HomeMy WebLinkAboutSpartan Foamy Q and ARevision Date: 30-Jul-2015
Safety Data Sheet
Spartan Chemical Company, Inc.
1. PRODUCT AND COMPANY IDENTIFICATION
Product Identifier
Product Name:FOAMY Q&A
Product Number:3200 , 3202
Recommended Use:Disinfectant
Uses Advised Against:For Industrial and Institutional Use Only
Manufacturer/Supplier:Spartan Chemical Company, Inc.
1110 Spartan Drive
Maumee, Ohio 43537 USA
800-537-8990 (Business hours)
www.spartanchemical.com
24 Hour Emergency Phone Numbers:
Medical Emergency/Information:888-314-6171
Transportation/Spill/Leak:CHEMTREC 800-424-9300
2. HAZARDS IDENTIFICATION
GHS Classification
Skin Corrosion/Irritation:Category 1
Serious Eye Damage/Eye Irritation:Category 1
GHS Label Elements
Signal Word:Danger
Hazard Statements:Causes severe skin burns and serious eye damage.
May be corrosive to metals.
Precautionary Statements:
Prevention:Do not breathe mist, vapors or spray.
Wash hands and any exposed skin thoroughly after handling.
Wear protective gloves. Wear eye / face protection. Wear protective clothing.
Keep in original or other corrosion resistant container.
Response:IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
-Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
-Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water
or shower. Wash contaminated clothing before reuse.
-Inhalation:IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
-Ingestion:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
-Specific Treatment:See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information.
Spill:
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Absorb spillage to prevent material damage.
Storage:Store locked up. Store in corrosion resistant container.
Corrosive to Metals:
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Category 1
Symbols:
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3200 - FOAMY Q&A Revision Date: 30-Jul-2015
Disposal:Dispose of contents and container in accordance with local, state and federal regulations.
Hazards Not Otherwise Classified:Not Applicable
Other Information:• Corrosive.
• Harmful if swallowed
• Inhalation of vapors or mist may cause respiratory irritation.
• Keep out of reach of children.
• NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric
lavage.
1.81388% of the mixture consists of ingredient(s) of unknown toxicity.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-%
water 7732-18-5 60-100
phosphoric acid 7664-38-2 7-13
diethylene glycol monobutyl ether 112-34-5 1-5
hydroxyacetic acid 79-14-1 1-5
alcohol ethoxylate 68439-46-3 1-5
cocamidopropyl hydroxysultaine 70851-08-0 1-5
alkyl dimethyl benzyl ammonium chloride 68424-85-1 0.1-1
Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
-Eye Contact:Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
-Skin Contact:Take off immediately all contaminated clothing and shoes. Rinse with water or shower for
at least 15 minutes. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. Wash
contaminated clothing before reuse.
-Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
-Ingestion:Rinse mouth. Do NOT induce vomiting. IMMEDIATELY CALL A POISON CENTER OR
PHYSICIAN. Never give anything by mouth to an unconscious person.
Note to Physicians:NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric
lavage.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media:Product does not support combustion, Use extinguishing agent suitable for type of
surrounding fire
Specific Hazards Arising from the
Chemical:
Contact with metals may evolve flammable hydrogen gas. Dried product is capable of
burning.
Hazardous Combustion Products:May include Carbon monoxide Carbon dioxide and other toxic gases or vapors.
Protective Equipment and
Precautions for Firefighters:
Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full
protective gear. Cool fire-exposed containers with water spray.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions:
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Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Environmental Precautions:Do not rinse spill onto the ground, into storm sewers or bodies of water.
Methods for Clean-Up:
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Prevent further leakage or spillage if safe to do so. Contain and collect spillage with
non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and place in container for disposal according to local / national regulations (see Section 13).
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3200 - FOAMY Q&A Revision Date: 30-Jul-2015
7. HANDLING AND STORAGE
Advice on Safe Handling:Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly
after handling.
Storage Conditions:Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach
of children. Keep from freezing.
Incompatible Materials:Sodium hypochlorite (or other hypochlorites). Strong bases. Reactive metals such as
aluminum, zinc and tin.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits:.
Chemical Name ACGIH TLV OSHA PEL NIOSH
phosphoric acid
7664-38-2
STEL: 3 mg/m3
TWA: 1 mg/m3
TWA: 1 mg/m3
(vacated) TWA: 1 mg/m3
(vacated) STEL: 3 mg/m3
IDLH: 1000 mg/m3
TWA: 1 mg/m3
STEL: 3 mg/m3
Engineering Controls:Provide good general ventilation.
If work practices generate dust, fumes, gas, vapors or mists which expose workers to
chemicals above the occupational exposure limits, local exhaust ventilation or other
engineering controls should be considered.
Eye wash stations and shower facilities should be readily accessible in areas where the
product is handled.
Personal Protective Equipment
Eye/Face Protection:Wear splash goggles.
Skin and Body Protection:Wear rubber or other chemical-resistant gloves.
Respiratory Protection:Not required with expected use.
If occupational exposure limits are exceeded or respiratory irritation occurs, use of a
NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section
3 should be considered.
General Hygiene Considerations:Wash hands and any exposed skin thoroughly after handling.
See 29 CFR 1910.132-138 for further guidance.
10. STABILITY AND REACTIVITY
Reactivity:This material is considered to be non-reactive under normal conditions of use.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance/Physical State:Liquid
Color:Purple
Odor:Pleasant
pH:< 2
Melting Point / Freezing Point:No information available.
Boiling Point / Boiling Range:100 °C / 212 °F
Flash Point:> 100 °C / > 212 °F ASTM D56
Evaporation Rate:< 1 (BuAc = 1)
Flammability (solid, gas)No information available.
Upper Flammability Limit:No information available.
Lower Flammability Limit:No information available.
Vapor Pressure:No information available.
Vapor Density:No information available.
Specific Gravity:1.09
Solubility(ies):Soluble in water
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Partition Coefficient:No information available.
Autoignition Temperature:No information available.
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Decomposition Temperature:No information available.
Viscosity:No information available.
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3200 - FOAMY Q&A Revision Date: 30-Jul-2015
Chemical Stability:Stable under normal conditions.
Possibility of Hazardous Reactions:Not expected to occur with normal handling and storage.
Conditions to Avoid:Extremes of temperature and direct sunlight.
Incompatible Materials:Sodium hypochlorite (or other hypochlorites). Strong bases. Reactive metals such as
aluminum, zinc and tin.
Hazardous Decomposition
Products:
May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors.
11. TOXICOLOGICAL INFORMATION
Likely Routes of Exposure:Eyes, Skin, Ingestion, Inhalation.
Symptoms of Exposure:
-Eye Contact:Pain, redness, swelling of the conjunctiva and tissue damage. Eye contact may cause
permanent damage.
-Skin Contact:Pain, redness, blistering and possible chemical burn.
-Inhalation:Irritation or damage to the mucus membranes of the respiratory tract. Nasal discomfort and
coughing.
-Ingestion:Damage or chemical burns to mouth, throat and stomach. Pain, nausea, vomiting and
diarrhea.
Immediate, Delayed, Chronic Effects
Product Information:Data not available or insufficient for classification.
Target Organ Effects:-Eyes. Respiratory System. -Skin.
Numerical Measures of Toxicity
The following acute toxicity estimates (ATE) are calculated based on the GHS document.
.
ATEmix (oral):5729 mg/kg
ATEmix (dermal):11716 mg/kg
ATEmix (inhalation-dust/mist):203.3 mg/l
Component Acute Toxicity Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
water
7732-18-5
> 90 mL/kg ( Rat )Not Available Not Available
phosphoric acid
7664-38-2
= 1530 mg/kg ( Rat )= 2730 mg/kg ( Rabbit )> 850 mg/m3 ( Rat ) 1 h
diethylene glycol monobutyl ether
112-34-5
= 3384 mg/kg ( Rat )= 2700 mg/kg ( Rabbit )Not Available
hydroxyacetic acid
79-14-1
= 1950 mg/kg ( Rat )Not Available = 7.7 mg/L ( Rat ) 4 h
alcohol ethoxylate
68439-46-3
= 1378 mg/kg ( Rat )> 2 g/kg ( Rabbit )Not Available
alkyl dimethyl benzyl ammonium
chloride
68424-85-1
= 426 mg/kg ( Rat )Not Available Not Available
Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Chemical Name Algae/Aquatic Plants Fish Toxicity to
Microorganisms
Crustacea
phosphoric acid
7664-38-2
Not Available 3 - 3.5: 96 h Gambusia
affinis mg/L LC50
Not Available 4.6: 12 h Daphnia magna
mg/L EC50
diethylene glycol monobutyl
ether
112-34-5
100: 96 h Desmodesmus
subspicatus mg/L EC50
1300: 96 h Lepomis
macrochirus mg/L LC50
static
Not Available 2850: 24 h Daphnia magna
mg/L EC50 100: 48 h
Daphnia magna mg/L EC50
hydroxyacetic acid
79-14-1
Not Available 5000: 96 h Brachydanio rerio
mg/L LC50 static
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Not Available Not Available
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Persistence and Degradability: No information available.
Bioaccumulation: No information available.
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3200 - FOAMY Q&A Revision Date: 30-Jul-2015
Other Adverse Effects: No information available.
13. DISPOSAL CONSIDERATIONS
Disposal of Wastes:Dispose of in accordance with federal, state and local regulations.
Contaminated Packaging:Dispose of in accordance with federal, state and local regulations.
US EPA Waste Number:D002
14. TRANSPORT INFORMATION
DOT: Not Regulated
Proper Shipping Name:Non Hazardous Product
Special Provisions:Shipping descriptions may vary based on mode of transport, quantities, package size,
and/or origin and destination. Check with a trained hazardous materials transportation
expert for information specific to your situation.
IMDG: Not Regulated
Proper Shipping Name:Non Hazardous Product
15. REGULATORY INFORMATION
TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory)
All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances.
SARA 313
This product contains the following listed substances:
diethylene glycol monobutyl ether
CAS No 112-34-5 applies to R-(OCH2CH2)n-OR', where n = 1, 2, or 3, R=Alkyl C7 or less, or R = Phenyl or Alkyl substituted
phenyl, R' = H or Alkyl C7 or less, or OR' consisting of Carboxylic acid ester, Sulfate, Phosphate, Nitrate, or Sulfonate, Chemical
Category N230
SARA 311/312 Hazard Categories
Acute Health Hazard:Yes
Chronic Health Hazard:No
Fire Hazard:No
Sudden release of pressure hazard:No
Reactive Hazard:No
California Proposition 65
This product is not subject to warning requirements under California Proposition 65.
EPA Pesticide Registration Number:5741-23
EPA Statement:
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required
for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the
pesticide label:
EPA Pesticide Label:Danger. Corrosive. Causes irreversible eye damage or skin burns. May be fatal if swallowed. Harmful if absorbed through the skin or inhaled. Do
not get in eyes, on skin or on clothing. Avoid breathing spray mist. Wear goggles or face shield. Wear protective clothing and rubber gloves.
Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco, or using the toilet. Remove
contaminated clothing and wash clothing before reuse.
16. OTHER INFORMATION
Revision Date:30-Jul-2015
NFPA Health Hazards: 3
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Flammability: 0 Instability: 0 Special: N/A
HMIS
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Health Hazards: 3 Flammability: 0 Physical Hazards: 0
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3200 - FOAMY Q&A Revision Date: 30-Jul-2015
Reasons for Revision:Section 14 and 15
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Disclaimer:
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
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