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HomeMy WebLinkAboutDiversey BathmateSAFETY DATA SHEET Bath MateTM/MC Acid-Free Disinfectant Washroom Cleaner Concentrate 1. IDENTIFICATION Product name:Bath MateTM/MC Acid-Free Disinfectant Washroom Cleaner Concentrate Product Code:5516250, 5516276 SDS #:MS0800467 Recommended use:• Disinfectant Cleaner • This product is intended to be diluted prior to use Uses advised against:Uses other than those identified are not recommended Emergency telephone number:1-800-851-7145 (U.S.); 1-651-917-6133 (Int'l) 2. HAZARDS IDENTIFICATION Classification for the undiluted product Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 1 Specific target organ toxicity (single exposure) Category 3 Signal Word: Danger. Precautionary Statements MAY CAUSE RESPIRATORY IRRITATION. CAUSES SKIN IRRITATION. CAUSES SERIOUS EYE DAMAGE. Causes burns/ serious damage to mouth, throat and stomach. Avoid contact with eyes, skin and clothing. Avoid breathing vapors. Avoid breathing spray. Wash affected areas thoroughly after handling. Use only in a well-ventilated area. Wear chemical-splash goggles and chemical-resistant gloves. IF SWALLOWED: Rinse mouth. DO NOT induce vomiting unless directed to do so by medical personnel. Drink a cupful of milk or water. IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice or attention. IF INHALED: Remove person to fresh airand keep comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 15 minutes. Immediately call a Poison Center (1-800-851-7145) or physician. Take off contaminated clothing and wash it before reuse. Store in a well-ventilated place. Keep container tightly closed. Dispose of in accordance with all federal, state and local applicable regulations. Health hazards not otherwise classified (HHNOC) - Not applicable Physical hazards not otherwise classified (PHNOC) - Not applicable Preparation date: 2015-09-14Version Number: 4 Bath MateTM/MC Acid-Free Disinfectant Washroom Cleaner Concentrate 1 of 6 Manufacturer, importer, supplier: US Headquarters Diversey, Inc.P.O. Box 19747 Charlotte, NC 28219-0747 Phone: 1-888-352-2249 SDS Internet Address: https://sds.sealedair.com Percentage of unknown Acute Toxicity 1.15313 3. COMPOSITION/INFORMATION ON INGREDIENTS Classified Ingredients Ingredient(s)CAS #Weight % Diethylene glycol butyl ether 112-34-5 20 - 30% Ethoxylated secondary alcohol 84133-50-6 10 - 20% Monoethanolamine 141-43-5 5 - 10% Tetrasodium salt of EDTA 64-02-8 1% - < 3% n-alkyl dimethyl benzyl ammonium chloride 68424-85-1 > 0.1% - < 1% Phenylethyl alcohol 60-12-8 > 0.1% - < 1% Gamma methyl ionone 127-51-5 > 0.1% - < 1% Isoeugenol 97-54-1 < 0.1% *Exact percentages are being withheld as trade secret information 4. FIRST AID MEASURES Undiluted Product: Eyes: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing for at least 15 minutes. Skin: IF ON SKIN: Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Inhalation: IF INHALED: Remove person to fresh air and keep comfortable for breathing. Ingestion: IF SWALLOWED: Rinse mouth. DO NOT induce vomiting unless directed to do so by medical personnel. Drink a cupful of milk or water. Notes to physician: Probable mucosal damage may contraindicate the use of gastric lavage. Most Important Symptoms/Effects: No information available. Immediate medical attention and special treatment needed Not applicable. Aggravated Medical Conditions: Individuals with chronic respiratory disorders such as asthma, chronic bronchitis, emphysema, etc., may be more susceptible to irritating effects. 5. FIRE-FIGHTING MEASURES Specific methods:No special methods required Suitable extinguishing media:The product is not flammable. Extinguish fire using agent suitable for surrounding fire. Specific hazards:Not applicable. Special protective equipment for firefighters: As in any fire, wear self-contained breathing apparatus pressure-demand, MSHA/NIOSH (approved or equivalent) and full protective gear. Extinguishing media which must not be used for safety reasons: No information available. 6. ACCIDENTAL RELEASE MEASURES Inhalation: No specific first aid measures are required Ingestion: Rinse mouth with water. Classification for the diluted product @ 1:12 Diluted Product: Precautionary Statements This product, when diluted as stated on the label, is not classified as hazardous according to OSHA 29CFR 1910.1200 (HazCom 2012-GHS) and Canadian Hazardous Products Regulations (HPR) (WHMIS 2015-GHS). Bath MateTM/MC Acid-Free Disinfectant Washroom Cleaner Concentrate Eyes: Rinse with plenty of water If irritation occurs and persists, get medical attention. 2 of 6 None required. Skin: Rinse with plenty of water If irritation occurs and persists, get medical attention. Personal precautions:Put on appropriate personal protective equipment (see Section 8.). Environmental precautions and clean-up methods: Material is toxic to fish. Do not discharge into lakes, streams, ponds, or public water unless in accordance with an NPDES permit. Clean-up methods - large spillage. Absorb spill with inert material (e.g. dry sand or earth), then place in a chemical waste container. Use a water rinse for final clean-up. 7. HANDLING AND STORAGE Handling: Avoid contact with skin, eyes and clothing. Do not taste or swallow. Avoid breathing vapors or mists. Use only with adequate ventilation. Remove and wash contaminated clothing and footwear before re-use. Wash thoroughly after handling. Product residue may remain on/in empty containers. All precautions for handling the product must be used in handling the empty container and residue. FOR COMMERCIAL AND INDUSTRIAL USE ONLY. Storage: Protect from freezing. Keep tightly closed in a dry, cool and well-ventilated place. KEEP OUT OF REACH OF CHILDREN. Aerosol Level (if applicable) : Not applicable 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Exposure Guidelines:. Ingredient(s)CAS #ACGIH OSHA Diethylene glycol butyl ether 112-34-5 10 ppm (TWA)- Ethoxylated secondary alcohol 84133-50-6 -- Monoethanolamine 141-43-5 6 ppm (STEL) 3 ppm (TWA) 3 ppm (TWA) 6 mg/m3 (TWA) Tetrasodium salt of EDTA 64-02-8 -- n-alkyl dimethyl benzyl ammonium chloride 68424-85-1 -- Phenylethyl alcohol 60-12-8 -- Gamma methyl ionone 127-51-5 -- Isoeugenol 97-54-1 -- Undiluted Product: Engineering measures to reduce exposure:Good general ventilation should be sufficient to control airborne levels Respiratory protection is not required if good ventilation is maintained. Personal Protective Equipment Eye protection:Chemical-splash goggles. Hand protection:Chemical-resistant gloves. Skin and body protection:No personal protective equipment required under normal use conditions. Respiratory protection:No personal protective equipment required under normal use conditions. Hygiene measures:Handle in accordance with good industrial hygiene and safety practice. 9. PHYSICAL AND CHEMICAL PROPERTIES Explosion limits: - upper: Not determined - lower: Not determined Decomposition temperature: Not determined Hygiene measures:Handle in accordance with good industrial hygiene and safety practice. Autoignition temperature: No information available Solubility: Completely Soluble Eye protection:No personal protective equipment required under normal use conditions. Solubility in other solvents: No information available Relative Density (relative to water): 1.001 Density: 8.35 lbs/gal 1.001 Kg/L Vapor density: No information available Bulk density: No information available Vapor pressure: No information available. Hand protection:No personal protective equipment required under normal use conditions. Flash point: > 200 °F > 93.3 °C Partition coefficient (n-octanol/water): No information available Diluted Product: Dilution Flash Point: > 200 °F > 93.3 °C Viscosity: No information available Skin and body protection:No personal protective equipment required under normal use conditions. Elemental Phosphorus: 0.00 % by wt. Physical State: Liquid VOC: 6.37 % * pH: 11.6 Personal Protective Equipment VOC % by wt. at use dilution 0.49 % * Color: Clear, Green Dilution pH: 10.8 @ 1:12 Flammability (Solid or Gas): Not applicable Evaporation Rate: No information available Metal Corrosion: Not determined Odor: Fresh Respiratory protection:No personal protective equipment required under normal use conditions. Odor threshold: No information available. Bath MateTM/MC Acid-Free Disinfectant Washroom Cleaner Concentrate 3 of 6 Boiling point/range: Not determined Melting point/range: Not determined * - Title 17, California Code of Regulations, Division 3, Chapter 1, Subchapter 8.5, Article 2, Consumer Products, Sections 94508 10. STABILITY AND REACTIVITY Reactivity:Not Applicable Stability:The product is stable Hazardous decomposition products:None reasonably foreseeable. Materials to avoid:Acids. Oxidizing agents. Conditions to avoid:Do not freeze. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure: Eye contact, Skin contact, Inhalation, Ingestion Delayed, immediate, or chronic effects and symptoms from short and long-term exposure Skin contact: Causes skin irritation. Symptoms may include pain (which may be delayed), redness, and/or discomfort. Eye contact: Corrosive. Causes serious eye damage. Symptoms may include pain, burning sensation, redness, watering, blurred vision or loss of vision. Ingestion: Causes burns/ serious damage to mouth, throat and stomach. Symptoms may include stomach pain and nausea. Inhalation: May cause irritation and corrosive effects to nose, throat and respiratory tract. Symptoms may include coughing and difficulty breathing. Sensitization: No known effects. Target Organs (SE): None known Target Organs (RE): None known Carcinogen Listings: Statment per route of exposure or specific component Ingredient(s)CAS #NTP IARC OSHA Ethyl alcohol 64-17-5 - Numerical measures of toxicity ATE - Oral (mg/kg):>5000 ATE - Dermal (mg/kg):>5000 ATE - Inhalatory, mists (mg/l):7.9 ATE - Inhalatory, vapors (mg/l):>50 Percentage of unknown Acute Toxicity 1.15313 12. ECOLOGICAL INFORMATION Ecotoxicity: No information available. Persistence and Degradability: No information available. Bioaccumulation: No information available. 13. DISPOSAL CONSIDERATIONS Waste from residues / unused products: Pesticide wastes are acutely hazardous. Improper disposal of excess pesticide, spray mixture, or rinsate is a violation of Federal Law. If these wastes cannot be disposed of by use according to label instructions contact your State Pesticide or Environmental Control Agency, or the Hazardous Waste reporesentative at the nearest EPA Regional Office for guidance. This product, as sold, if discarded or disposed, is not a hazardous waste according to Federal regulations (40 CFR 261.4 (b)(4)). Dispose in compliance with all Federal, state, provincial, and local laws and regulations. This product, when diluted as stated on this SDS, is not a hazardous waste according to Federal regulations (40 CFR 261.4 (b)(4)). Under RCRA, it is the responsibility of the user of the product to determine, at the time of disposal, whether the waste solution meets RCRA criteria for hazardous waste. Dispose in compliance with all Federal, state, provincial, and local laws and regulations. Contaminated Packaging: Do not re-use empty containers. RCRA Hazard Class (undiluted product): Not Regulated RCRA Hazard Class (diluted product):Not Regulated Bath MateTM/MC Acid-Free Disinfectant Washroom Cleaner Concentrate 4 of 6 14. TRANSPORT INFORMATION DOT/TDG/IMDG: Proper shipping descriptions can vary by pack size. Please refer to the Diversey HazMat Library, only available through Internet Explorer, http://naextranet.diversey.com/dot/, for up to date shipping information. DOT (Ground) Bill of Lading Description: DISINFECTANTS IMDG (Ocean) Bill of Lading Description: DISINFECTANTS 15. REGULATORY INFORMATION International Inventories at CAS# Level All components of this product are listed on the following inventories: U.S.A. (TSCA), Canada (DSL/NDSL). U.S. Regulations EPA Reg. No. : 70627-68 This chemical is a pesticide product registered by the United States Environmental Protection Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SDS), and for workplace labels of non-pesticide chemicals. The hazard information required on the pesticide label is reproduced below. The pesticide label also includes other important information, including directions for use. DANGER: CORROSIVE. Causes irreversible eye damage. Causes skin irritation. Do not get in eyes, on skin or on clothing. Wear protective eyewear (goggles, face shield or safety glasses). Harmful if swallowed, absorbed through the skin or inhaled. Avoid breathing spray mist. Wash thoroughly with soap and water after handling. Remove contaminated clothing and wash clothing before reuse. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals. ENVIRONMENTAL HAZARDS: This product is toxic to fish and aquatic invertebrates. California Proposition 65: This product is not subject to the reporting requirements under California's Proposition 65. RIGHT TO KNOW (RTK) Ingredient(s)CAS #MARTK:NJRTK:PARTK:RIRTK: Water 7732-18-5 ---- Diethylene glycol butyl ether 112-34-5 -X -- Ethoxylated secondary alcohol 84133-50-6 ---- Monoethanolamine 141-43-5 X X X - Tetrasodium salt of EDTA 64-02-8 ---- n-alkyl dimethyl benzyl ammonium chloride 68424-85-1 ---- Ethyl alcohol 64-17-5 X X X - 2-butoxyethanol 111-76-2 X X X - Gamma methyl ionone 127-51-5 ---- Isoeugenol 97-54-1 ---- CERCLA/ SARA Ingredient(s)CAS #Weight %CERCLA/SARA RQ (lbs)Section 302 TPQ (lbs)Section 313 Diethylene glycol butyl ether 112-34-5 20 - 30%X 2-butoxyethanol 111-76-2 > 0.1% - < 1%X Ingredient(s)CAA HAP CAA ODS CWA Priority Pollutants Diethylene glycol butyl ether X 2-butoxyethanol X SARA 311/312 Hazard Categories Immediate:x Delayed:- Fire:- Reactivity:- Sudden Release of Pressure:- Canadian Regulations WHMIS hazard class: Not for sale in Canada. Ingredient(s)CAS #NPRI Diethylene glycol butyl ether 112-34-5 X Bath MateTM/MC Acid-Free Disinfectant Washroom Cleaner Concentrate 5 of 6 2-butoxyethanol 111-76-2 X 16. OTHER INFORMATION NFPA (National Fire Protection Association) Rating Scale: (Low Hazard) 0 - 4 (Extreme Hazard) Health 3 Flammability 0 Instability 0 Version Number: 4 Preparation date: 2015-09-14 Reason for revision:Not applicable Prepared by:NAPRAC Additional advice:• Contains an added fragrance, see "Odor" heading in section 9 for specific description Notice to Reader: This document has been prepared using data from sources considered technically reliable. It does not constitute a warranty, express or implied, as to the accuracy of the information contained within. Actual conditions of use and handling are beyond seller's control. User is responsible to evaluate all available information when using product for any particular use and to comply with all Federal, State, Provincial and Local laws and regulations. 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