined Oxidizing Properties Not determined BE-5260 - Buckeye Sparkle Revision Date: 26-Nov-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 8 10. STABILITY AND REACTIVITY Reactivity Not reactive under normal conditions. Chemical Stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to Avoid Keep separated from incompatible substances. Keep out of reach of children. Avoid contact with ferrous metals and Formica. Incompatible Materials Chlorine bleach. Caustics. Alkalis. Hazardous Decomposition Products Carbon oxides. Phosphorous oxides. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information Eye Contact Causes serious eye damage. Skin Contact Avoid contact with skin. Inhalation Harmful if inhaled. Ingestion May be harmful if swallowed. Component Information Chemical Name Oral LD50 Dermal LD50 Inhalation LC50 Phosphoric acid 7664-38-2 = 1530 mg/kg ( Rat ) = 2730 mg/kg ( Rabbit ) > 850 mg/m3 ( Rat ) 1 h Information on physical, chemical and toxicological effects Symptoms Please see section 4 of this SDS for symptoms. Delayed and immediate effects as well as chronic effects from short and long-term exposure Carcinogenicity This product does not contain any carcinogens or potential carcinogens as listed by OSHA, IARC or NTP. Numerical measures of toxicity Not determined 12. ECOLOGICAL INFORMATION Ecotoxicity Toxic to aquatic life with long lasting effects. BE-5260 - Buckeye Sparkle Revision Date: 26-Nov-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 8 Component Information Chemical Name Algae/aquatic plants Fish Toxicity to microorganisms Crustacea Phosphoric acid 7664-38-2 3 - 3.5: 96 h Gambusia affinis mg/L LC50 4.6: 12 h Daphnia magna mg/L EC50 Persistence/Degradability Not determined. Bioaccumulation Not determined. Mobility Not determined Other Adverse Effects Not determined 13. DISPOSAL CONSIDERATIONS Waste Treatment Methods Disposal of Wastes Disposal should be in accordance with applicable regional, national and local laws and regulations. Contaminated Packaging Disposal should be in accordance with applicable regional, national and local laws and regulations. California Hazardous Waste Status Chemical Name California Hazardous Waste Status Phosphoric acid 7664-38-2 Corrosive 14. TRANSPORT INFORMATION Note Please see current shipping paper for most up to date shipping information, including exemptions and special circumstances. DOT UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (Phosphoric acid) Hazard Class 8 Packing Group III IATA UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (Phosphoric acid) Hazard Class 8 Packing Group III IMDG UN/ID No UN1760 Proper Shipping Name Corrosive liquid, n.o.s. (Phosphoric acid) Hazard Class 8 Packing Group III BE-5260 - Buckeye Sparkle Revision Date: 26-Nov-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 8 15. REGULATORY INFORMATION International Inventories Chemical Name TSCA DSL NDSL EINECS ELINCS ENCS IECSC KECL PICCS AICS Phosphoric acid Present X Present Present X Present X X Legend: TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances IECSC - China Inventory of Existing Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations CERCLA Chemical Name Hazardous Substances RQs CERCLA/SARA RQ Reportable Quantity (RQ) Phosphoric acid 7664-38-2 5000 lb RQ 5000 lb final RQ RQ 2270 kg final RQ SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 CWA (Clean Water Act) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Phosphoric acid 5000 lb X US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Phosphoric acid 7664-38-2 X X X BE-5260 - Buckeye Sparkle Revision Date: 26-Nov-2014 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 8 16. OTHER INFORMATION NFPA Health Hazards 3 Flammability 0 Instability 0 Special Hazards Not determined HMIS Health Hazards Not determined Flammability Not determined Physical Hazards Not determined Personal Protection Not determined Issue Date: 27-Dec-2011 Revision Date: 26-Nov-2014 Revision Note: New format Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet