Loading...
HomeMy WebLinkAboutClorox Liquid Bleach SAFETY DATA SHEET Issuing Date January 5, 2015 Revision Date New Revision Number 0 Page 1 / 10 1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING Product identifier Product Name Clorox® Clean Linen® Bleach Other means of identification Synonyms None Recommended use of the chemical and restrictions on use Recommended use Laundry and household bleach Uses advised against No information available Details of the supplier of the safety data sheet Supplier Address The Clorox Company 1221 Broadway, Oakland, CA 94612 USA Phone: 1-510-271-7000 Emergency telephone number Emergency Phone Numbers For Medical Emergencies, call: 1-800-446-1014 For Transportation Emergencies, call Chemtrec: 1-800-424-9300 Clorox® Clean Linen® Bleach Revision Date New Page 2 / 10 2. HAZARDS IDENTIFICATION Classification This chemical is considered hazardous by the 2012 OSHA Hazard Communication Standard (29 CFR 1910.1200). Serious eye damage/eye irritation Category 2A GHS Label elements, including precautionary statements Emergency Overview Signal word Warning Hazard Statements Causes serious eye irritation Appearance Clear, pale yellow Physical State Liquid Odor Floral, green, bleach Precautionary Statements - Prevention Wash hands and any exposed skin thoroughly after handling. Wear eye protection/face protection such as safety glasses. Precautionary Statements - Response Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. Precautionary Statements - Storage None Precautionary Statements - Disposal None Hazards not otherwise classified (HNOC) Not applicable. Unknown Toxicity 0.06% of the mixture consists of ingredient(s) of unknown toxicity Other information Very toxic to aquatic life with long lasting effects. Interactions with Other Chemicals Reacts with other household chemicals such as toilet bowl cleaners, rust removers, acids, and ammonia-containing products to produce hazardous gases, such as chlorine and other chlorinated compounds. Clorox® Clean Linen® Bleach Revision Date New Page 3 / 10 3. COMPOSITION/INFORMATION ON INGREDIENTS Chemical Name CAS-No Weight % Trade Secret Sodium hypochlorite 7681-52-9 1 - 5 * Sodium hydroxide 1310-73-2 0.1 - 1 * * The exact percentage (concentration) of composition has been withheld as a trade secret. 4. FIRST AID MEASURES First aid measures General Advice Show this safety data sheet to the doctor in attendance. Eye Contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep eye wide open while rinsing. Do not rub affected area. Get medical attention if irritation develops and persists. Skin Contact Take off contaminated clothing. Rinse skin with plenty of water. If irritation develops, call a doctor. Inhalation Move to fresh air. If breathing is affected, call a doctor. Ingestion Drink a glassful of water. Call a poison control center or doctor immediately. DO NOT induce vomiting unless told to do so by a poison control center or doctor. Protection of First-aiders Avoid contact with skin, eyes or clothing. Use personal protective equipment as required. Wear personal protective clothing (see section 8). Most important symptoms and effects, both acute and delayed Most Important Symptoms and Effects Stinging and irritation of eyes. Indication of any immediate medical attention and special treatment needed Notes to Physician Treat symptomatically. Clorox® Clean Linen® Bleach Revision Date New Page 4 / 10 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Unsuitable Extinguishing Media CAUTION: Use of water spray when fighting fire may be inefficient. Specific Hazards Arising from the Chemical No information available. Explosion Data Sensitivity to Mechanical Impact None. Sensitivity to Static Discharge None. Protective equipment and precautions for firefighters As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal Precautions Avoid contact with eyes, skin, and clothing. Use personal protective equipment as required. Other Information Refer to protective measures listed in Sections 7 and 8. Environmental precautions Environmental Precautions See Section 12 for ecological Information. Methods and material for containment and cleaning up Methods for Containment Prevent further leakage or spillage if safe to do so. Methods for Cleaning Up Absorb and containerize. Wash residual down to sanitary sewer. Contact the sanitary treatment facility in advance to assure ability to process washed-down material. 7. HANDLING AND STORAGE Precautions for safe handling Handling Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin, eyes and clothing. Do not eat, drink or smoke when using this product. Conditions for safe storage, including any incompatibilities Storage Keep containers tightly closed in a dry, cool and well-ventilated place. Incompatible Products Toilet bowl cleaners, rust removers, acids, and ammonia-containing products. Clorox® Clean Linen® Bleach Revision Date New Page 5 / 10 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Guidelines Chemical Name ACGIH TLV OSHA PEL NIOSH IDLH Sodium hydroxide 1310-73-2 Ceiling: 2 mg/m3 TWA: 2 mg/m3 IDLH: 10 mg/m3 Ceiling: 2 mg/m3 ACGIH TLV: American Conference of Governmental Industrial Hygienists - Threshold Limit Value. OSHA PEL: Occupational Safety and Health Administration - Permissible Exposure Limits. NIOSH IDLH: Immediately Dangerous to Life or Health. Appropriate engineering controls Engineering Measures Showers Eyewash stations Ventilation systems Individual protection measures, such as personal protective equipment Eye/Face Protection If splashes are likely to occur: Wear safety glasses with side shields (or goggles). None required for consumer use. Skin and Body Protection Wear rubber or neoprene gloves if there is the potential for repeated or prolonged skin contact. Respiratory Protection If exposure limits are exceeded or irritation is experienced, NIOSH/MSHA approved respiratory protection should be worn. Positive-pressure supplied air respirators may be required for high airborne contaminant concentrations. Respiratory protection must be provided in accordance with current local regulations. Hygiene Measures Remove and wash contaminated clothing before re-use. Avoid contact with skin, eyes or clothing. Do not eat, drink or smoke when using this product. Clorox® Clean Linen® Bleach Revision Date New Page 6 / 10 9. PHYSICAL AND CHEMICAL PROPERTIES Physical and Chemical Properties Physical State Liquid Appearance Clear Odor Floral, green, bleach Color Pale yellow Odor Threshold No information available Property Values Remarks/ Method pH ~12.5 None known Melting/freezing point No data available None known Boiling point / boiling range No data available None known Flash Point Not flammable None known Evaporation rate No data available None known Flammability (solid, gas) No data available None known Flammability Limits in Air Upper flammability limit No data available None known Lower flammability limit No data available None known Vapor pressure No data available None known Vapor density No data available None known Specific Gravity ~1.05 None known Water Solubility Soluble in water None known Solubility in other solvents No data available None known Partition coefficient: n-octanol/water No data available None known Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Explosive Properties Not explosive Oxidizing Properties No data available Other Information Softening Point No data available VOC Content (%) No data available Particle Size No data available Particle Size Distribution No data available 10. STABILITY AND REACTIVITY Reactivity Reacts with other household chemicals such as toilet bowl cleaners, rust removers, acids, and ammonia-containing products to produce hazardous gases, such as chlorine and other chlorinated compounds. Chemical stability Stable under recommended storage conditions. Possibility of Hazardous Reactions None under normal processing. Conditions to avoid None known based on information supplied. Incompatible materials Toilet bowl cleaners, rust removers, acids, and ammonia-containing products. Hazardous Decomposition Products None known based on information supplied. Clorox® Clean Linen® Bleach Revision Date New Page 7 / 10 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure Product Information . Inhalation Exposure to vapor or mist may irritate respiratory tract. Eye Contact May cause eye irritation. Skin Contact Prolonged contact may cause irritation. Ingestion Ingestion may cause irritation to mucous membranes and gastrointestinal tract, nausea, vomiting, and diarrhea. Component Information Chemical Name LD50 Oral LD50 Dermal LC50 Inhalation Sodium hypochlorite 7681-52-9 8200 mg/kg (Rat) >10000 mg/kg (Rabbit) - Sodium hydroxide 1310-73-2 - 1350 mg/kg (Rabbit) - Information on toxicological effects Symptoms May cause redness and tearing of the eyes. Delayed and immediate effects as well as chronic effects from short and long-term exposure Sensitization No information available. Mutagenic Effects No information available. Carcinogenicity The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical Name ACGIH IARC NTP OSHA Sodium hypochlorite 7681-52-9 - Group 3 - - IARC (International Agency for Research on Cancer) Group 3 - Not Classifiable as to Carcinogenicity in Humans Reproductive Toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Chronic Toxicity Carcinogenic potential is unknown. Target Organ Effects Respiratory system, eyes, skin, gastrointestinal tract (GI). Aspiration Hazard No information available. Numerical measures of toxicity - Product Information The following values are calculated based on chapter 3.1 of the GHS document 117.20 mg/l ATEmix (4 hr) Clorox® Clean Linen® Bleach Revision Date New Page 8 / 10 12. ECOLOGICAL INFORMATION Ecotoxicity Very toxic to aquatic life with long lasting effects. Persistence and Degradability No information available. Bioaccumulation No information available. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Disposal methods Dispose of in accordance with all applicable federal, state, and local regulations. Contaminated Packaging Do not reuse empty containers. Dispose of in accordance with all applicable federal, state, and local regulations. 14. TRANSPORT INFORMATION DOT NOT REGULATED TDG UN-No UN3082 Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class 9 Packing Group III Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III, MARINE POLLUTANT ICAO UN-No UN3082 Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class 9 Packing Group III Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III IATA UN-No UN3082 Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class 9 Packing Group III Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III Clorox® Clean Linen® Bleach Revision Date New Page 9 / 10 IMDG/IMO UN-No UN3082 Proper Shipping Name ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. Hazard Class 9 Packing Group III EmS No. F-A, S-F Marine Pollutant Product is a marine pollutant according to the criteria set by IMDG/IMO Description UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (SODIUM HYPOCHLORITE), 9, III, MARINE POLLUTANT 15. REGULATORY INFORMATION Chemical Inventories TSCA All components of this product are either on the TSCA 8(b) Inventory or otherwise exempt from listing. DSL/NDSL All components are on the DSL or NDSL. TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List U.S. Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Acute Health Hazard Yes Chronic Health Hazard No Fire Hazard No Sudden Release of Pressure Hazard No Reactive Hazard No Clean Water Act This product contains the following substances which are regulated pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) Chemical Name CWA - Reportable Quantities CWA - Toxic Pollutants CWA - Priority Pollutants CWA - Hazardous Substances Sodium hypochlorite 7681-52-9 100 lb X Sodium hydroxide 1310-73-2 1000 lb X CERCLA This material, as supplied, contains one or more substances regulated as a hazardous substance under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) Chemical Name Hazardous Substances RQs Extremely Hazardous Substances RQs RQ Sodium hypochlorite 7681-52-9 100 lb - RQ 100 lb final RQ RQ 45.4 kg final RQ Sodium hydroxide 1310-73-2 1000 lb - RQ 1000 lb final RQ RQ 454 kg final RQ Clorox® Clean Linen® Bleach Revision Date New Page 10 / 10 US State Regulations California Proposition 65 This product does not contain any Proposition 65 chemicals. U.S. State Right-to-Know Regulations Chemical Name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Sodium hypochlorite 7681-52-9 X X X X Sodium hydroxide 1310-73-2 X X X X International Regulations Canada WHMIS Hazard Class D2B - Toxic materials 16. OTHER INFORMATION NFPA Health Hazard 2 Flammability 0 Instability 0 Physical and Chemical Hazards - HMIS Health Hazard 2 Flammability 0 Physical Hazard 0 Personal Protection B Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501 Revision Date New Revision Note Reference New 1059788/185645.002 General Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. End of Safety Data Sheet