HomeMy WebLinkAboutSpartan HDQ NeutralRevision Date: 14-Aug-2015
Safety Data Sheet
Spartan Chemical Company, Inc.
1. PRODUCT AND COMPANY IDENTIFICATION
Product Identifier
Product Name:HDQ NEUTRAL
Product Number:1202
Recommended Use:Disinfectant
Uses Advised Against:For Industrial and Institutional Use Only
Manufacturer/Supplier:Spartan Chemical Company, Inc.
1110 Spartan Drive
Maumee, Ohio 43537 USA
800-537-8990 (Business hours)
www.spartanchemical.com
24 Hour Emergency Phone Numbers:
Medical Emergency/Information:888-314-6171
Transportation/Spill/Leak:CHEMTREC 800-424-9300
2. HAZARDS IDENTIFICATION
GHS Classification
Acute Toxicity - Oral:Category 4
Skin Corrosion/Irritation:Category 1 Sub-category B
Serious Eye Damage/Eye Irritation:Category 1
GHS Label Elements
Signal Word:Danger
Hazard Statements:Harmful if swallowed.
Causes severe skin burns and serious eye damage.
Precautionary Statements:
Prevention:Wash hands and any exposed skin thoroughly after handling.
Do not eat, drink or smoke when using this product
Do not breathe mist, vapors or spray.
Wear protective gloves. Wear eye / face protection. Wear protective clothing.
Response:IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
-Eyes IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
-Skin IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water
or shower. Wash contaminated clothing before reuse.
-Inhalation:IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
-Ingestion:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
-Specific Treatment:
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See Safety Data Sheet Section 4: "FIRST AID MEASURES" for additional information.
Storage:Store locked up.
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Disposal:Dispose of contents and container in accordance with local, state and federal regulations.
Symbols:
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1202 - HDQ NEUTRAL Revision Date: 14-Aug-2015
Hazards Not Otherwise Classified:Not Applicable
Other Information:• Corrosive.
• Inhalation of vapors or mist may cause respiratory irritation.
• Keep out of reach of children.
• NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric
lavage.
0.32918% of the mixture consists of ingredient(s) of unknown toxicity.
3. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS No Weight-%
water 7732-18-5 60-100
didecyldimethylammonium chloride 7173-51-5 3-7
alkyl dimethyl benzyl ammonium chloride 68424-85-1 1-5
ethanol 64-17-5 1-5
tetrasodium ethylenediaminetetraacetate 64-02-8 1-5
alcohol ethoxylate 68439-46-3 1-5
Specific chemical identity and/or exact percentage of composition has been withheld as a trade secret.
4. FIRST AID MEASURES
-Eye Contact:Rinse cautiously with water for at least 15 minutes. Remove contact lenses, if present and
easy to do. Continue rinsing. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
-Skin Contact:Take off immediately all contaminated clothing and shoes. Rinse with water or shower for
at least 15 minutes. IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN. Wash
contaminated clothing before reuse.
-Inhalation:Remove victim to fresh air and keep at rest in a position comfortable for breathing.
IMMEDIATELY CALL A POISON CENTER OR PHYSICIAN.
-Ingestion:Rinse mouth. Do NOT induce vomiting. IMMEDIATELY CALL A POISON CENTER OR
PHYSICIAN. Never give anything by mouth to an unconscious person.
Note to Physicians:NOTE TO PHYSICIAN: Probable mucosal damage may contraindicate the use of gastric
lavage.
5. FIRE-FIGHTING MEASURES
Suitable Extinguishing Media:Product does not support combustion, Use extinguishing agent suitable for type of
surrounding fire
Specific Hazards Arising from the
Chemical:
Dried product is capable of burning. Combustion products are toxic.
Hazardous Combustion Products:May include Carbon monoxide Carbon dioxide and other toxic gases or vapors.
Protective Equipment and
Precautions for Firefighters:
Wear MSHA/NIOSH approved self-contained breathing apparatus (SCBA) and full
protective gear. Cool fire-exposed containers with water spray.
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions:Avoid contact with skin, eyes or clothing. Use personal protective equipment as required.
Environmental Precautions:
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Do not rinse spill onto the ground, into storm sewers or bodies of water.
Methods for Clean-Up:Prevent further leakage or spillage if safe to do so. Contain and collect spillage with
non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite)
and place in container for disposal according to local / national regulations (see Section 13).
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7. HANDLING AND STORAGE
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1202 - HDQ NEUTRAL Revision Date: 14-Aug-2015
Advice on Safe Handling:Handle in accordance with good industrial hygiene and safety practice. Wash thoroughly
after handling.
Storage Conditions:Keep containers tightly closed in a dry, cool and well-ventilated place. Keep out of the reach
of children. Keep from freezing.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Occupational Exposure Limits:.
Chemical Name ACGIH TLV OSHA PEL NIOSH
ethanol
64-17-5
STEL: 1000 ppm TWA: 1000 ppm
TWA: 1900 mg/m3
(vacated) TWA: 1000 ppm
(vacated) TWA: 1900 mg/m3
IDLH: 3300 ppm
TWA: 1000 ppm
TWA: 1900 mg/m3
Engineering Controls:Provide good general ventilation.
If work practices generate dust, fumes, gas, vapors or mists which expose workers to
chemicals above the occupational exposure limits, local exhaust ventilation or other
engineering controls should be considered.
Eye wash stations and shower facilities should be readily accessible in areas where the
product is handled.
Personal Protective Equipment
Eye/Face Protection:Wear splash goggles.
Skin and Body Protection:Wear rubber or other chemical-resistant gloves.
Respiratory Protection:Not required with expected use.
If occupational exposure limits are exceeded or respiratory irritation occurs, use of a
NIOSH/MSHA approved respirator suitable for the use-conditions and chemicals in Section
3 should be considered.
General Hygiene Considerations:Wash hands and any exposed skin thoroughly after handling.
See 29 CFR 1910.132-138 for further guidance.
10. STABILITY AND REACTIVITY
Reactivity:This material is considered to be non-reactive under normal conditions of use.
Chemical Stability:Stable under normal conditions.
Possibility of Hazardous Reactions:Not expected to occur with normal handling and storage.
Conditions to Avoid:Extremes of temperature and direct sunlight.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance/Physical State:Liquid
Color:Red
Odor:Mild Citrus fragrance
pH:7.2-8.2
Melting Point / Freezing Point:No information available.
Boiling Point / Boiling Range:100 °C / 212 °F
Flash Point:> 100 °C / > 212 °F
Evaporation Rate:< 1 (Butyl acetate = 1)
Flammability (solid, gas)No information available.
Upper Flammability Limit:No information available.
Lower Flammability Limit:No information available.
Vapor Pressure:No information available.
Vapor Density:No information available.
Specific Gravity:1.00
Solubility(ies):Soluble in water
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Partition Coefficient:No information available.
Autoignition Temperature:No information available.
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Decomposition Temperature:No information available.
Viscosity:No information available.
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1202 - HDQ NEUTRAL Revision Date: 14-Aug-2015
Incompatible Materials:Strong oxidizing agents. Strong acids.
Hazardous Decomposition
Products:
May include carbon monoxide, carbon dioxide (CO2) and other toxic gases or vapors.
11. TOXICOLOGICAL INFORMATION
Likely Routes of Exposure:Eyes, Skin, Ingestion, Inhalation.
Symptoms of Exposure:
-Eye Contact:Pain, redness, swelling of the conjunctiva and tissue damage. Eye contact may cause
permanent damage.
-Skin Contact:Pain, redness, blistering and possible chemical burn.
-Inhalation:Nasal discomfort and coughing. Irritation or damage to the mucus membranes of the
respiratory tract.
-Ingestion:Damage or chemical burns to mouth, throat and stomach. Pain, nausea, vomiting and
diarrhea.
Immediate, Delayed, Chronic EffectsProduct Information:Data not available or insufficient for classification.
Numerical Measures of Toxicity
The following acute toxicity estimates (ATE) are calculated based on the GHS document.
.
ATEmix (oral):1016 mg/kg
ATEmix (dermal):7198 mg/kg
ATEmix (inhalation-dust/mist):5.9 mg/l
Component Acute Toxicity Information
Chemical Name Oral LD50 Dermal LD50 Inhalation LC50
water
7732-18-5
> 90 mL/kg ( Rat )Not Available Not Available
didecyldimethylammonium chloride
7173-51-5
= 84 mg/kg ( Rat )Not Available Not Available
alkyl dimethyl benzyl ammonium
chloride
68424-85-1
= 426 mg/kg ( Rat )Not Available Not Available
ethanol
64-17-5
= 7060 mg/kg ( Rat )Not Available = 124.7 mg/L ( Rat ) 4 h
tetrasodium
ethylenediaminetetraacetate
64-02-8
= 10 g/kg ( Rat )Not Available Not Available
alcohol ethoxylate
68439-46-3
= 1378 mg/kg ( Rat )> 2 g/kg ( Rabbit )Not Available
Carcinogenicity: No components present at 0.1% or greater are listed as to being carcinogens by ACGIH, IARC, NTP or OSHA.
12. ECOLOGICAL INFORMATION
Ecotoxicity
Chemical Name Algae/Aquatic Plants Fish Toxicity to
Microorganisms
Crustacea
ethanol
64-17-5
Not Available 12.0 - 16.0: 96 h
Oncorhynchus mykiss mL/L
LC50 static 100: 96 h
Pimephales promelas mg/L
LC50 static 13400 - 15100:
96 h Pimephales promelas
mg/L LC50 flow-through
Not Available 9268 - 14221: 48 h Daphnia
magna mg/L LC50 10800:
24 h Daphnia magna mg/L
EC50 2: 48 h Daphnia
magna mg/L EC50 Static
tetrasodium
ethylenediaminetetraacetate
64-02-8
1.01: 72 h Desmodesmus
subspicatus mg/L EC50
41: 96 h Lepomis
macrochirus mg/L LC50
static 59.8: 96 h Pimephales
promelas mg/L LC50 static
Not Available
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610: 24 h Daphnia magna
mg/L EC50
Persistence and Degradability:
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No information available.
Bioaccumulation: No information available.
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1202 - HDQ NEUTRAL Revision Date: 14-Aug-2015
Other Adverse Effects: No information available.
13. DISPOSAL CONSIDERATIONS
Disposal of Wastes:Dispose of in accordance with federal, state and local regulations.
Contaminated Packaging:Dispose of in accordance with federal, state and local regulations.
14. TRANSPORT INFORMATION
DOT:
UN/ID No:UN1903
Proper Shipping Name:Disinfectants, liquid corrosive, n.o.s., (contains didecyl dimethyl ammonium chloride, n-alkyl
dimethyl benzyl ammonium chloride)
Hazard Class:8
Packing Group:III
Special Provisions:Shipping descriptions may vary based on mode of transport, quantities, package size,
and/or origin and destination. Check with a trained hazardous materials transportation
expert for information specific to your situation.
IMDG:
UN/ID No:UN1903
Proper Shipping Name:Disinfectants, liquid corrosive, n.o.s., (contains didecyl dimethyl ammonium chloride, n-alkyl
dimethyl benzyl ammonium chloride)
Hazard Class:8
Packing Group:III
15. REGULATORY INFORMATION
TSCA Status: (Toxic Substance Control Act Section 8(b) Inventory)
All chemical substances in this product are included on or exempted from listing on the TSCA Inventory of Chemical Substances.
SARA 313
This product does not contain listed substances above the "de minimus" level
SARA 311/312 Hazard Categories
Acute Health Hazard:Yes
Chronic Health Hazard:No
Fire Hazard:No
Sudden release of pressure hazard:No
Reactive Hazard:No
California Proposition 65
This product is not subject to warning requirements under California Proposition 65.
EPA Pesticide Registration Number:10324-155-5741
EPA Statement:
This chemical is a pesticide product registered by the Environmental Protection Agency and is subject to certain labeling
requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required
for safety data sheets, and for workplace labels of non-pesticide chemicals. Following is the hazard information as required on the
pesticide label:
EPA Pesticide Label:
Danger. Keep out of reach of children. Corrosive. Causes irreversible eye damage and skin burns. Harmful if swallowed, inhaled or absorbed
through the skin. Avoid breathing spray mist. Do not get in eyes, on skin, or on clothing. Wear goggles or face shield, rubber gloves and protective
clothing when handling. Wash thoroughly with soap and water after handling and before eating, drinking, chewing gum, using tobacco or using the
toilet. Remove contaminated clothing and wash clothing before reuse.
16. OTHER INFORMATION
NFPA Health Hazards: 3
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Flammability: 0 Instability: 0 Special: N/A
HMIS
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Health Hazards: 3 Flammability: 0 Physical Hazards: 0
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1202 - HDQ NEUTRAL Revision Date: 14-Aug-2015
Revision Date:
_____________________________________________________________________________________________
14-Aug-2015
Reasons for Revision:Section 11
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Disclaimer:
The information provided in this Material Safety Data Sheet is correct to the best of our knowledge, information and belief
at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,
storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in combination
with any other materials or in any process, unless specified in the text.
End of Safety Data Sheet