HomeMy WebLinkAboutClaire Chalkkboard CleanerSAFETY DATA SHEET
1. Identification
Product number 1000006466
Product identifier CHALKBOARD CLEANER
Company information Claire Manufacturing Co.
1005 S. Westgate Drive
Addison, IL 60101 United States
Company phone General Assistance 1-630-543-7600
Emergency telephone US 1-866-836-8855
Emergency telephone outside
US
1-952-852-4646
Version #01
Recommended use cleaner
Recommended restrictions None known.
2. Hazard(s) identification
Liquefied gasGases under pressurePhysical hazards
Not classified.Health hazards
Not classified.Environmental hazards
Not classified.OSHA defined hazards
Label elements
Signal word Warning
Hazard statement Contains gas under pressure; may explode if heated.
Precautionary statement
Prevention Observe good industrial hygiene practices.
Response Wash hands after handling.
Storage Protect from sunlight. Store in a well-ventilated place.
Disposal Dispose of waste and residues in accordance with local authority requirements.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
111-76-22-Butoxyethanol 2.5 - 10
64-17-5Ethyl Alcohol 2.5 - 10
106-97-8Butane 1 - 2.5
74-98-6Propane
Other components below reportable levels 90 - 100
1 - 2.5
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation Move to fresh air. Get medical attention if symptoms persist.
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Skin contact Get medical attention if irritation develops and persists.
Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses.
Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth.
Most important
symptoms/effects, acute and
delayed
Direct contact with eyes may cause temporary irritation.
Indication of immediate
medical attention and special
treatment needed
Provide general supportive measures and treat symptomatically.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing
media
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from
the chemical
Contents under pressure. During fire, gases hazardous to health may be formed.
Special protective equipment
and precautions for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Fire-fighting
equipment/instructions
In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed
to heat. Move containers from fire area if you can do so without risk. Cool containers exposed to
heat with water spray and remove container, if no risk is involved. Containers should be cooled
with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose
holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Wear appropriate protective equipment and clothing during clean-up. Emergency
personnel need self-contained breathing equipment. Do not touch damaged containers or spilled
material unless wearing appropriate protective clothing. Ventilate closed spaces before entering
them. Local authorities should be advised if significant spillages cannot be contained. See Section
8 of the SDS for Personal Protective Equipment. For personal protection, see section 8 of the
SDS.
Methods and materials for
containment and cleaning up
Refer to attached safety data sheets and/or instructions for use. Eliminate all ignition sources (no
smoking, flares, sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.)
away from spilled material. Stop leak if you can do so without risk. Move the cylinder to a safe and
open area if the leak is irreparable. Isolate area until gas has dispersed. Prevent entry into
waterways, sewer, basements or confined areas. Wipe up with absorbent material (e.g. cloth,
fleece). Clean surface thoroughly to remove residual contamination. For waste disposal, see
section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing
or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke
while using or until sprayed surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or
expose containers to heat, flame, sparks, or other sources of ignition. Ground and bond containers
when transferring material. Do not re-use empty containers. Do not get in eyes, on skin, or on
clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal
protective equipment. Observe good industrial hygiene practices.
Conditions for safe storage,
including any incompatibilities
Level 1 Aerosol.
Pressurized container. Protect from sunlight and do not expose to temperatures exceeding
50°C/122 °F. Do not puncture, incinerate or crush. Do not handle or store near an open flame,
heat or other sources of ignition. Keep containers tightly closed in a dry, cool and well-ventilated
place. Refrigeration recommended. Store away from incompatible materials (see Section 10 of the
SDS).
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8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents Type
PEL 240 mg/m32-Butoxyethanol (CAS
111-76-2)
50 ppm
PEL 1900 mg/m3Ethyl Alcohol (CAS 64-17-5)
1000 ppm
PEL 1800 mg/m3Propane (CAS 74-98-6)
1000 ppm
US. ACGIH Threshold Limit Values
ValueComponents Type
TWA 20 ppm2-Butoxyethanol (CAS
111-76-2)
STEL 1000 ppmButane (CAS 106-97-8)
STEL 1000 ppmEthyl Alcohol (CAS 64-17-5)
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents Type
TWA 24 mg/m32-Butoxyethanol (CAS
111-76-2)
5 ppm
TWA 1900 mg/m3Butane (CAS 106-97-8)
800 ppm
TWA 1900 mg/m3Ethyl Alcohol (CAS 64-17-5)
1000 ppm
TWA 1800 mg/m3Propane (CAS 74-98-6)
1000 ppm
Biological limit values
ACGIH Biological Exposure Indices
ValueComponents Determinant Specimen Sampling Time
200 mg/g Butoxyacetic
acid (BAA),
with hydrolysis
Creatinine in
urine
*2-Butoxyethanol (CAS
111-76-2)
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
2-Butoxyethanol (CAS 111-76-2) Skin designation applies.
US - Tennesse OELs: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US NIOSH Pocket Guide to Chemical Hazards: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
Appropriate engineering
controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection If contact is likely, safety glasses with side shields are recommended.
Hand protection For prolonged or repeated skin contact use suitable protective gloves.
Skin protection
Other Wear suitable protective clothing.
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Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an
air-supplied respirator. If engineering controls do not maintain airborne concentrations below
recommended exposure limits (where applicable) or to an acceptable level (in countries where
exposure limits have not been established), an approved respirator must be worn.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene
considerations
When using do not smoke. Always observe good personal hygiene measures, such as washing
after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.
9. Physical and chemical properties
Appearance Clear.
Physical state Gas.
Form Aerosol. Liquefied gas.
Color Light yellow.
Odor Characteristic.
Odor threshold Not available.
pH 9.1 - 10.1 estimated
Melting point/freezing point Not available.
Initial boiling point and boiling
range
212 °F (100 °C) estimated
Flash point -156.0 °F (-104.4 °C) Propellant estimated
Evaporation rate Not available.
Flammability (solid, gas)Not available.
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Not available.
Flammability limit - upper
(%)
Not available.
Explosive limit - lower (%)Not available.
Explosive limit - upper (%)Not available.
Vapor pressure 80 - 100 psig @70F estimated
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water)Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Aerosol spray enclosed space
Deflagration density > 2.52 g/cm3 Tested
Aerosol spray ignition
distance
< 15 cm Tested estimated
Specific gravity 0.977 - 0.997
10. Stability and reactivity
Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous
reactions
No dangerous reaction known under conditions of normal use. Hazardous polymerization does not
occur.
Conditions to avoid Avoid heat, sparks, open flames and other ignition sources. Avoid temperatures exceeding the
flash point. Contact with incompatible materials.
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Incompatible materials Strong oxidizing agents.
Hazardous decomposition
products
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Ingestion Expected to be a low ingestion hazard.
Inhalation Prolonged inhalation may be harmful.
Skin contact No adverse effects due to skin contact are expected.
2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and
prolonged. These effects have not been observed in humans.
Eye contact Direct contact with eyes may cause temporary irritation.
Symptoms related to the
physical, chemical and
toxicological characteristics
Direct contact with eyes may cause temporary irritation.
Information on toxicological effects
Acute toxicity May be harmful if swallowed. May be harmful in contact with skin. May be harmful if inhaled.
Expected to be a low hazard for usual industrial or commercial handling by trained personnel.
Test ResultsComponents Species
2-Butoxyethanol (CAS 111-76-2)
LD50 Guinea pig
Dermal
Acute
230 ml/kg, 24 Hours
7.3 ml/kg, 4 Days
Rabbit 450 ml/kg, 24 Hours
435 mg/kg, 24 Hours
0.63 ml/kg
Rat > 2000 mg/kg, 24 Hours
LC50 Rabbit
Inhalation
400 ppm, 7 Hours
Rat 450 ppm, 4 Hours
LD100 Rabbit
Oral
695 mg/kg
LD50 Dog > 695 mg/kg
Guinea pig 1200 mg/kg
Rat 530 - 2800 mg/kg
Butane (CAS 106-97-8)
LC50 Mouse
Inhalation
Acute
1237 mg/l, 120 Minutes
52 %, 120 Minutes
Rat 1355 mg/l
Ethyl Alcohol (CAS 64-17-5)
LC50 Cat
Inhalation
Acute
85.41 mg/l, 4.5 Hours
43.68 mg/l, 6 Hours
Mouse > 60000 ppm
79.43 mg/l, 134 Minutes
Rat > 115.9 mg/l, 4 Hours
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Test ResultsComponents Species
51.3 mg/l, 6 Hours
LD50 Monkey
Oral
6000 mg/kg
Mouse 10500 ml/kg
Rat 1187 - 2769 mg/kg
7800 ml/kg
Propane (CAS 74-98-6)
LC50 Mouse
Inhalation
Acute
1237 mg/l, 120 Minutes
52 %, 120 Minutes
Rat 1355 mg/l
658 mg/l/4h
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation May be irritating to the skin. Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye
irritation
Direct contact with eyes may cause temporary irritation. May be irritating to eyes.
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -
single exposure
Not classified.
Specific target organ toxicity -
repeated exposure
Not classified.
Aspiration hazard Not an aspiration hazard. Not likely, due to the form of the product.
Chronic effects Prolonged inhalation may be harmful. May be harmful if absorbed through skin.
2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and
prolonged. These effects have not been observed in humans.
12. Ecological information
Ecotoxicity Harmful to aquatic life.
Product Test ResultsSpecies
CHALKBOARD CLEANER (CAS Mixture)
Aquatic
EC50Crustacea 13838.1602 mg/l, 48 hours estimatedDaphnia
Components Test ResultsSpecies
2-Butoxyethanol (CAS 111-76-2)
Aquatic
LC50Fish 1250 mg/l, 96 hoursInland silverside (Menidia beryllina)
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Components Test ResultsSpecies
Ethyl Alcohol (CAS 64-17-5)
Aquatic
EC50Crustacea 7700 - 11200 mg/l, 48 hoursWater flea (Daphnia magna)
* Estimates for product may be based on additional component data not shown.
LC50Fish > 100.1 mg/l, 96 hoursFathead minnow (Pimephales promelas)
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Partition coefficient n-octanol / water (log Kow)
2-Butoxyethanol 0.83
Butane 2.89
Ethyl Alcohol -0.31
Propane 2.36
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions Consult authorities before disposal. Contents under pressure. Do not puncture, incinerate or crush.
Dispose of contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
products
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Do not re-use empty containers.
14. Transport information
DOT
UN1950UN number
AerosolsUN proper shipping name
2.2Class
Transport hazard class(es)
-Subsidiary risk
2.2Label(s)
Not applicable.Packing group
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
306Packaging exceptions
NonePackaging non bulk
NonePackaging bulk
This product meets the exception requirements of section 173.306 as a limited quantity and may be shipped as a limited quantity.
Until 12/31/2020, the "Consumer Commodity - ORM-D" marking may still be used in place of the new limited quantity diamond
mark for packages of UN 1950 Aerosols. Limited quantities require the limited quantity diamond mark on cartons after 12/31/20
and may be used now in place of the "Consumer Commodity ORM-D" marking and both may be displayed concurrently.
IATA
UN1950UN number
Aerosols, non-flammableUN proper shipping name
2.2Class
Transport hazard class(es)
-Subsidiary risk
2.2Label(s)
Not applicable.Packing group
No.Environmental hazards
2LERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
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Allowed.Passenger and cargo
aircraft
Other information
Allowed.Cargo aircraft only
LTD QTYPackaging Exceptions
IMDG
UN1950UN number
AEROSOLSUN proper shipping name
2.2Class
Transport hazard class(es)
-Subsidiary risk
2.2Label(s)
Not applicable.Packing group
No.Marine pollutant
Environmental hazards
Not available.EmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
LTD QTYPackaging Exceptions
Not applicable.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
DOT
IATA; IMDG
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - Yes
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
No
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
Safe Drinking Water Act
(SDWA)
Not regulated.
US state regulations
US. Massachusetts RTK - Substance List
2-Butoxyethanol (CAS 111-76-2)
Butane (CAS 106-97-8)
Ethyl Alcohol (CAS 64-17-5)
Propane (CAS 74-98-6)
US. New Jersey Worker and Community Right-to-Know Act
2-Butoxyethanol (CAS 111-76-2)
Butane (CAS 106-97-8)
Ethyl Alcohol (CAS 64-17-5)
Propane (CAS 74-98-6)
US. Pennsylvania Worker and Community Right-to-Know Law
2-Butoxyethanol (CAS 111-76-2)
Butane (CAS 106-97-8)
Ethyl Alcohol (CAS 64-17-5)
Propane (CAS 74-98-6)
US. Rhode Island RTK
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope European List of Notified Chemical Substances (ELINCS)
NoJapan Inventory of Existing and New Chemical Substances (ENCS)
NoKorea Existing Chemicals List (ECL)
NoNew Zealand New Zealand Inventory
NoPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
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Country(s) or region Inventory name On inventory (yes/no)*
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date 05-30-2015
Version #01
References EPA: AQUIRE database
NLM: Hazardous Substances Data Base
US. IARC Monographs on Occupational Exposures to Chemical Agents
Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
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