HomeMy WebLinkAboutHillyard Nutra RinseSAFETY DATA SHEET
1. Identification
Product identifier NUTRA-RINSE
Other means of identification
SDS number 538N-76A
Product code HIL00219
Recommended use Concentrated Neutral Cleaner
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Manufacturer
Company name HILLYARD INDUSTRIES
Address 302 North Fourth St.
St. Joseph, MO 64501
Contact person Regulatory Affairs
Telephone number (816) 233-1321 (Ext. 8285)
Fax (816) 383-8485
E-mail regulatoryaffairs@hillyard.com
Emergency telephone #(800) 424-9300
(Only in the event of chemical emergency involving a spill, leak, fire, exposure,
or accident involving chemicals.)
2. Hazard(s) identification
Not classified.Physical hazards
Category 2Skin corrosion/irritationHealth hazards
Category 2ASerious eye damage/eye irritation
Not classified.Environmental hazards
Not classified.OSHA defined hazards
Label elements
Signal word Warning
Hazard statement Causes skin irritation. Causes serious eye irritation.
Precautionary statement
Prevention Wash thoroughly after handling. Wear protective gloves. Wear eye/face protection.
Response If on skin: Wash with plenty of water. If in eyes: Rinse cautiously with water for several minutes.
Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment (see this
label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical
advice/attention. Take off contaminated clothing and wash before reuse.
Storage Store away from incompatible materials.
Disposal Dispose of waste and residues in accordance with local authority requirements.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information Not applicable.
3. Composition/information on ingredients
Mixtures
Hazardous components
CAS number %Chemical name
60-00-4Ethylenediaminetetraacetic
Acid
5 - < 10
68439-46-3Alcohols, C9-11, ethoxylated 1 - < 3
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Material name: NUTRA-RINSE
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SDS US
Hazardous components
CAS number %Chemical name
67-63-0Isopropyl Alcohol 1 - < 3
1310-73-2SODIUM HYDROXIDE
Other components below reportable levels 80 - < 90
1 - < 3
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact Wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Take off
contaminated clothing and wash before reuse.
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists.
Ingestion Rinse mouth. Get medical attention if symptoms occur.
Most important
symptoms/effects, acute and
delayed
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
cause redness and pain.
Indication of immediate
medical attention and special
treatment needed
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing
media
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from
the chemical
During fire, gases hazardous to health may be formed.
Special protective equipment
and precautions for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Fire-fighting
equipment/instructions
Move containers from fire area if you can do so without risk.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Wear appropriate protective equipment and clothing during clean-up. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ensure
adequate ventilation. Local authorities should be advised if significant spillages cannot be
contained. For personal protection, see section 8 of the SDS.
Methods and materials for
containment and cleaning up
This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers. Prevent entry into waterways, sewer, basements or confined areas.
Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling Avoid contact with skin. Avoid contact with eyes. Avoid prolonged exposure. Avoid contact with
clothing. Provide adequate ventilation. Wear appropriate personal protective equipment. Observe
good industrial hygiene practices.
Conditions for safe storage,
including any incompatibilities
Store in original tightly closed container. Store away from incompatible materials (see Section 10
of the SDS).
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Material name: NUTRA-RINSE
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SDS US
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents Type
PEL 980 mg/m3Isopropyl Alcohol (CAS
67-63-0)
400 ppm
PEL 2 mg/m3SODIUM HYDROXIDE
(CAS 1310-73-2)
US. ACGIH Threshold Limit Values
ValueComponents Type
STEL 400 ppmIsopropyl Alcohol (CAS
67-63-0)
TWA 200 ppm
Ceiling 2 mg/m3SODIUM HYDROXIDE
(CAS 1310-73-2)
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents Type
STEL 1225 mg/m3Isopropyl Alcohol (CAS
67-63-0)
500 ppm
TWA 980 mg/m3
400 ppm
Ceiling 2 mg/m3SODIUM HYDROXIDE
(CAS 1310-73-2)
Biological limit values
ACGIH Biological Exposure Indices
ValueComponents Determinant Specimen Sampling Time
40 mg/l Acetone Urine *Isopropyl Alcohol (CAS
67-63-0)
* - For sampling details, please see the source document.
Appropriate engineering
controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Eye
wash facilities and emergency shower must be available when handling this product.
Individual protection measures, such as personal protective equipment
Eye/face protection Where splashing of concentrate is a concern, use protective glasses with side shield.
Skin protection
Hand protection For prolonged or repeated skin contact use suitable protective gloves.
Other No special protective equipment required.
Respiratory protection No personal respiratory protective equipment normally required.
Thermal hazards Wear appropriate thermal protective clothing, when necessary.
General hygiene
considerations
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and chemical properties
Appearance Clear, blue liquid
Physical state Liquid.
Form Liquid.
Color Blue
Odor non-objectionable odor
Odor threshold Not available
pH 6 - 7
Melting point/freezing point Not available
Initial boiling point and boiling
range
209 °F (98.33 °C)
Flash point > 200.0 °F (> 93.3 °C)
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Material name: NUTRA-RINSE
HIL00219 Version #: 01 Issue date: 09-26-2014
SDS US
Evaporation rate < 1 Ethyl ether = 1
Flammability (solid, gas)Not available.
Upper/lower flammability or explosive limits
Explosive limit - lower (%)Not available.
Explosive limit - upper (%)Not available.
Vapor pressure 17.53 mm Hg
Vapor density 0.62 AIR=1
Relative density 1.051 at 77°F
Solubility(ies)
Solubility (water)100 % Complete
Partition coefficient
(n-octanol/water)
Not available
Auto-ignition temperature Not available
Decomposition temperature Not available
Viscosity Not available
Other information
Density 8.75 lb/gal
Percent volatile 87.5 - 89 %
VOC (Weight %)1 %
10. Stability and reactivity
Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous
reactions
Hazardous polymerization does not occur.
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition
products
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Ingestion Expected to be a low ingestion hazard.
Inhalation Prolonged inhalation may be harmful.
Skin contact Causes skin irritation.
Eye contact Causes serious eye irritation.
Symptoms related to the
physical, chemical and
toxicological characteristics
Symptoms may include stinging, tearing, redness, swelling, and blurred vision. Skin irritation. May
cause redness and pain.
Information on toxicological effects
Acute toxicity
Test ResultsProduct Species
NUTRA-RINSE (CAS Mixture)
LD50 Rabbit
Dermal
Acute
9756.0977 ml/kg estimated
LD50 Guinea pig
Oral
2728.6821 g/kg estimated
Mouse 404.3368 mg/kg estimated
Rabbit 503 g/kg estimated
Rat 7219.5122 ml/kg estimated
403.925 g/kg estimated
LD50 Mouse
Other
1446.1852 mg/kg estimated
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Material name: NUTRA-RINSE
HIL00219 Version #: 01 Issue date: 09-26-2014
SDS US
Test ResultsProduct Species
Rat 5080.4063 mg/kg estimated
* Estimates for product may be based on additional component data not shown.
Skin corrosion/irritation Causes skin irritation.
Serious eye damage/eye
irritation
Causes serious eye irritation.
Respiratory or skin sensitization
Respiratory sensitization Not available.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -
single exposure
Not classified.
Specific target organ toxicity -
repeated exposure
Not classified.
Aspiration hazard Not available.
Chronic effects Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential No data available.
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Dispose of
contents/container in accordance with local/regional/national/international regulations.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
products
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Contaminated packaging Empty containers should be taken to an approved waste handling site for recycling or disposal.
Since emptied containers may retain product residue, follow label warnings even after container is
emptied.
14. Transport information
DOT
Not regulated as dangerous goods.
IATA
Not regulated as dangerous goods.
IMDG
Not regulated as dangerous goods.
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Ethylenediaminetetraacetic Acid (CAS 60-00-4) Listed.
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Material name: NUTRA-RINSE
HIL00219 Version #: 01 Issue date: 09-26-2014
SDS US
SODIUM HYDROXIDE (CAS 1310-73-2) Listed.
SARA 304 Emergency release notification
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely
hazardous substance
No
SARA 311/312 Hazardous
chemical
No
SARA 313 (TRI reporting)
Not regulated.
US state regulations
US. Massachusetts RTK - Substance List
Ethylenediaminetetraacetic Acid (CAS 60-00-4)
Isopropyl Alcohol (CAS 67-63-0)
SODIUM HYDROXIDE (CAS 1310-73-2)
US. New Jersey Worker and Community Right-to-Know Act
Not regulated.
US. Pennsylvania RTK - Hazardous Substances
Ethylenediaminetetraacetic Acid (CAS 60-00-4)
Isopropyl Alcohol (CAS 67-63-0)
SODIUM HYDROXIDE (CAS 1310-73-2)
US. Rhode Island RTK
Ethylenediaminetetraacetic Acid (CAS 60-00-4)
Isopropyl Alcohol (CAS 67-63-0)
SODIUM HYDROXIDE (CAS 1310-73-2)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date 09-26-2014
Version #01
HMIS® ratings Health: 2
Flammability: 0
Physical hazard: 0
Disclaimer No representations or warranties, either express or implied, of merchantability, fitness for a
particular purpose, or of any nature are made with respect to the product(s) or information
contained in this material safety data sheet. The information and recommendations contained in
this Material Safety Data Sheet are supplied pursuant to 29 CFR 1910.1200 of the Occupational
Safety and Health Standards Hazard Communication Rule. All information contained herein is
presented in good faith and is believed to be appropriate and accurate. The buyer or user
assumes all risks associated with the use, misuse or disposal of this product. The buyer or user is
responsible to comply with all federal, state or local regulations concerning the use, misuse or
disposal of these products.
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Material name: NUTRA-RINSE
HIL00219 Version #: 01 Issue date: 09-26-2014
SDS US