HomeMy WebLinkAboutSprayWay Glass CleanerSAFETY DATA SHEET
1. Identification
1000000075Product number
SW050 GLASS CLEANERProduct identifier
Sprayway, Inc.
1000 INTEGRAM DR
Pacific, MO 63069 United States
Company information
1-630-628-3000Company phone
1-866-836-8855Emergency telephone US
1-952-852-4646Emergency telephone outside
US
01Version #
cleanerRecommended use
None known.Recommended restrictions
2. Hazard(s) identification
Liquefied gasGases under pressurePhysical hazards
Not classified.Health hazards
Not classified.OSHA defined hazards
Label elements
Signal word Warning
Hazard statement Contains gas under pressure; may explode if heated.
Precautionary statement
Prevention Observe good industrial hygiene practices.
Response If exposed or concerned: Get medical advice/attention.
Storage Protect from sunlight. Store in a well-ventilated place.
Disposal Dispose of waste and residues in accordance with local authority requirements.
Hazard(s) not otherwise
classified (HNOC)
None known.
Supplemental information None.
3. Composition/information on ingredients
Mixtures
CAS number %Common name and synonymsChemical name
111-76-2 2.5 - 102-Butoxyethanol
64-17-5 2.5 - 10Ethyl Alcohol
106-97-8 1 - 2.5Butane
Other components below reportable levels 90 - 100
74-98-6 1 - 2.5Propane
*Designates that a specific chemical identity and/or percentage of composition has been withheld as a trade secret.
4. First-aid measures
Move to fresh air. Call a physician if symptoms develop or persist.Inhalation
No adverse effects due to skin contact are expected.Skin contact
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No specific first aid measures noted.Eye contact
Not likely, due to the form of the product.Ingestion
Direct contact with eyes may cause temporary irritation.Most important
symptoms/effects, acute and
delayed
Provide general supportive measures and treat symptomatically.Indication of immediate
medical attention and special
treatment needed
Ensure that medical personnel are aware of the material(s) involved, and take precautions to
protect themselves.
General information
5. Fire-fighting measures
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).Suitable extinguishing media
None known.Unsuitable extinguishing
media
During fire, gases hazardous to health may be formed.Specific hazards arising from
the chemical
Self-contained breathing apparatus and full protective clothing must be worn in case of fire.Special protective equipment
and precautions for firefighters
In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed
to heat. Move containers from fire area if you can do so without risk. Containers should be cooled
with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose
holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
Fire fighting
equipment/instructions
Cool containers exposed to flames with water until well after the fire is out.Specific methods
Contents under pressure. Pressurized container may explode when exposed to heat or flame.General fire hazards
6. Accidental release measures
Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of
low areas. Many gases are heavier than air and will spread along ground and collect in low or
confined areas (sewers, basements, tanks). Wear appropriate protective equipment and clothing
during clean-up. Emergency personnel need self-contained breathing equipment. Do not touch
damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate
closed spaces before entering them. Local authorities should be advised if significant spillages
cannot be contained. For personal protection, see section 8 of the SDS.
Personal precautions,
protective equipment and
emergency procedures
Refer to attached safety data sheets and/or instructions for use. Stop leak if you can do so without
risk. Move the cylinder to a safe and open area if the leak is irreparable. Isolate area until gas has
dispersed. Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Keep combustibles (wood, paper, oil, etc.) away from spilled material. For waste disposal, see
section 13 of the SDS.
Methods and materials for
containment and cleaning up
Avoid discharge into drains, water courses or onto the ground.Environmental precautions
7. Handling and storage
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Pressurized container: Do
not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray
on a naked flame or any other incandescent material. Do not smoke while using or until sprayed
surface is thoroughly dry. Do not cut, weld, solder, drill, grind, or expose containers to heat, flame,
sparks, or other sources of ignition. Ground and bond containers when transferring material. Close
valve after each use and when empty. Protect cylinders from physical damage; do not drag, roll,
slide, or drop. When moving cylinders, even for short distances, use a cart (trolley, hand truck,
etc.) designed to transport cylinders. Suck back of water into the container must be prevented. Do
not allow backfeed into the container. Purge air from system before introducing gas. Use only
properly specified equipment which is suitable for this product, its supply pressure and
temperature. Contact your gas supplier if in doubt. Do not re-use empty containers. Do not get in
eyes, on skin, or on clothing. Avoid prolonged exposure. Use only in well-ventilated areas. Wear
appropriate personal protective equipment. Observe good industrial hygiene practices.
Precautions for safe handling
Level 1 Aerosol.
Contents under pressure. Do not expose to heat or store at temperatures above 120°F/49°C as
can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame,
heat or other sources of ignition. Cylinders should be stored upright, with valve protection cap in
place, and firmly secured to prevent falling or being knocked over. Stored containers should be
periodically checked for general condition and leakage. Store in a well-ventilated place. Store
away from incompatible materials (see Section 10 of the SDS).
Conditions for safe storage,
including any incompatibilities
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8. Exposure controls/personal protection
Occupational exposure limits
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
ValueComponents Type
PEL 240 mg/m32-Butoxyethanol (CAS
111-76-2)
50 ppm
PEL 1900 mg/m3Ethyl Alcohol (CAS 64-17-5)
1000 ppm
PEL 1800 mg/m3Propane (CAS 74-98-6)
1000 ppm
US. ACGIH Threshold Limit Values
ValueComponents Type
TWA 20 ppm2-Butoxyethanol (CAS
111-76-2)
STEL 1000 ppmButane (CAS 106-97-8)
STEL 1000 ppmEthyl Alcohol (CAS 64-17-5)
US. NIOSH: Pocket Guide to Chemical Hazards
ValueComponents Type
TWA 24 mg/m32-Butoxyethanol (CAS
111-76-2)
5 ppm
TWA 1900 mg/m3Butane (CAS 106-97-8)
800 ppm
TWA 1900 mg/m3Ethyl Alcohol (CAS 64-17-5)
1000 ppm
TWA 1800 mg/m3Propane (CAS 74-98-6)
1000 ppm
Biological limit values
ACGIH Biological Exposure Indices
ValueComponents Determinant Specimen Sampling Time
200 mg/g Butoxyacetic
acid (BAA),
with hydrolysis
Creatinine in
urine
*2-Butoxyethanol (CAS
111-76-2)
* - For sampling details, please see the source document.
Exposure guidelines
US - California OELs: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US - Minnesota Haz Subs: Skin designation applies
2-Butoxyethanol (CAS 111-76-2) Skin designation applies.
US - Tennessee OELs: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US NIOSH Pocket Guide to Chemical Hazards: Skin designation
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
US. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000)
2-Butoxyethanol (CAS 111-76-2) Can be absorbed through the skin.
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates
should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation,
or other engineering controls to maintain airborne levels below recommended exposure limits. If
exposure limits have not been established, maintain airborne levels to an acceptable level.
Appropriate engineering
controls
Individual protection measures, such as personal protective equipment
Wear safety glasses with side shields (or goggles).Eye/face protection
Skin protection
Wear appropriate chemical resistant gloves. Suitable gloves can be recommended by the glove
supplier.
Hand protection
Wear suitable protective clothing.Other
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If permissible levels are exceeded use NIOSH mechanical filter / organic vapor cartridge or an
air-supplied respirator.
Respiratory protection
Wear appropriate thermal protective clothing, when necessary.Thermal hazards
When using do not smoke. Always observe good personal hygiene measures, such as washing
after handling the material and before eating, drinking, and/or smoking. Routinely wash work
clothing and protective equipment to remove contaminants.
General hygiene
considerations
9. Physical and chemical properties
Appearance
Gas.Physical state
Aerosol. Liquefied gas.Form
Not available.Color
Not available.Odor
Odor threshold Not available.
pH 9.1 - 10.1 estimated
Melting point/freezing point Not available.
Initial boiling point and boiling
range
212 °F (100 °C) estimated
Flash point -156.0 °F (-104.4 °C) Propellant estimated
Evaporation rate Not available.
Not available.Flammability (solid, gas)
Upper/lower flammability or explosive limits
Flammability limit - lower
(%)
Not available.
Flammability limit - upper
(%)
Not available.
Explosive limit - lower (%)Not available.
Explosive limit - upper (%)Not available.
Vapor pressure 80 - 100 psig @70F estimated
Vapor density Not available.
Relative density Not available.
Solubility(ies)
Solubility (water)Not available.
Partition coefficient
(n-octanol/water)
Not available.
Auto-ignition temperature Not available.
Decomposition temperature Not available.
Viscosity Not available.
Other information
Aerosol spray enclosed space
Deflagration density > 2.52 g/cm3 Tested
Aerosol spray ignition
distance
< 15 cm Tested estimated
Not explosive.Explosive properties
Not oxidizing.Oxidizing properties
Specific gravity 0.977 - 0.997
VOC (Weight %)9.5 % estimated
10. Stability and reactivity
The product is stable and non-reactive under normal conditions of use, storage and transport.Reactivity
Material is stable under normal conditions.Chemical stability
Hazardous polymerization does not occur.Possibility of hazardous
reactions
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Heat. Avoid temperatures exceeding the flash point. Contact with incompatible materials.Conditions to avoid
Strong oxidizing agents.Incompatible materials
No hazardous decomposition products are known.Hazardous decomposition
products
11. Toxicological information
Information on likely routes of exposure
Inhalation Prolonged inhalation may be harmful.
Skin contact 2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and
prolonged. These effects have not been observed in humans.
Eye contact Direct contact with eyes may cause temporary irritation.
Ingestion Expected to be a low ingestion hazard.
Symptoms related to the
physical, chemical and
toxicological characteristics
Direct contact with eyes may cause temporary irritation.
Information on toxicological effects
Acute toxicity
Test ResultsComponents Species
2-Butoxyethanol (CAS 111-76-2)
Dermal
Acute
LD50 Guinea pig 7.3 ml/kg, 4 Days
0.23 ml/kg, 24 Hours
Rabbit 435 mg/kg, 24 Hours
0.68 ml/kg, 24 Hours
0.63 ml/kg
Rat > 2000 mg/kg, 24 Hours
Inhalation
LC50 Rabbit 400 ppm, 7 Hours
Rat 450 ppm, 4 Hours
Oral
LD100 Rabbit 695 mg/kg
LD50 Dog > 695 mg/kg
Guinea pig 1414 mg/kg
Mouse 1519 mg/kg
Rat 1746 mg/kg
Butane (CAS 106-97-8)
Inhalation
Acute
LC50 Mouse 1237 mg/l, 120 Minutes
52 %, 120 Minutes
Rat 1355 mg/l
Ethyl Alcohol (CAS 64-17-5)
Inhalation
Acute
LC50 Cat 85.41 mg/l, 4.5 Hours
43.68 mg/l, 6 Hours
Mouse > 60000 ppm
79.43 mg/l, 134 Minutes
Rat > 115.9 mg/l, 4 Hours
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Test ResultsComponents Species
51.3 mg/l, 6 Hours
Oral
LD50 Monkey 6000 mg/kg
Mouse 10500 ml/kg
Pig > 5000 mg/kg
Rat 10470 mg/kg
7800 ml/kg
Propane (CAS 74-98-6)
Inhalation
Acute
LC50 Mouse 1237 mg/l, 120 Minutes
52 %, 120 Minutes
Rat 1355 mg/l
* Estimates for product may be based on additional component data not shown.
658 mg/l/4h
Prolonged skin contact may cause temporary irritation.Skin corrosion/irritation
Direct contact with eyes may cause temporary irritation.Serious eye damage/eye
irritation
Respiratory or skin sensitization
Respiratory sensitization Not a respiratory sensitizer.
This product is not expected to cause skin sensitization.Skin sensitization
No data available to indicate product or any components present at greater than 0.1% are
mutagenic or genotoxic.
Germ cell mutagenicity
Carcinogenicity This product is not considered to be a carcinogen by IARC, ACGIH, NTP, or OSHA.
IARC Monographs. Overall Evaluation of Carcinogenicity
2-Butoxyethanol (CAS 111-76-2) 3 Not classifiable as to carcinogenicity to humans.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
US. National Toxicology Program (NTP) Report on Carcinogens
Not listed.
This product is not expected to cause reproductive or developmental effects.Reproductive toxicity
Specific target organ toxicity -
single exposure
Not classified.
Specific target organ toxicity -
repeated exposure
Not classified.
Aspiration hazard Not likely, due to the form of the product.
Chronic effects May be harmful if absorbed through skin. Prolonged inhalation may be harmful.
2-Butoxy ethanol may be absorbed through the skin in toxic amounts if contact is repeated and
prolonged. These effects have not been observed in humans.
12. Ecological information
The product is not classified as environmentally hazardous. However, this does not exclude the
possibility that large or frequent spills can have a harmful or damaging effect on the environment.
Ecotoxicity
Product Test ResultsSpecies
SW050 GLASS CLEANER
Aquatic
EC50Crustacea 13838.1602 mg/l, 48 hours estimatedDaphnia
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Components Test ResultsSpecies
2-Butoxyethanol (CAS 111-76-2)
Aquatic
LC50Fish 1250 mg/l, 96 hoursInland silverside (Menidia beryllina)
Ethyl Alcohol (CAS 64-17-5)
Aquatic
EC50Crustacea 7700 - 11200 mg/l, 48 hoursWater flea (Daphnia magna)
* Estimates for product may be based on additional component data not shown.
LC50Fish > 100.1 mg/l, 96 hoursFathead minnow (Pimephales promelas)
No data is available on the degradability of this product. Persistence and degradability
Bioaccumulative potential
Partition coefficient n-octanol / water (log Kow)
2-Butoxyethanol 0.83
Butane 2.89
Ethyl Alcohol -0.31
Propane 2.36
No data available.Mobility in soil
Other adverse effects No other adverse environmental effects (e.g. ozone depletion, photochemical ozone creation
potential, endocrine disruption, global warming potential) are expected from this component.
13. Disposal considerations
Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents
under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance
with local/regional/national/international regulations.
Disposal instructions
Dispose in accordance with all applicable regulations.Local disposal regulations
The waste code should be assigned in discussion between the user, the producer and the waste
disposal company.
Hazardous waste code
Dispose of in accordance with local regulations. Empty containers or liners may retain some
product residues. This material and its container must be disposed of in a safe manner (see:
Disposal instructions).
Waste from residues / unused
products
Since emptied containers may retain product residue, follow label warnings even after container is
emptied. Empty containers should be taken to an approved waste handling site for recycling or
disposal. Do not re-use empty containers.
Contaminated packaging
14. Transport information
DOT
UN1950UN number
AerosolsUN proper shipping name
2.2Class
Transport hazard class(es)
-Subsidiary risk
2.2Label(s)
Not applicable.Packing group
Not available.Special precautions for user
306Packaging exceptions
NonePackaging non bulk
NonePackaging bulk
IATA
UN1950UN number
Aerosols, non-flammableUN proper shipping name
2.2Class
Transport hazard class(es)
-Subsidiary risk
2.2Label(s)
Not applicable.Packing group
No.Environmental hazards
2LERG Code
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
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Allowed with restrictions.Passenger and cargo
aircraft
Other information
Allowed with restrictions.Cargo aircraft only
LTD QTYPackaging Exceptions
IMDG
UN1950UN number
AEROSOLSUN proper shipping name
2.2Class
Transport hazard class(es)
-Subsidiary risk
2.2Label(s)
Not applicable.Packing group
No.Marine pollutant
Environmental hazards
Not available.EmS
Read safety instructions, SDS and emergency procedures before handling.Special precautions for user
LTD QTYPackaging Exceptions
Not applicable.Transport in bulk according to
Annex II of MARPOL 73/78 and
the IBC Code
DOT
IATA; IMDG
Avoid transport on vehicles where the load space is not separated from the driver's compartment.
Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the
event of an accident or an emergency. Before transporting product containers: Ensure that
containers are firmly secured. Ensure cylinder valve is closed and not leaking. Ensure valve outlet
cap nut or plug (where provided) is correctly fitted. Ensure valve protection device (where
provided) is correctly fitted. Ensure adequate ventilation. Ensure compliance with applicable
regulations.
General information
15. Regulatory information
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
US federal regulations
TSCA Section 12(b) Export Notification (40 CFR 707, Subpt. D)
Not regulated.
CERCLA Hazardous Substance List (40 CFR 302.4)
Not listed.
SARA 304 Emergency release notification
Not regulated.
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OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not regulated.
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - No
Delayed Hazard - No
Fire Hazard - No
Pressure Hazard - Yes
Reactivity Hazard - No
Hazard categories
SARA 302 Extremely hazardous substance
Not listed.
NoSARA 311/312 Hazardous
chemical
SARA 313 (TRI reporting)
Chemical name CAS number % by wt.
2-Butoxyethanol 111-76-2 2.5 - 10
Other federal regulations
Clean Air Act (CAA) Section 112 Hazardous Air Pollutants (HAPs) List
Not regulated.
Clean Air Act (CAA) Section 112(r) Accidental Release Prevention (40 CFR 68.130)
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
Not regulated.Safe Drinking Water Act
(SDWA)
US state regulations
US. California Controlled Substances. CA Department of Justice (California Health and Safety Code Section 11100)
Not listed.
US. California. Candidate Chemicals List. Safer Consumer Products Regulations (Cal. Code Regs, tit. 22, 69502.3, subd.
(a))
2-Butoxyethanol (CAS 111-76-2)
Butane (CAS 106-97-8)
US. Massachusetts RTK - Substance List
2-Butoxyethanol (CAS 111-76-2)
Butane (CAS 106-97-8)
Ethyl Alcohol (CAS 64-17-5)
Propane (CAS 74-98-6)
US. New Jersey Worker and Community Right-to-Know Act
2-Butoxyethanol (CAS 111-76-2)
Butane (CAS 106-97-8)
Ethyl Alcohol (CAS 64-17-5)
Propane (CAS 74-98-6)
US. Pennsylvania Worker and Community Right-to-Know Law
2-Butoxyethanol (CAS 111-76-2)
Butane (CAS 106-97-8)
Ethyl Alcohol (CAS 64-17-5)
Propane (CAS 74-98-6)
US. Rhode Island RTK
Butane (CAS 106-97-8)
Propane (CAS 74-98-6)
US. California Proposition 65
California Safe Drinking Water and Toxic Enforcement Act of 1986 (Proposition 65): This material is not known to contain
any chemicals currently listed as carcinogens or reproductive toxins.
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
YesAustralia Australian Inventory of Chemical Substances (AICS)
YesCanada Domestic Substances List (DSL)
NoCanada Non-Domestic Substances List (NDSL)
YesChina Inventory of Existing Chemical Substances in China (IECSC)
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Country(s) or region Inventory name On inventory (yes/no)*
YesEurope European Inventory of Existing Commercial Chemical
Substances (EINECS)
NoEurope European List of Notified Chemical Substances (ELINCS)
NoJapan Inventory of Existing and New Chemical Substances (ENCS)
NoKorea Existing Chemicals List (ECL)
NoNew Zealand New Zealand Inventory
NoPhilippines Philippine Inventory of Chemicals and Chemical Substances
(PICCS)
YesUnited States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory
*A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
A "No" indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing
country(s).
16. Other information, including date of preparation or last revision
03-09-2018Issue date
Version #01
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is
not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
Disclaimer
Product and Company Identification: Alternate Trade NamesRevision information
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Product name: SW050 GLASS CLEANER
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SDS US