HomeMy WebLinkAboutHillyard Super Shine AllSAFETY DATA SHEET
1. Identification
Product identifier SUPER SHINE-ALL
Other means of identification
SDS number 476N84A
Product code HIL00140
Recommended use Neutral Cleaner
Recommended restrictions None known.
Manufacturer/Importer/Supplier/Distributor information
Manufacturer
Manufacturer
Company name HILLYARD INDUSTRIES
Address 302 North Fourth St.
St. Joseph, MO 64501
Contact person Regulatory Affairs
Telephone number (816) 233-1321 (Ext. 8285)
Fax (816) 383-8485
E-mail regulatoryaffairs@hillyard.com
Emergency telephone #(800) 424-9300
(Only in the event of chemical emergency involving a spill, leak, fire, exposure,
or accident involving chemicals.)
2. Hazard(s) identification
Not classified.Physical hazards
Category 2BSerious eye damage/eye irritationHealth hazards
Not classified.Environmental hazards
Not classified.OSHA defined hazards
Label elements
None.Hazard symbol
Signal word Warning
Hazard statement Causes eye irritation.
Precautionary statement
Prevention Wash thoroughly after handling. Observe good industrial hygiene practices.
Response If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Storage Store away from incompatible materials.
Disposal Buyer assumes all risk and liability associated with disposal of this product (original concentration
or dilution) in violation of applicable law. Waste from normal use may be sewered to a
public-owned treatment works in compliance with applicable federal, state and local requirements.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information Do not get in eyes, on skin, or on clothing. Avoid breathing spray mist. Use with adequate
ventilation. Wash thoroughly after handling. Do not take internally. Keep container closed when
not in use. If prolonged or repeated contact is possible, wear rubber or other impervious gloves
and splash goggles. Use only as directed: Improper dilution can lead to adverse health effects.
3. Composition/information on ingredients
Mixtures
CAS number %Chemical name Common name and synonyms
76-22-2Camphor 0.003
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Material name: SUPER SHINE-ALL
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CAS number %Chemical name Common name and synonyms
Other components below reportable levels 99.99874
80-56-8Pin-2(3)-ene 0.0009
Additional components
CAS number %Chemical name
Fatty Acids, Tall-oil, Triethanolamine Salts 67784-78-5 2 - < 3.05
Tall Oil, Potassium Salt 68647-71-2 0.5 - < 1
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Inhalation Move to fresh air. Call a physician if symptoms develop or persist.
Skin contact Wash off with soap and water. Get medical attention if irritation develops and persists.
Eye contact Immediately flush with plenty of water for at least 15 minutes. If easy to do, remove contact lenses.
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention.
Ingestion Rinse mouth. Get medical attention if symptoms occur.
Most important
symptoms/effects, acute and
delayed
Irritation of eyes. Exposed individuals may experience eye tearing, redness, and discomfort.
Indication of immediate
medical attention and special
treatment needed
Provide general supportive measures and treat symptomatically. Keep victim under observation.
Symptoms may be delayed.
General information Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
5. Fire-fighting measures
Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Unsuitable extinguishing
media
Do not use water jet as an extinguisher, as this will spread the fire.
Specific hazards arising from
the chemical
During fire, gases hazardous to health may be formed.
Special protective equipment
and precautions for firefighters
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.
Fire fighting
equipment/instructions
Move containers from fire area if you can do so without risk.
Specific methods Use standard firefighting procedures and consider the hazards of other involved materials.
General fire hazards No unusual fire or explosion hazards noted.
6. Accidental release measures
Personal precautions,
protective equipment and
emergency procedures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Wear
appropriate protective equipment and clothing during clean-up. Do not touch damaged containers
or spilled material unless wearing appropriate protective clothing. Ensure adequate ventilation.
Local authorities should be advised if significant spillages cannot be contained. For personal
protection, see section 8 of the SDS.
Methods and materials for
containment and cleaning up
This product is miscible in water.
Large Spills: Stop the flow of material, if this is without risk. Dike the spilled material, where this is
possible. Cover with plastic sheet to prevent spreading. Absorb in vermiculite, dry sand or earth
and place into containers. Following product recovery, flush area with water.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination.
Never return spills to original containers for re-use. For waste disposal, see section 13 of the SDS.
Environmental precautions Avoid discharge into drains, water courses or onto the ground.
7. Handling and storage
Precautions for safe handling Avoid contact with eyes. Avoid prolonged exposure. Provide adequate ventilation. Wear
appropriate personal protective equipment. Observe good industrial hygiene practices.
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Conditions for safe storage,
including any incompatibilities
Store in original tightly closed container. Store away from incompatible materials (see Section 10
of the SDS).
8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents Type
PEL 2 mg/m3Camphor (CAS 76-22-2)
US. ACGIH Threshold Limit Values
ValueComponents Type
STEL 3 ppmCamphor (CAS 76-22-2)
TWA 2 ppm
TWA 20 ppmPin-2(3)-ene (CAS 80-56-8)
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents Type
TWA 2 mg/m3Camphor (CAS 76-22-2)
Biological limit values No biological exposure limits noted for the ingredient(s).
Appropriate engineering
controls
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level. Provide
eyewash station.
Individual protection measures, such as personal protective equipment
Eye/face protection Chemical splash goggles where there is a potential for eye contact.
Skin protection
Hand protection For prolonged or repeated skin contact use suitable protective gloves.
Other Not available.
Respiratory protection Not normally needed.
Thermal hazards Not applicable.
General hygiene
considerations
Always observe good personal hygiene measures, such as washing after handling the material
and before eating, drinking, and/or smoking. Routinely wash work clothing and protective
equipment to remove contaminants.
9. Physical and chemical properties
Appearance Light amber liquid
Physical state Liquid.
Form Liquid.
Color Light Amber, Will darken with age.
Odor Sassafras odor
Odor threshold Not available
pH 9 - 9.3
8 - 9 (diluted 1:128)
Melting point/freezing point Not available
Initial boiling point and boiling
range
205 °F (96.11 °C)
Flash point > 205.0 °F (> 96.1 °C) Tag Closed Cup
Evaporation rate < 1 Ethyl ether = 1
Flammability (solid, gas)Not available.
Upper/lower flammability or explosive limits
Explosive limit - lower (%)Not available.
Explosive limit - upper (%)Not available.
Vapor pressure 17.6 mm Hg
Vapor density 0.6 Air=1
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Material name: SUPER SHINE-ALL
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Relative density 1.008 at 77°F
Solubility(ies)
Solubility (water)100 % Complete
Partition coefficient
(n-octanol/water)
Not available
Auto-ignition temperature Not available
Decomposition temperature Not available
Viscosity Not available
Other information
Density 8.39 lb/gal
Percent volatile 87 - 88 %
VOC (Weight %)0.62 %
10. Stability and reactivity
Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport.
Chemical stability Material is stable under normal conditions.
Possibility of hazardous
reactions
No dangerous reaction known under conditions of normal use.
Conditions to avoid Avoid temperatures exceeding the flash point. Contact with incompatible materials.
Incompatible materials Strong oxidizing agents.
Hazardous decomposition
products
No hazardous decomposition products are known.
11. Toxicological information
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact No adverse effects due to skin contact are expected.
Eye contact Causes eye irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the
physical, chemical and
toxicological characteristics
Irritation of eyes. Exposed individuals may experience eye tearing, redness, and discomfort.
Information on toxicological effects
Acute toxicity
Test ResultsProduct Species
SUPER SHINE-ALL
LC50 Mouse
Inhalation
Acute
72543.4688 mg/l, 4 Hours estimated
LD50 Guinea pig
Oral
21960.7852 g/kg estimated
Rat 24313.7246 g/kg estimated
Test ResultsComponents Species
Camphor (CAS 76-22-2)
LD50 Mouse
Oral
Acute
1310 mg/kg
Pin-2(3)-ene (CAS 80-56-8)
LD50 Rat
Oral
Acute
3700 mg/kg
* Estimates for product may be based on additional component data not shown.
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Skin corrosion/irritation Prolonged skin contact may cause temporary irritation.
Serious eye damage/eye
irritation
Causes eye irritation.
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
Skin sensitization This product is not expected to cause skin sensitization.
Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity This product is not expected to cause reproductive or developmental effects.
Specific target organ toxicity -
single exposure
Not classified.
Specific target organ toxicity -
repeated exposure
Not classified.
Aspiration hazard Prolonged inhalation may be harmful.
Chronic effects Prolonged inhalation may be harmful.
12. Ecological information
Ecotoxicity The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Product Test ResultsSpecies
SUPER SHINE-ALL
Aquatic
EC50Crustacea 4232213 mg/l, 48 hours estimatedDaphnia
* Estimates for product may be based on additional component data not shown.
LC50Fish 4597756.5 mg/l, 96 hours estimatedFish
Persistence and degradability No data is available on the degradability of this product.
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
Pin-2(3)-ene 4.83
Mobility in soil No data available.
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Disposal instructions Buyer assumes all risk and liability associated with disposal of this product (original concentration
or dilution) in violation of applicable law. Do not contaminate ponds, waterways or ditches with
chemical or used container.
Local disposal regulations Dispose in accordance with all applicable regulations.
Hazardous waste code The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Waste from residues / unused
products
Dispose of in accordance with local regulations. Waste from normal product use may be sewered
to a public owned treatment works (POTW) in compliance with applicable Federal, State, and local
pretreatment requirements.
Contaminated packaging Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Triple rinse (or equivalent). Then offer clean, dry container for recycling or reconditioning.
14. Transport information
DOT
Not regulated as dangerous goods.
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Material name: SUPER SHINE-ALL
HIL00140 Version #: 01 Issue date: 03-11-2015
SDS US
15. Regulatory information
US federal regulations This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories Immediate Hazard - Yes
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - No
Reactivity Hazard - No
SARA 302 Extremely hazardous substance
Not listed.
SARA 311/312 Hazardous
chemical
No
SARA 313 (TRI reporting)
Not regulated.
Other federal regulations
Safe Drinking Water Act
(SDWA)
Not regulated.
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. Massachusetts RTK - Substance List
Camphor (CAS 76-22-2)
Pin-2(3)-ene (CAS 80-56-8)
US. New Jersey Worker and Community Right-to-Know Act
Camphor (CAS 76-22-2)
Pin-2(3)-ene (CAS 80-56-8)
US. Pennsylvania Worker and Community Right-to-Know Law
Camphor (CAS 76-22-2)
Pin-2(3)-ene (CAS 80-56-8)
US. Rhode Island RTK
Not regulated.
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
Issue date 03-11-2015
Version #01
Further information This product meets Green Seal™ Standard GS-37 based on effective performance, concentrated
volume, minimized/recycled packaging, and protective limits on VOCs and human & environmental
toxicity. GreenSeal.org.
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Material name: SUPER SHINE-ALL
HIL00140 Version #: 01 Issue date: 03-11-2015
SDS US
HMIS® ratings Health: 1
Flammability: 0
Physical hazard: 0
Disclaimer No representations or warranties, either express or implied, of merchantability, fitness for a
particular purpose, or of any nature are made with respect to the product(s) or information
contained in this material safety data sheet. The information and recommendations contained in
this Material Safety Data Sheet are supplied pursuant to 29 CFR 1910.1200 of the Occupational
Safety and Health Standards Hazard Communication Rule. All information contained herein is
presented in good faith and is believed to be appropriate and accurate. The buyer or user
assumes all risks associated with the use, misuse or disposal of this product. The buyer or user is
responsible to comply with all federal, state or local regulations concerning the use, misuse or
disposal of these products.
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Material name: SUPER SHINE-ALL
HIL00140 Version #: 01 Issue date: 03-11-2015
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