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HomeMy WebLinkAboutWOW-All-PurposeWOW ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 02/11/1998 Revision date: 06/15/2015 Supersedes: 10/15/2013 06/15/2015 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Mixture Product name : WOW ALL PURPOSE CLEANER Product code : ALL 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : Industrial and Institutional All Purpose Cleaner 1.3. Details of the supplier of the safety data sheet Sky Blue Industries, Inc. 760 W. Exchange Road Ogden, Utah 84401 - USA T (800) 998-2808 1.4. Emergency telephone number Emergency number : Chemtrec 1-800-424-9300 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Skin Irrit. 2 H315 Eye Irrit. 2A H319 Full text of H-statements: see section 16 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS07 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : Causes skin irritation Causes serious eye irritation Precautionary statements (GHS-US) Prevention : Wash hands and exposed skin thoroughly after handling. Wear eye protection, protective clothing, protective gloves. Response : IF ON SKIN: Wash with plenty of soap and water. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse. 2.3. Other hazards No additional information available 2.4. Unknown acute toxicity (GHS-US) Not applicable SECTION 3: Composition/information on ingredients 3.1. Substance Not applicable WOW ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/15/2015 EN (English) 2/1 3.2. Mixture Name Product identifier % GHS-US classification 2-(2-butoxyethoxy)ethanol (CAS No) 112-34-5 5 - 10 Eye Irrit. 2A, H319 Polyethylene glycol undecyl ether (CAS No) 34398-01-1 5 - 10 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 Ethanolamine (CAS No) 141-43-5 1 - 3 Flam. Liq. 4, H227 Acute Tox. 4 (Oral), H302 Acute Tox. 4 (Dermal), H312 Skin Corr. 1A, H314 Full text of H-statements: see section 16 SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures after inhalation : Remove person to fresh air and keep comfortable for breathing. First-aid measures after skin contact : Wash skin with plenty of water. Take off contaminated clothing. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Call a poison center or a doctor if you feel unwell. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after skin contact : Irritation. Symptoms/injuries after eye contact : Eye irritation. 4.3. Indication of any immediate medical attention and special treatment needed Treat symptomatically. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : All extinguishing media allowed. Adapt extinguishing media to the environment. 5.2. Special hazards arising from the substance or mixture Fire hazard : Non combustible. 5.3. Advice for firefighters Protection during firefighting : Do not attempt to take action without suitable protective equipment. Self-contained breathing apparatus. Complete protective clothing. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Emergency procedures : Avoid contact with skin and eyes. Ventilate spillage area. Use personal protective equipment (PPE). 6.1.2. For emergency responders Protective equipment : Do not attempt to take action without suitable protective equipment. For further information refer to section 8: "Exposure controls/personal protection". 6.2. Environmental precautions Avoid release to the environment. See Section 12 for additional Ecological information. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Take up liquid spill into inert absorbent material. Scoop absorbed substance into closing containers. Store away from other materials. Other information : Dispose of materials or solid residues at an authorized site. 6.4. Reference to other sections For further information refer to section 13. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Ensure good ventilation of the work station. Avoid contact with skin and eyes. Wear personal protective equipment. WOW ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/15/2015 EN (English) 3/1 Hygiene measures : Wash contaminated clothing before reuse. Do not eat, drink or smoke when using this product. Always wash hands after handling the product. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Store in a well-ventilated place. Keep cool. Incompatible products : Strong acids. Strong oxidizing agents. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters WOW ALL PURPOSE CLEANER ACGIH Not applicable OSHA Not applicable Ethanolamine (141-43-5) ACGIH ACGIH TWA (ppm) 3 ppm ACGIH ACGIH STEL (ppm) 6 ppm ACGIH Remark (ACGIH) Eye & skin irr OSHA OSHA PEL (TWA) (mg/m³) 6 mg/m³ OSHA OSHA PEL (TWA) (ppm) 3 ppm 2-(2-butoxyethoxy)ethanol (112-34-5) ACGIH ACGIH TWA (ppm) 10 ppm ACGIH ACGIH STEL (ppm) 10 ppm OSHA Not applicable 8.2. Exposure controls Appropriate engineering controls : Ensure good ventilation of the work station. Hand protection : Protective gloves. Eye protection : Safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Environmental exposure controls : Avoid release to the environment. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear, green liquid. Colour : Green Odour : Detergent Odour threshold : No data available pH : 9.8 pH solution : 1 % Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : No data available Relative evaporation rate (butylacetate=1) : No data available Flammability (solid, gas) : No data available Explosive limits : No data available Explosive properties : No data available Oxidising properties : No data available Vapour pressure : No data available Relative density : 1.01 WOW ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/15/2015 EN (English) 4/1 Relative vapour density at 20 °C : No data available Density : 8.40 lb/gal Solubility : Soluble in water Log Pow : No data available Log Kow : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available 9.2. Other information VOC content : 4.0 % SECTION 10: Stability and reactivity 10.1. Reactivity No additional information available 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions No dangerous reactions known under normal conditions of use. 10.4. Conditions to avoid None under recommended storage and handling conditions (see section 7). 10.5. Incompatible materials Strong acids. Strong oxidizing agents. 10.6. Hazardous decomposition products Thermal decomposition generates: Carbon monoxide. Carbon dioxide. Oxides of product. Ammonia. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified Ethanolamine (141-43-5) LD50 oral rat 1720 mg/kg (Rat) LD50 dermal rabbit 1018 mg/kg (Rabbit) ATE US (oral) 1720 mg/kg bodyweight ATE US (dermal) 1018 mg/kg bodyweight 2-(2-butoxyethoxy)ethanol (112-34-5) LD50 oral rat 5660 mg/kg (Rat) LD50 dermal rabbit 2764 mg/kg (Rabbit; Experimental value; OECD 402: Acute Dermal Toxicity) ATE US (oral) 5660 mg/kg bodyweight ATE US (dermal) 2764 mg/kg bodyweight Polyethylene glycol undecyl ether (34398-01-1) LD50 oral rat > 1400 mg/kg LD50 dermal rabbit > 2000 mg/kg Skin corrosion/irritation : Causes skin irritation. pH: 9.8 Serious eye damage/irritation : Causes serious eye irritation. pH: 9.8 Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Not classified Reproductive toxicity : Not classified Specific target organ toxicity (single exposure) : Not classified WOW ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/15/2015 EN (English) 5/1 Specific target organ toxicity (repeated exposure) : Not classified Aspiration hazard : Not classified Symptoms/injuries after skin contact : Irritation. Symptoms/injuries after eye contact : Eye irritation. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : The product is not considered harmful to aquatic organisms or to cause long-term adverse effects in the environment. Ethanolamine (141-43-5) LC50 fish 1 150 mg/l 96 h; Salmo gairdneri (Oncorhynchus mykiss) EC50 Daphnia 1 140 mg/l (24 h; Daphnia magna) LC50 fish 2 329.16 mg/l (96 h; Lepomis macrochirus) TLM fish 1 100 - 1000,96 h; Pisces TLM other aquatic organisms 1 100 - 1000,96 h Threshold limit algae 1 0.97 mg/l (192 h; Scenedesmus quadricauda; Inhibitory) Threshold limit algae 2 35 mg/l (72 h; Algae) 2-(2-butoxyethoxy)ethanol (112-34-5) LC50 fish 1 1300 mg/l (96 h; Lepomis macrochirus) LC50 other aquatic organisms 1 10 - 100 mg/l (96 h) EC50 Daphnia 1 2850 mg/l (24 h; Daphnia magna; GLP) LC50 fish 2 1805 mg/l (48 h; Leuciscus idus) EC50 Daphnia 2 > 100 mg/l (48 h; Daphnia magna) TLM fish 1 10 - 100,96 h; Pisces TLM other aquatic organisms 1 10 - 100,96 h Threshold limit other aquatic organisms 1 10 - 100,96 h Threshold limit algae 1 53 mg/l (192 h; Microcystis aeruginosa) Threshold limit algae 2 >= 100 mg/l (96 h; Scenedesmus subspicatus) Polyethylene glycol undecyl ether (34398-01-1) LC50 fish 1 1 - 10 mg/l (96 hr.) EC50 Daphnia 1 1 - 10 mg/l (48 hr.) EC50 other aquatic organisms 1 1 - 10 mg/l (96 hr.)(Algae) 12.2. Persistence and degradability Ethanolamine (141-43-5) Persistence and degradability Readily biodegradable in water. Biodegradable in the soil. Biochemical oxygen demand (BOD) 0.80 g O₂/g substance Chemical oxygen demand (COD) 1.34 g O₂/g substance ThOD 2.49 g O₂/g substance BOD (% of ThOD) 0.32 % ThOD 2-(2-butoxyethoxy)ethanol (112-34-5) Persistence and degradability Readily biodegradable in w ater. Biodegradable in the soil. No (test)data on mobility of the substance available. Photodegradation in the air. Biochemical oxygen demand (BOD) 0.25 g O₂/g substance Chemical oxygen demand (COD) 2.08 g O₂/g substance ThOD 2.173 g O₂/g substance BOD (% of ThOD) 0.11 % ThOD 12.3. Bioaccumulative potential Ethanolamine (141-43-5) Log Pow -1.91 Bioaccumulative potential Bioaccumulation: not applicable. WOW ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/15/2015 EN (English) 6/1 2-(2-butoxyethoxy)ethanol (112-34-5) BCF fish 1 0.46 (QSAR) Log Pow 0.56 (Experimental value) Bioaccumulative potential Low potential for bioaccumulation (Log Kow < 4). 12.4. Mobility in soil Ethanolamine (141-43-5) Surface tension 0.050 N/m 2-(2-butoxyethoxy)ethanol (112-34-5) Surface tension 0.034 N/m (25 °C) 12.5. Other adverse effects Effect on the global warming : No known ecological damage caused by this product. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose of contents/container in accordance with local/state/federal regulations. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT: Not regulated for transport Additional information Other information : No supplementary information available. ADR No additional information available Transport by sea No additional information available Air transport No additional information available SECTION 15: Regulatory information 15.1. US Federal regulations All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory Chemical(s) subject to the reporting requirements of Section 313 or Title III of the Superfund Amendments and Reauthorization Act (SARA) of 1986 and 40 CFR Part 372. Formaldehyde CAS No 50-00-0 < 0.1 1,4-dioxane CAS No 123-91-1 < 0.1 Acetaldehyde CAS No 75-07-0 < 0.1 Ethylene oxide CAS No 75-21-8 < 0.1 Methyl alcohol CAS No 67-56-1 < 1 Diethanolamine CAS No 111-42-2 < 0.1 2-butoxyethanol (111-76-2) SARA Section 311/312 Hazard Classes Fire hazard Immediate (acute) health hazard Delayed (chronic) health hazard SARA Section 313 - Emission Reporting 100 % Polyethylene glycol undecyl ether (34398-01-1) SARA Section 311/312 Hazard Classes Immediate (acute) health hazard 15.2. International regulations CANADA No additional information available EU-Regulations No additional information available WOW ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/15/2015 EN (English) 7/1 Classification according to Regulation (EC) No. 1272/2008 [CLP] No additional information available Classification according to Directive 67/548/EEC [DSD] or 1999/45/EC [DPD] Not classified National regulations No additional information available 15.3. US State regulations California Proposition 65 - This product contains, or may contain, trace quantities of a substance(s) known to the state of California to cause cancer and/or reproductive toxicity Formaldehyde (50-00-0) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) Yes No No No 1,4-dioxane (123-91-1) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) Yes No No No Acetaldehyde (75-07-0) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) Yes No No No Ethylene oxide (75-21-8) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) Yes Yes Yes Yes Methyl alcohol (67-56-1) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) No Yes No No Diethanolamine (111-42-2) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significance risk level (NSRL) Yes No No No Sodium hydroxide (1310-73-2) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Formaldehyde (50-00-0) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List U.S. - Massachusetts - Right To Know List Ethanolamine (141-43-5) U.S. - New Jersey - Right to Know Hazardous Substance List 2-butoxyethanol (111-76-2) U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List WOW ALL PURPOSE CLEANER Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/15/2015 EN (English) 8/1 1,4-dioxane (123-91-1) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Acetaldehyde (75-07-0) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Methyl alcohol (67-56-1) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List Diethanolamine (111-42-2) U.S. - Massachusetts - Right To Know List U.S. - New Jersey - Right to Know Hazardous Substance List U.S. - Pennsylvania - RTK (Right to Know) List 1,7,7-trimethylnorcamphor (76-22-2) U.S. - New Jersey - Right to Know Hazardous Substance List SECTION 16: Other information Indication of changes : Formatting change. Revision date : 06/15/2015 Full text of H-statements: ------ Acute Tox. 4 (Dermal) Acute toxicity (dermal), Category 4 ------ Acute Tox. 4 (Oral) Acute toxicity (oral), Category 4 ------ Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A ------ Flam. Liq. 4 Flammable liquids, Category 4 ------ Skin Corr. 1A Skin corrosion/irritation, Category 1A ------ Skin Irrit. 2 Skin corrosion/irritation, Category 2 ------ H227 Combustible liquid ------ H302 Harmful if swallowed ------ H312 Harmful in contact with skin ------ H314 Causes severe skin burns and eye damage ------ H315 Causes skin irritation ------ H319 Causes serious eye irritation SDS US (GHS HazCom 2012) - Custom The information provided on this document is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered as a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other material or in any process, unless specified in the text.