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HomeMy WebLinkAboutClorox Health Care Hydrogen Peroxide Cleaner Disinfectant Wipes SAFETY DATA SHEET Issuing Date January 5, 2015 Revision Date January 14, 2016 Revision Number 1 Page 1 / 9 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Clorox Healthcare® Hydrogen Peroxide Cleaner Disinfectant Wipes Other means of identification EPA Registration Number 67619-25 Recommended use of the chemical and restrictions on use Recommended use Moistened disinfecting wipes Uses advised against No information available Details of the supplier of the safety data sheet Supplier Address Clorox Professional Products Company 1221 Broadway Oakland, CA 94612 Phone: 1-510-271-7000 Emergency telephone number Emergency Phone Numbers For Medical Emergencies call: 1-800-446-1014 For Transportation Emergencies, call Chemtrec: 1-800-424-9300 Clorox Healthcare® Hydrogen Peroxide Cleaner Disinfectant Wipes Revision Date January 14, 2016 Page 2 / 9 2. HAZARDS IDENTIFICATION Classification This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). GHS Label elements, including precautionary statements Emergency Overview This product is not considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Appearance Clear, colorless liquid absorbed into white, non-woven wipes Physical State Thin liquid absorbed into non-woven wipes Odor Cherry, almond Precautionary Statements - Prevention None Precautionary Statements - Response None Precautionary Statements - Storage None Precautionary Statements - Disposal None Hazards not otherwise classified (HNOC) Not applicable Unknown Toxicity 19% of the mixture consists of ingredient(s) of unknown toxicity Other information Harmful to aquatic life with long-lasting effects. Interactions with Other Chemicals No information available. 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS No. Weight % Trade Secret Hydrogen peroxide 7722-84-1 0.5 - 2 * Benzyl alcohol 100-51-6 1 - 5 * * The exact percentage (concentration) of composition has been withheld as a trade secret. Clorox Healthcare® Hydrogen Peroxide Cleaner Disinfectant Wipes Revision Date January 14, 2016 Page 3 / 9 4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye Contact Hold eye open and rinse slowly and gently with water for 15 - 20 minutes. If present, remove contact lenses after the first 5 minutes of rinsing, then continue rinsing eye. Call a poison control center or doctor for further treatment advice. Skin Contact Rinse skin with plenty of water. If irritation persists, call a doctor. Inhalation Move to fresh air. If breathing problems develop, call a doctor. Ingestion Drink a glassful of water. Call a doctor or poison control center. Most important symptoms and effects, both acute and delayed Most Important Symptoms and Effects Liquid may cause eye irritation. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical Hazardous Combustion Products Oxides of carbon. Explosion Data Sensitivity to Mechanical Impact No. Sensitivity to Static Discharge No. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Clorox Healthcare® Hydrogen Peroxide Cleaner Disinfectant Wipes Revision Date January 14, 2016 Page 4 / 9 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with eyes. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental Precautions See Section 12 for additional ecological information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with eyes, skin, and clothing. Do not eat, drink, or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Keep containers tightly closed in a dry, cool, and well-ventilated place. Incompatible Products None known. 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Hydrogen peroxide 7722-84-1 TWA: 1 ppm TWA: 1 ppm TWA: 1.4 mg/m3 IDLH: 75 ppm TWA: 1 ppm TWA: 1.4 mg/m3 ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health. Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Clorox Healthcare® Hydrogen Peroxide Cleaner Disinfectant Wipes Revision Date January 14, 2016 Page 5 / 9 Individual protection measures, such as personal protective equipment Eye/Face Protection No special protective equipment required. Skin and Body Protection No special protective equipment required. Respiratory Protection No protective equipment is needed under normal use conditions. If irritation is experienced, ventilation and evacuation may be required. Hygiene Measures Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Thin liquid absorbed into non-woven wipes Appearance Clear liquid absorbed into non-woven wipes Odor Cherry, almond Color Colorless liquid - white non-woven wipes Odor Threshold No information available Property Values Remarks/ Method pH 2 - 3 (liquid) None known Melting/freezing point No data available None known Boiling point / boiling range No data available None known Flash Point >93°C None known Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air Upper flammability limit No data available None known Lower flammability limit No data available None known Vapor pressure No data available None known Vapor density No data available None known Specific Gravity ~1.0 (liquid) None known Water Solubility Complete (liquid) None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive Properties Not explosive Oxidizing Properties No data available Other Information Softening Point No data available VOC Content (%) No data available Particle Size No data available Particle Size Distribution No data available Clorox Healthcare® Hydrogen Peroxide Cleaner Disinfectant Wipes Revision Date January 14, 2016 Page 6 / 9 10. STABILITY AND REACTIVITY Reactivity No data available. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid None known based on information supplied. Incompatible materials None known. Hazardous Decomposition Products None known. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information . Inhalation Exposure to vapor or mist may irritate respiratory tract. Eye Contact Liquid may cause irritation. Skin Contact Liquid may cause slight irritation. Ingestion Ingestion of liquid may cause slight irritation to mucous membranes and gastrointestinal tract. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Hydrogen peroxide 7722-84-1 801 mg/kg (Rat) 4.06 g/kg (Rat) 2 g/kg (Rabbit) 2 g/m3 (Rat, 4 h) Benzyl alcohol 100-51-6 1230 mg/kg (Rat) 2 g/kg (Rabbit) 8.8 mg/L (Rat, 4 h) Information on toxicological effects Symptoms Liquid may cause redness and tearing of eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Clorox Healthcare® Hydrogen Peroxide Cleaner Disinfectant Wipes Revision Date January 14, 2016 Page 7 / 9 Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Hydrogen peroxide 7722-84-1 A3 Group 3 - - ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen IARC (International Agency for Research on Cancer) Group 3 - Not classifiable as to carcinogenicity to humans Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity No known effect based on information supplied. Target Organ Effects Respiratory system, eyes, skin, gastrointestinal tract (GI). Aspiration Hazard No information available. Numerical measures of toxicity - Product Information ATEmix (oral) 13 g/kg ATEmix (dermal) 28 g/kg (ATE) ATEmix (inhalation-gas) 63,705 ppm (4 hr) ATEmix (inhalation-dust/mist) 24.77 mg/L ATEmix (inhalation-vapor) 156 mg/L ATEmix 12. ECOLOGICAL INFORMATION Ecotoxicity Harmful to aquatic life with long lasting effects. Persistence and Degradability No information available. Bioaccumulation No information available. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations. Contaminated Packaging Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations. Clorox Healthcare® Hydrogen Peroxide Cleaner Disinfectant Wipes Revision Date January 14, 2016 Page 8 / 9 14. TRANSPORT INFORMATION DOT Not regulated. TDG Not regulated. ICAO Not regulated. IATA Not regulated IMDG/IMO Not regulated 15. REGULATORY INFORMATION Chemical Inventories TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing. DSL/NDSL All components are on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals that are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372. SARA 311/312 Hazard Categories Acute Health Hazard No Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No CWA (Clean Water Act) This product contains the following substance that is regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42). Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Hydrogen peroxide 7722-84-1 X X X X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302). Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ Hydrogen peroxide 7722-84-1 - 1000 lb - Clorox Healthcare® Hydrogen Peroxide Cleaner Disinfectant Wipes Revision Date January 14, 2016 Page 9 / 9 EPA Statement This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the pesticide label: CAUTION: Causes moderate eye irritation. Avoid contact with eyes or clothing. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the toilet. US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Hydrogen peroxide 7722-84-1 X X X - - Benzyl alcohol 100-51-6 - X X - - International Regulations Canada WHMIS Hazard Class Not controlled. 16. OTHER INFORMATION NFPA Health Hazard 1 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 1 Flammability 0 Physical Hazard 0 Personal Protection A Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501 Preparation/Revision Date January 14, 2016 Revision Note Reference The flash point was added to section 9 1138497/164708.001 General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information, and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal, and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet