HomeMy WebLinkAboutSpartan Graffiti Remover SACRevision Date: 10-Aug-2015
Safety Data Sheet
Spartan Chemical Company, Inc.
1. PRODUCT AND COMPANY IDENTIFICATION
Product Identifier
Product Name:GRAFFITI REMOVER SAC
Product Number:3071 , 3171
Recommended Use:Cleaning agent
Uses Advised Against:For Industrial and Institutional Use Only
Manufacturer/Supplier:Spartan Chemical Company, Inc.
1110 Spartan Drive
Maumee, Ohio 43537 USA
800-537-8990 (Business hours)
www.spartanchemical.com
24 Hour Emergency Phone Numbers:
Medical Emergency/Information:888-314-6171
Transportation/Spill/Leak:CHEMTREC 800-424-9300
2. HAZARDS IDENTIFICATION
GHS Classification
Acute Toxicity - Oral:Category 4
Serious Eye Damage/Eye Irritation:Category 1
Specific Target Organ Toxicity (Single
Exposure):
Category 3
Aspiration Toxicity:Category 1
GHS Label Elements
Signal Word:Danger
Hazard Statements:Harmful if swallowed.
Causes serious eye damage
May cause respiratory irritation
May be fatal if swallowed and enters airways
Combustible liquid
Precautionary Statements:
Prevention:
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Wash hands and any exposed skin thoroughly after handling.
Do not eat, drink or smoke when using this product
Wear eye / face protection
Wear protective gloves
Avoid breathing dust/fume/gas/mist/vapors/spray
Use only outdoors or in a well-ventilated area.
Keep away from heat/sparks/open flames/hot surfaces. — No smoking
Response:
Flammable Liquids
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Category 4
Symbols:
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3071 - GRAFFITI REMOVER SAC Revision Date: 10-Aug-2015
-Eyes IF IN EYES: IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. Rinse cautiously
with water for several minutes. Remove contact lenses, if present and easy to do. Continue
rinsing.
-Inhalation:IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing. Call a POISON CENTER or doctor/physician if you feel unwell
-Ingestion:IF SWALLOWED: IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. Do NOT
induce vomiting. Rinse mouth.
-Specific Treatment:See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information.
Fire:In case of fire: Use CO2, dry chemical, or foam for extinction
Storage:Store locked up. Store in a well-ventilated place. Keep container tightly closed.
Disposal:Dispose of contents and container in accordance with local, state and federal regulations.
Hazards Not Otherwise Classified:Not Applicable
Other Information:• May cause skin irritation.
• Contains petroleum distillates. Possible aspiration hazard.
• Keep out of reach of children.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-%
soybean oil methyl esters 67784-80-9 15-40
ethyl lactate 97-64-3 15-40
petroleum distillates 64742-47-8 15-40
alcohol ethoxylate 34398-01-1 5-10
1-undecanol 112-42-5 1-5
Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
-Eye Contact:Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
-Skin Contact:Wash with soap and water. If skin irritation occurs: Get medical attention.
-Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a
poison control center or physician if you feel unwell.
-Ingestion:IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. Do NOT induce vomiting.
Rinse mouth.
Note to Physicians:Contains petroleum distillates. Possible aspiration hazard.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media:Dry chemical, CO2, water spray or regular foam, Move containers from fire area if you can
do it without risk
Specific Hazards Arising from the
Chemical:
Thermal decomposition can lead to release of toxic/corrosive gases and vapors.
Hazardous Combustion Products:May include Carbon monoxide Carbon dioxide and other toxic gases or vapors.
Protective Equipment and
Precautions for Firefighters:
Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full
protective gear. Cool fire-exposed containers with water spray.
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6. ACCIDENTAL RELEASE MEASURES
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Personal Precautions:Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Remove all sources of ignition.
Environmental Precautions:Do not rinse spill onto the ground, into storm sewers or bodies of water.
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3071 - GRAFFITI REMOVER SAC Revision Date: 10-Aug-2015
Methods for Clean-Up:Prevent further leakage or spillage if safe to do so. Contain and collect spillage with
non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and place in container for disposal according to local / national regulations (see Section 13).
Rags, towels or mops soaked with this product are subject to spontaneous combustion if
not handled properly. Thoroughly rinse these materials with water to remove product before
disposal or discard in special containers designed for this purpose.
7. HANDLING AND STORAGE
Advice on Safe Handling:Handle in accordance with good industrial hygiene and safety practice. Use personal
protective equipment as required. Keep away from heat/sparks/open flames/hot surfaces.
— No smoking. All equipment used when handling the product must be grounded. Rags,
towels or mops soaked with this product are subject to spontaneous combustion if not
handled properly. Thoroughly rinse these materials with water to remove product before
disposal or discard in special containers designed for this purpose.
Storage Conditions:Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from
heat/sparks/open flames/hot surfaces. — No smoking. Do not store above 125°F. Product
will expand and may cause container to swell and possibly rupture. In case of container
expansion, carefully vent container.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits:None established.
Engineering Controls:Provide good general ventilation.
If work practices generate dust, fumes, gas, vapors or mists which expose workers to
chemicals above the occupational exposure limits, local exhaust ventilation or other
engineering controls should be considered.
Personal Protective Equipment
Eye/Face Protection:
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Wear splash goggles.
Skin and Body Protection:Wear rubber or other chemical-resistant gloves. (neoprene or nitrile is recommended).
Respiratory Protection:
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Not required with expected use.
If occupational exposure limits are exceeded or respiratory irritation occurs, use of a
NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section
3 should be considered.
General Hygiene Considerations:Wash hands and any exposed skin thoroughly after handling.
See 29 CFR 1910.132-138 for further guidance.
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3071 - GRAFFITI REMOVER SAC Revision Date: 10-Aug-2015
10. STABILITY AND REACTIVITY
Reactivity:This material is considered to be non-reactive under normal conditions of use.
Chemical Stability:Stable under normal conditions.
Possibility of Hazardous Reactions:Not expected to occur with normal handling and storage.
Conditions to Avoid:Heat, flames and sparks.
Incompatible Materials:Strong oxidizing agents. Strong acids.
Hazardous Decomposition
Products:
May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors.
11. TOXICOLOGICAL INFORMATION
Likely Routes of Exposure:Eyes, Skin, Ingestion, Inhalation.
Symptoms of Exposure:
-Eye Contact:Pain, redness, swelling of the conjunctiva and tissue damage. Eye contact may cause
permanent damage.
-Skin Contact:Drying of the skin.
-Inhalation:Nasal discomfort and coughing.
-Ingestion:Harmful if swallowed. Pain, nausea, vomiting and diarrhea. Aspiration may cause
pulmonary edema and pneumonitis.
Immediate, Delayed, Chronic Effects
Product Information:Data not available or insufficient for classification.
Numerical Measures of Toxicity
The following acute toxicity estimates (ATE) are calculated based on the GHS document.
.
ATEmix (oral):1675 mg/kg
ATEmix (dermal):3057 mg/kg
Component Acute Toxicity Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
ethyl lactate 97-64-3 > 2000 mg/kg ( Rat )> 5000 mg/kg ( Rat )Not Available
petroleum distillates
64742-47-8
> 5000 mg/kg ( Rat )> 2000 mg/kg ( Rabbit )> 5.2 mg/L ( Rat ) 4 h
1-undecanol
112-42-5
= 3 g/kg ( Rat )= 4760 µL/kg ( Rabbit )Not Available
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance/Physical State:Liquid
Color:Yellow
Odor:Bland
pH:Not Applicable
Melting Point / Freezing Point:No information available.
Boiling Point / Boiling Range:> 149 °C / 300 °F
Flash Point:64 °C / 147 °F ASTM D56
Evaporation Rate:< 1 (Butyl acetate = 1)
Flammability (solid, gas)No information available.
Upper Flammability Limit:No information available.
Lower Flammability Limit:No information available.
Vapor Pressure:No information available.
Vapor Density:No information available.
Specific Gravity:0.8935
Solubility(ies):No information available.
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Partition Coefficient:No information available.
Autoignition Temperature:No information available.
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Decomposition Temperature:No information available.
Viscosity:No information available.
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3071 - GRAFFITI REMOVER SAC Revision Date: 10-Aug-2015
Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Chemical Name Algae/Aquatic Plants Fish Toxicity to
Microorganisms
Crustacea
petroleum distillates
64742-47-8
Not Available 45: 96 h Pimephales
promelas mg/L LC50
flow-through 2.2: 96 h
Lepomis macrochirus mg/L
LC50 static 2.4: 96 h
Oncorhynchus mykiss mg/L
LC50 static
Not Available 4720: 96 h Den-dronereides
heteropoda mg/L LC50
1-undecanol
112-42-5
Not Available 1.04: 96 h Pimephales
promelas mg/L LC50
flow-through
Not Available Not Available
Persistence and Degradability: No information available.
Bioaccumulation: No information available.
Other Adverse Effects: No information available.
13. DISPOSAL CONSIDERATIONS
Disposal of Wastes:Dispose of in accordance with federal, state and local regulations.
Contaminated Packaging:Dispose of in accordance with federal, state and local regulations.
14. TRANSPORT INFORMATION
DOT: Not Regulated
Proper Shipping Name:Non-Hazardous Product
Special Provisions:Shipping descriptions may vary based on mode of transport, quantities, package size,
and/or origin and destination. Check with a trained hazardous materials transportation
expert for information specific to your situation.
IMDG: Not Regulated
Proper Shipping Name:Non-Hazardous Product
15. REGULATORY INFORMATION
TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory)
All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances.
SARA 313
This product does not contain listed substances above the "de minimus" level
SARA 311/312 Hazard Categories
Acute Health Hazard:Yes
Chronic Health Hazard:No
Fire Hazard:Yes
Sudden release of pressure hazard:No
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Reactive Hazard:No
California Proposition 65
This product is not subject to warning requirements under California Proposition 65.
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16. OTHER INFORMATION
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3071 - GRAFFITI REMOVER SAC Revision Date: 10-Aug-2015
Revision Date:10-Aug-2015
Reasons for Revision:Section 14 and 15
Disclaimer:
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet
NFPA Health Hazards: 2
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Flammability: 2 Instability: 0 Special: N/A
HMIS
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Health Hazards: 2 Flammability: 2 Physical Hazards: 0