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HomeMy WebLinkAboutWaxie Gum Away AerosolSAFETY DATA SHEET This Safety Data Sheet (SDS) complies with the requirements of the U.S. Federal Occupational Safety and Health Administration Hazard Communication Standard (29 CFR 1910.1200, as updated in 2012) and equivalent state Standards. It has also been developed in accordance with the United Nations Globally Harmonized System of Classification of Chemicals (GHS) and the Canadian Workplace Hazardous Materials Information System (WHMIS). Refer to Section 16 of this document for the definition of terms and abbreviations WAXIE GUM AWAY II 1070451 A00183 Version 1.0 Revision Date 04/27/2015 Print Date 05/18/2015 WAXIE–GUM AWAY II WAXIE Sanitary Supply SAFETY DATA SHEET xxxxxxxxxxx Page 1 of 10 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Material name : WAXIE GUM AWAY II Material number : 1070451 Manufacturer or supplier's details Company : WAXIE Sanitary Supply Address : 9353 Waxie Way, San Diego CA. 92123-1036 Telephone : 1-800-995-4466 Emergency telephone numbers For a Medical Emergency : 1-800-255-3924 (CHEMTEL; 24 hours) For a Transportation Emergency : 1-800-255-3924 (CHEMTEL; 24 hours) SECTION 2. HAZARDS IDENTIFICATION Emergency Overview Appearance Aerosol containing a liquefied gas Color clear Odor odorless GHS Classification Flammable aerosols : Category 1 Gases under pressure : Liquefied gas GHS Label element Hazard pictograms : Signal word : Danger Hazard statements : H222 Extremely flammable aerosol. H280 Contains gas under pressure; may explode if heated. Precautionary statements : Prevention: P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. SAFETY DATA SHEET This Safety Data Sheet (SDS) complies with the requirements of the U.S. Federal Occupational Safety and Health Administration Hazard Communication Standard (29 CFR 1910.1200, as updated in 2012) and equivalent state Standards. It has also been developed in accordance with the United Nations Globally Harmonized System of Classification of Chemicals (GHS) and the Canadian Workplace Hazardous Materials Information System (WHMIS). Refer to Section 16 of this document for the definition of terms and abbreviations WAXIE GUM AWAY II 1070451 A00183 Version 1.0 Revision Date 04/27/2015 Print Date 05/18/2015 WAXIE–GUM AWAY II WAXIE Sanitary Supply SAFETY DATA SHEET xxxxxxxxxxx Page 2 of 10 P211 Do not spray on an open flame or other ignition source. P251 Pressurized container: Do not pierce or burn, even after use. Storage: P410 + P412 Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F. Potential Health Effects Carcinogenicity: IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance / Mixture : Mixture Hazardous components Chemical Name CAS-No. Concentration [%] butane 106-97-8 >= 70 - < 90 propane 74-98-6 >= 20 - < 30 SECTION 4. FIRST AID MEASURES General advice : Move out of dangerous area. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled : If unconscious place in recovery position and seek medical advice. If symptoms persist, call a physician. In case of skin contact : Take off contaminated clothing and shoes immediately. Get medical attention if irritation develops and persists. Wash contaminated clothing before re-use. SAFETY DATA SHEET This Safety Data Sheet (SDS) complies with the requirements of the U.S. Federal Occupational Safety and Health Administration Hazard Communication Standard (29 CFR 1910.1200, as updated in 2012) and equivalent state Standards. It has also been developed in accordance with the United Nations Globally Harmonized System of Classification of Chemicals (GHS) and the Canadian Workplace Hazardous Materials Information System (WHMIS). Refer to Section 16 of this document for the definition of terms and abbreviations WAXIE GUM AWAY II 1070451 A00183 Version 1.0 Revision Date 04/27/2015 Print Date 05/18/2015 WAXIE–GUM AWAY II WAXIE Sanitary Supply SAFETY DATA SHEET xxxxxxxxxxx Page 3 of 10 Wash off immediately with plenty of water for at least 15 minutes. In case of eye contact : Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If in eyes, rinse with water for 15 minutes. If swallowed : Keep respiratory tract clear. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. DO NOT induce vomiting unless directed to do so by a physician or poison control center. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media : Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Water spray jet Unsuitable extinguishing media : High volume water jet Specific hazards during firefighting : Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion products : Carbon dioxide (CO2) Carbon monoxide Smoke Specific extinguishing methods : Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Further information : For safety reasons in case of fire, cans should be stored separately in closed containments. Use a water spray to cool fully closed containers. Special protective equipment for firefighters : Wear self-contained breathing apparatus for firefighting if necessary. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures : Ensure adequate ventilation. Remove all sources of ignition. Evacuate personnel to safe areas. SAFETY DATA SHEET This Safety Data Sheet (SDS) complies with the requirements of the U.S. Federal Occupational Safety and Health Administration Hazard Communication Standard (29 CFR 1910.1200, as updated in 2012) and equivalent state Standards. It has also been developed in accordance with the United Nations Globally Harmonized System of Classification of Chemicals (GHS) and the Canadian Workplace Hazardous Materials Information System (WHMIS). Refer to Section 16 of this document for the definition of terms and abbreviations WAXIE GUM AWAY II 1070451 A00183 Version 1.0 Revision Date 04/27/2015 Print Date 05/18/2015 WAXIE–GUM AWAY II WAXIE Sanitary Supply SAFETY DATA SHEET xxxxxxxxxxx Page 4 of 10 Beware of vapors accumulating to form explosive concentrations. Vapors can accumulate in low areas. Environmental precautions : Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for containment and cleaning up : Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Sweep up or vacuum up spillage and collect in suitable container for disposal. SECTION 7. HANDLING AND STORAGE Advice on safe handling : For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Always replace cap after use. Do not breathe vapors or spray mist. Conditions for safe storage : BEWARE: Aerosol is pressurized. Keep away from direct sun exposure and temperatures over 50 °C. Do not open by force or throw into fire even after use. Do not spray on flames or red-hot objects. No smoking. Observe label precautions. Keep in a cool, well-ventilated place. Electrical installations / working materials must comply with the technological safety standards. Materials to avoid : Strong oxidizing agents SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type (Form of exposure) Control parameters / Permissible concentration Basis SAFETY DATA SHEET This Safety Data Sheet (SDS) complies with the requirements of the U.S. Federal Occupational Safety and Health Administration Hazard Communication Standard (29 CFR 1910.1200, as updated in 2012) and equivalent state Standards. It has also been developed in accordance with the United Nations Globally Harmonized System of Classification of Chemicals (GHS) and the Canadian Workplace Hazardous Materials Information System (WHMIS). Refer to Section 16 of this document for the definition of terms and abbreviations WAXIE GUM AWAY II 1070451 A00183 Version 1.0 Revision Date 04/27/2015 Print Date 05/18/2015 WAXIE–GUM AWAY II WAXIE Sanitary Supply SAFETY DATA SHEET xxxxxxxxxxx Page 5 of 10 butane 106-97-8 TWA 800 ppm 1,900 mg/m3 NIOSH REL TWA 800 ppm 1,900 mg/m3 OSHA P0 propane 74-98-6 TWA 1,000 ppm ACGIH TWA 1,000 ppm 1,800 mg/m3 NIOSH REL TWA 1,000 ppm 1,800 mg/m3 OSHA Z-1 TWA 1,000 ppm 1,800 mg/m3 OSHA P0 Personal protective equipment Respiratory protection : In case of insufficient ventilation, wear suitable respiratory equipment. Hand protection Remarks : The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection : Eye wash bottle with pure water Tightly fitting safety goggles Skin and body protection : impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures : Wash hands before breaks and at the end of workday. When using do not smoke. When using do not eat or drink. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : Aerosol containing a liquefied gas Color : clear Odor : odorless Odor Threshold : no data available pH : not applicable Melting point/freezing point : no data available Boiling point : no data available Flash point : SAFETY DATA SHEET This Safety Data Sheet (SDS) complies with the requirements of the U.S. Federal Occupational Safety and Health Administration Hazard Communication Standard (29 CFR 1910.1200, as updated in 2012) and equivalent state Standards. It has also been developed in accordance with the United Nations Globally Harmonized System of Classification of Chemicals (GHS) and the Canadian Workplace Hazardous Materials Information System (WHMIS). Refer to Section 16 of this document for the definition of terms and abbreviations WAXIE GUM AWAY II 1070451 A00183 Version 1.0 Revision Date 04/27/2015 Print Date 05/18/2015 WAXIE–GUM AWAY II WAXIE Sanitary Supply SAFETY DATA SHEET xxxxxxxxxxx Page 6 of 10 no data available Evaporation rate : no data available Flammability (solid, gas) : Extremely flammable aerosol. Upper explosion limit : no data available Lower explosion limit : no data available Vapor pressure : no data available Relative vapor density : no data available Density : no data available Solubility(ies) Water solubility : negligible Partition coefficient: n- octanol/water : no data available Auto-ignition temperature : not determined Thermal decomposition : no data available Viscosity Viscosity, kinematic : no data available Heat of combustion : 49.35 kJ/g SECTION 10. STABILITY AND REACTIVITY Reactivity : Stable Chemical stability : Stable under normal conditions. Possibility of hazardous reactions : No decomposition if stored and applied as directed. Vapors may form explosive mixture with air. Conditions to avoid : Heat, flames and sparks. Extremes of temperature and direct sunlight. Incompatible materials : Strong oxidizing agents Hazardous decomposition products : Carbon oxides SAFETY DATA SHEET This Safety Data Sheet (SDS) complies with the requirements of the U.S. Federal Occupational Safety and Health Administration Hazard Communication Standard (29 CFR 1910.1200, as updated in 2012) and equivalent state Standards. It has also been developed in accordance with the United Nations Globally Harmonized System of Classification of Chemicals (GHS) and the Canadian Workplace Hazardous Materials Information System (WHMIS). Refer to Section 16 of this document for the definition of terms and abbreviations WAXIE GUM AWAY II 1070451 A00183 Version 1.0 Revision Date 04/27/2015 Print Date 05/18/2015 WAXIE–GUM AWAY II WAXIE Sanitary Supply SAFETY DATA SHEET xxxxxxxxxxx Page 7 of 10 SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Components: butane: Acute inhalation toxicity : LC50 mouse: 1,237 mg/l Exposure time: 2 h LC50 rat: 1,355 mg/l propane: Acute inhalation toxicity : LC50 mouse: 1,237 mg/l Exposure time: 2 h LC50 rat: 658 mg/l Exposure time: 4 h LC50 rat: 1,355 mg/l Skin corrosion/irritation no data available Serious eye damage/eye irritation no data available Respiratory or skin sensitization no data available Germ cell mutagenicity no data available Carcinogenicity no data available Reproductive toxicity no data available butane: propane: STOT - single exposure no data available STOT - repeated exposure no data available SAFETY DATA SHEET This Safety Data Sheet (SDS) complies with the requirements of the U.S. Federal Occupational Safety and Health Administration Hazard Communication Standard (29 CFR 1910.1200, as updated in 2012) and equivalent state Standards. It has also been developed in accordance with the United Nations Globally Harmonized System of Classification of Chemicals (GHS) and the Canadian Workplace Hazardous Materials Information System (WHMIS). Refer to Section 16 of this document for the definition of terms and abbreviations WAXIE GUM AWAY II 1070451 A00183 Version 1.0 Revision Date 04/27/2015 Print Date 05/18/2015 WAXIE–GUM AWAY II WAXIE Sanitary Supply SAFETY DATA SHEET xxxxxxxxxxx Page 8 of 10 Aspiration toxicity no data available Further information Product: Remarks: no data available SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity no data available Persistence and degradability no data available Bioaccumulative potential Product: Partition coefficient: n- octanol/water : Remarks: no data available Components: butane : Partition coefficient: n- octanol/water : Pow: 2.89 Mobility in soil no data available Other adverse effects no data available Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Substances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological information : no data available SAFETY DATA SHEET This Safety Data Sheet (SDS) complies with the requirements of the U.S. Federal Occupational Safety and Health Administration Hazard Communication Standard (29 CFR 1910.1200, as updated in 2012) and equivalent state Standards. It has also been developed in accordance with the United Nations Globally Harmonized System of Classification of Chemicals (GHS) and the Canadian Workplace Hazardous Materials Information System (WHMIS). Refer to Section 16 of this document for the definition of terms and abbreviations WAXIE GUM AWAY II 1070451 A00183 Version 1.0 Revision Date 04/27/2015 Print Date 05/18/2015 WAXIE–GUM AWAY II WAXIE Sanitary Supply SAFETY DATA SHEET xxxxxxxxxxx Page 9 of 10 SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues : Dispose of in accordance with local regulations. Do not dispose of waste into sewer. Do not contaminate ponds, waterways or ditches with chemical or used container. Contaminated packaging : Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION Transportation Regulation: 49 CFR (USA): ORM-D, CONSUMER COMMODITY Transportation Regulation: IMDG (Vessel): UN1950, AEROSOLS, 2.1, - Limited quantity Transportation Regulation: IATA (Cargo Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity Transportation Regulation: IATA (Passenger Air): UN1950, Aerosols, flammable, 2.1, - Limited quantity Transportation Regulation: TDG (Canada): UN1950, AEROSOLS, 2.1, - Limited quantity SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SAFETY DATA SHEET This Safety Data Sheet (SDS) complies with the requirements of the U.S. Federal Occupational Safety and Health Administration Hazard Communication Standard (29 CFR 1910.1200, as updated in 2012) and equivalent state Standards. It has also been developed in accordance with the United Nations Globally Harmonized System of Classification of Chemicals (GHS) and the Canadian Workplace Hazardous Materials Information System (WHMIS). Refer to Section 16 of this document for the definition of terms and abbreviations WAXIE GUM AWAY II 1070451 A00183 Version 1.0 Revision Date 04/27/2015 Print Date 05/18/2015 WAXIE–GUM AWAY II WAXIE Sanitary Supply SAFETY DATA SHEET xxxxxxxxxxx Page 10 of 10 SARA 311/312 Hazards : Sudden Release of Pressure Hazard Fire Hazard SARA 302 : SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 : SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: TSCA On TSCA Inventory DSL All components of this product are on the Canadian DSL. AICS On the inventory, or in compliance with the inventory NZIoC On the inventory, or in compliance with the inventory PICCS On the inventory, or in compliance with the inventory IECSC On the inventory, or in compliance with the inventory Inventory Acronym and Validity Area Legend: AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) SECTION 16. OTHER INFORMATION SAFETY DATA SHEET This Safety Data Sheet (SDS) complies with the requirements of the U.S. Federal Occupational Safety and Health Administration Hazard Communication Standard (29 CFR 1910.1200, as updated in 2012) and equivalent state Standards. It has also been developed in accordance with the United Nations Globally Harmonized System of Classification of Chemicals (GHS) and the Canadian Workplace Hazardous Materials Information System (WHMIS). Refer to Section 16 of this document for the definition of terms and abbreviations WAXIE GUM AWAY II 1070451 A00183 Version 1.0 Revision Date 04/27/2015 Print Date 05/18/2015 WAXIE–GUM AWAY II WAXIE Sanitary Supply SAFETY DATA SHEET xxxxxxxxxxx Page 11 of 10 Further information NFPA: HMIS III: OSHA GHS Label Information: Hazard pictograms : Signal word : Danger: Hazard statements : Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Precautionary statements : Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122 °F. We believe the statements, technical information and recommendations contained herein are reliable, but they are given without warranty or guarantee of any kind. The information in this document applies to this specific material as supplied. It may not be valid for this material if it is used in combination with any other materials. Users should make their own investigations to determine the suitability and applicability of the information for their particular purposes. This SDS has been prepared by the Compliance Services organization supporting this manufacturer, supplier or distributor. Flammability Health Instability 3 4 0 Special hazard. FLAMMABILITY PHYSICAL HAZARD HEALTH 4 2 3 0 = not significant, 1 =Slight, 2 = Moderate, 3 = High 4 = Extreme, * = Chronic