HomeMy WebLinkAboutHillyard Defoamer IISAFETY DATA SHEET
1. Identification
Product identifier DEFOAMER II
Other means of identification
SDS number 535N-78A
Product code HIL00183
Recommended use Defoamer
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Manufacturer
Company name HILLYARD INDUSTRIES
Address 302 North Fourth St.
St. Joseph, MO 64501
Contact person Regulatory Affairs
Telephone number (816) 233-1321 (Ext. 8285)
Fax (816) 383-8485
E-mail regulatoryaffairs@hillyard.com
Emergency telephone #(800) 424-9300
(Only in the event of chemical emergency involving a spill, leak, fire, exposure,
or accident involving chemicals.)
2. Hazard(s) identification
Not classified.Physical hazards
Not classified.Health hazards
Not classified.Environmental hazards
Not classified.OSHA defined hazards
Label elements
None.Hazard symbol
Signal word None.
Hazard statement The mixture does not meet the criteria for classification.
Precautionary statement
Prevention Observe good industrial hygiene practices.
Response Wash hands after handling.
Storage Store away from incompatible materials.
Disposal Buyer assumes all risk and liability associated with disposal of this product (original concentration
or dilution) in violation of applicable law in compliance with applicable federal, state and local
requirements.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information Not applicable.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
Other components below reportable levels 90 - 100
2634-33-51,2-Benzisothiazolin-3-one < 0.1
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
1 / 6
Material name: DEFOAMER II
HIL00183 Version #: 01 Issue date: 03-05-2015
SDS US
4. First-aid measures
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact Rinse with water. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Get medical attention if symptoms occur.
Most important
symptoms/effects, acute and
delayed
Direct contact with eyes may cause temporary irritation.
Indication of immediate
medical attention and special
treatment needed
Treat symptomatically.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing
media
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from
the chemical
During fire, gases hazardous to health may be formed.
Special protective equipment
and precautions for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Fire fighting
equipment/instructions
Move containers from fire area if you can do so without risk.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Keep unnecessary personnel away. For personal protection, see section 8 of the SDS.
Methods and materials for
containment and cleaning up
This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling Avoid prolonged exposure. Observe good industrial hygiene practices.
Conditions for safe storage,
including any incompatibilities
Store in original tightly closed container. Store away from incompatible materials (see Section 10
of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits No exposure limits noted for ingredient(s).
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering
controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Individual protection measures, such as personal protective equipment
Eye/face protection Chemical safety goggles when working with concentrate.
Skin protection
Hand protection Use protective gloves when dealing with the concentrate.
2 / 6
Material name: DEFOAMER II
HIL00183 Version #: 01 Issue date: 03-05-2015
SDS US
Other None normally required. If unable to avoid prolonged or repeated contact with skin, wear
impervious clothing.
Respiratory protection Not normally required with adequate ventilation.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene
considerations
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and chemical properties
Appearance White, opaque, viscous liquid
Physical state Liquid.
Form Liquid.
Color Not available.
Odor Non-objectionable
Odor threshold Not available
pH 6 - 9 Concentrate
Melting point/freezing point Not applicable / Not available
Initial boiling point and boiling
range
206 °F (96.67 °C)
Flash point > 200.0 °F (> 93.3 °C) Tag Closed Cup
Evaporation rate < 1 Ethyl ether = 1
Flammability (solid, gas)Not available.
Upper/lower flammability or explosive limits
Explosive limit - lower (%)Not available.
Explosive limit - upper (%)Not available.
Vapor pressure 17.53 mm Hg
Vapor density 0.622 Air =1
Relative density 0.999 at 77°F
Solubility(ies)
Solubility (water)100 % Complete
Partition coefficient
(n-octanol/water)
Not available
Auto-ignition temperature Not available
Decomposition temperature Not available
Viscosity Not available
Other information
Density 8.32 lb/gal
Percent volatile > 98 %
VOC (Weight %)Not available
10. Stability and reactivity
Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous
reactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition
products
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
3 / 6
Material name: DEFOAMER II
HIL00183 Version #: 01 Issue date: 03-05-2015
SDS US
Skin contact No adverse effects due to skin contact are expected.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the
physical, chemical and
toxicological characteristics
Direct contact with eyes may cause temporary irritation.
Information on toxicological effects
Acute toxicity Not available.
Test ResultsProduct Species
DEFOAMER II
LD50 Rabbit
Dermal
Acute
11439.6123 ml/kg estimated
LD50 Guinea pig
Oral
11964.6494 g/kg estimated
Rat 10061.1826 ml/kg estimated
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye
irritation
Direct contact with eyes may cause temporary irritation.
Respiratory or skin sensitization
Respiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -
single exposure
Not classified.
Specific target organ toxicity -
repeated exposure
Not classified.
Aspiration hazard Prolonged inhalation may be harmful.
Chronic effects Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Product Test ResultsSpecies
DEFOAMER II
Aquatic
LC50Fish 15986.6523 mg/l, 96 hours estimatedFish
Components Test ResultsSpecies
* Estimates for product may be based on additional component data not shown.
1,2-Benzisothiazolin-3-one (CAS 2634-33-5)
Aquatic
LC50Fish 8 - 13 mg/l, 96 hoursBleak (Alburnus alburnus)
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Mobility in soil No data available.
4 / 6
Material name: DEFOAMER II
HIL00183 Version #: 01 Issue date: 03-05-2015
SDS US
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Do not
contaminate ponds, waterways or ditches with chemical or used container. Buyer assumes all risk
and liability associated with disposal of this product (original concentration or dilution) in violation
of applicable law.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
products
Empty containers or liners may retain some product residues. This material and its container must
be disposed of in a safe manner (see: Disposal instructions). Waste from normal product use may
be sewered to a public owned treatment works (POTW) in compliance with applicable Federal,
State, and local pretreatment requirements.
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Triple rinse (or equivalent). Then offer clean, dry container for recycling or reconditioning.
14. Transport information
DOT
Not regulated as dangerous goods.
15. Regulatory information
US federal regulations This product is not known to be a "Hazardous Chemical" as defined by the OSHA Hazard
Communication Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List or Exempt.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
No
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Safe Drinking Water Act
(SDWA)
Not regulated.
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. Massachusetts RTK - Substance List
Not regulated.
US. New Jersey Worker and Community Right-to-Know Act
Not listed.
US. Pennsylvania Worker and Community Right-to-Know Law
Not listed.
5 / 6
Material name: DEFOAMER II
HIL00183 Version #: 01 Issue date: 03-05-2015
SDS US
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date 03-05-2015
Version #01
HMIS® ratings Health: 0
Flammability: 0
Physical hazard: 0
Disclaimer No representations or warranties, either express or implied, of merchantability, fitness for a
particular purpose, or of any nature are made with respect to the product(s) or information
contained in this material safety data sheet. The information and recommendations contained in
this Material Safety Data Sheet are supplied pursuant to 29 CFR 1910.1200 of the Occupational
Safety and Health Standards Hazard Communication Rule. All information contained herein is
presented in good faith and is believed to be appropriate and accurate. The buyer or user
assumes all risks associated with the use, misuse or disposal of this product. The buyer or user is
responsible to comply with all federal, state or local regulations concerning the use, misuse or
disposal of these products.
6 / 6
Material name: DEFOAMER II
HIL00183 Version #: 01 Issue date: 03-05-2015
SDS US