HomeMy WebLinkAboutWaxie Gum Away AerosolSAFETY DATA SHEET
This Safety Data Sheet (SDS) complies with the requirements of the U.S.
Federal Occupational Safety and Health Administration Hazard
Communication Standard (29 CFR 1910.1200, as updated in 2012) and
equivalent state Standards. It has also been developed in accordance with
the United Nations Globally Harmonized System of Classification of
Chemicals (GHS) and the Canadian Workplace Hazardous Materials
Information System (WHMIS). Refer to Section 16 of this document for the
definition of terms and abbreviations
WAXIE GUM AWAY II 1070451 A00183
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SECTION 1. PRODUCT AND COMPANY IDENTIFICATION
Material name : WAXIE GUM AWAY II
Material number : 1070451
Manufacturer or supplier's details
Company : WAXIE Sanitary Supply
Address : 9353 Waxie Way, San Diego CA. 92123-1036
Telephone : 1-800-995-4466
Emergency telephone numbers
For a Medical Emergency : 1-800-255-3924 (CHEMTEL; 24 hours)
For a Transportation
Emergency
: 1-800-255-3924 (CHEMTEL; 24 hours)
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Appearance Aerosol containing a liquefied gas
Color clear
Odor odorless
GHS Classification
Flammable aerosols : Category 1
Gases under pressure : Liquefied gas
GHS Label element
Hazard pictograms :
Signal word : Danger
Hazard statements : H222 Extremely flammable aerosol.
H280 Contains gas under pressure; may explode if heated.
Precautionary statements : Prevention:
P210 Keep away from heat, hot surfaces, sparks, open flames
and other ignition sources. No smoking.
SAFETY DATA SHEET
This Safety Data Sheet (SDS) complies with the requirements of the U.S.
Federal Occupational Safety and Health Administration Hazard
Communication Standard (29 CFR 1910.1200, as updated in 2012) and
equivalent state Standards. It has also been developed in accordance with
the United Nations Globally Harmonized System of Classification of
Chemicals (GHS) and the Canadian Workplace Hazardous Materials
Information System (WHMIS). Refer to Section 16 of this document for the
definition of terms and abbreviations
WAXIE GUM AWAY II 1070451 A00183
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P211 Do not spray on an open flame or other ignition source.
P251 Pressurized container: Do not pierce or burn, even after
use.
Storage:
P410 + P412 Protect from sunlight. Do not expose to
temperatures exceeding 50 °C/ 122 °F.
Potential Health Effects
Carcinogenicity:
IARC No component of this product present at levels greater than or
equal to 0.1% is identified as probable, possible or confirmed
human carcinogen by IARC.
ACGIH No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by ACGIH.
OSHA No component of this product present at levels greater than or
equal to 0.1% is identified as a carcinogen or potential
carcinogen by OSHA.
NTP No component of this product present at levels greater than or
equal to 0.1% is identified as a known or anticipated carcinogen
by NTP.
SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS
Substance / Mixture : Mixture
Hazardous components
Chemical Name CAS-No. Concentration [%]
butane 106-97-8 >= 70 - < 90
propane 74-98-6 >= 20 - < 30
SECTION 4. FIRST AID MEASURES
General advice : Move out of dangerous area.
Show this safety data sheet to the doctor in attendance.
Do not leave the victim unattended.
If inhaled : If unconscious place in recovery position and seek medical
advice.
If symptoms persist, call a physician.
In case of skin contact : Take off contaminated clothing and shoes immediately.
Get medical attention if irritation develops and persists.
Wash contaminated clothing before re-use.
SAFETY DATA SHEET
This Safety Data Sheet (SDS) complies with the requirements of the U.S.
Federal Occupational Safety and Health Administration Hazard
Communication Standard (29 CFR 1910.1200, as updated in 2012) and
equivalent state Standards. It has also been developed in accordance with
the United Nations Globally Harmonized System of Classification of
Chemicals (GHS) and the Canadian Workplace Hazardous Materials
Information System (WHMIS). Refer to Section 16 of this document for the
definition of terms and abbreviations
WAXIE GUM AWAY II 1070451 A00183
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Wash off immediately with plenty of water for at least 15
minutes.
In case of eye contact : Remove contact lenses.
Protect unharmed eye.
Keep eye wide open while rinsing.
If eye irritation persists, consult a specialist.
If in eyes, rinse with water for 15 minutes.
If swallowed : Keep respiratory tract clear.
Never give anything by mouth to an unconscious person.
If symptoms persist, call a physician.
DO NOT induce vomiting unless directed to do so by a
physician or poison control center.
SECTION 5. FIREFIGHTING MEASURES
Suitable extinguishing media : Alcohol-resistant foam
Carbon dioxide (CO2)
Dry chemical
Water spray jet
Unsuitable extinguishing
media
: High volume water jet
Specific hazards during
firefighting
: Do not allow run-off from fire fighting to enter drains or water
courses.
Hazardous combustion
products
: Carbon dioxide (CO2)
Carbon monoxide
Smoke
Specific extinguishing
methods
: Use extinguishing measures that are appropriate to local
circumstances and the surrounding environment.
Further information : For safety reasons in case of fire, cans should be stored
separately in closed containments.
Use a water spray to cool fully closed containers.
Special protective equipment
for firefighters
: Wear self-contained breathing apparatus for firefighting if
necessary.
SECTION 6. ACCIDENTAL RELEASE MEASURES
Personal precautions,
protective equipment and
emergency procedures
: Ensure adequate ventilation.
Remove all sources of ignition.
Evacuate personnel to safe areas.
SAFETY DATA SHEET
This Safety Data Sheet (SDS) complies with the requirements of the U.S.
Federal Occupational Safety and Health Administration Hazard
Communication Standard (29 CFR 1910.1200, as updated in 2012) and
equivalent state Standards. It has also been developed in accordance with
the United Nations Globally Harmonized System of Classification of
Chemicals (GHS) and the Canadian Workplace Hazardous Materials
Information System (WHMIS). Refer to Section 16 of this document for the
definition of terms and abbreviations
WAXIE GUM AWAY II 1070451 A00183
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Beware of vapors accumulating to form explosive
concentrations. Vapors can accumulate in low areas.
Environmental precautions : Prevent product from entering drains.
Prevent further leakage or spillage if safe to do so.
If the product contaminates rivers and lakes or drains inform
respective authorities.
Methods and materials for
containment and cleaning up
: Soak up with inert absorbent material (e.g. sand, silica gel,
acid binder, universal binder, sawdust).
Sweep up or vacuum up spillage and collect in suitable
container for disposal.
SECTION 7. HANDLING AND STORAGE
Advice on safe handling : For personal protection see section 8.
Smoking, eating and drinking should be prohibited in the
application area.
Take precautionary measures against static discharges.
Provide sufficient air exchange and/or exhaust in work rooms.
Open drum carefully as content may be under pressure.
Dispose of rinse water in accordance with local and national
regulations.
Always replace cap after use.
Do not breathe vapors or spray mist.
Conditions for safe storage : BEWARE: Aerosol is pressurized. Keep away from direct sun
exposure and temperatures over 50 °C. Do not open by force
or throw into fire even after use. Do not spray on flames or
red-hot objects.
No smoking.
Observe label precautions.
Keep in a cool, well-ventilated place.
Electrical installations / working materials must comply with
the technological safety standards.
Materials to avoid : Strong oxidizing agents
SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Components with workplace control parameters
Components CAS-No. Value type
(Form of
exposure)
Control
parameters /
Permissible
concentration
Basis
SAFETY DATA SHEET
This Safety Data Sheet (SDS) complies with the requirements of the U.S.
Federal Occupational Safety and Health Administration Hazard
Communication Standard (29 CFR 1910.1200, as updated in 2012) and
equivalent state Standards. It has also been developed in accordance with
the United Nations Globally Harmonized System of Classification of
Chemicals (GHS) and the Canadian Workplace Hazardous Materials
Information System (WHMIS). Refer to Section 16 of this document for the
definition of terms and abbreviations
WAXIE GUM AWAY II 1070451 A00183
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butane 106-97-8 TWA 800 ppm
1,900 mg/m3
NIOSH REL
TWA 800 ppm
1,900 mg/m3
OSHA P0
propane 74-98-6 TWA 1,000 ppm ACGIH
TWA 1,000 ppm
1,800 mg/m3
NIOSH REL
TWA 1,000 ppm
1,800 mg/m3
OSHA Z-1
TWA 1,000 ppm
1,800 mg/m3
OSHA P0
Personal protective equipment
Respiratory protection : In case of insufficient ventilation, wear suitable respiratory
equipment.
Hand protection
Remarks : The suitability for a specific workplace should be discussed
with the producers of the protective gloves.
Eye protection : Eye wash bottle with pure water
Tightly fitting safety goggles
Skin and body protection : impervious clothing
Choose body protection according to the amount and
concentration of the dangerous substance at the work place.
Hygiene measures : Wash hands before breaks and at the end of workday.
When using do not smoke.
When using do not eat or drink.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance : Aerosol containing a liquefied gas
Color : clear
Odor : odorless
Odor Threshold : no data available
pH : not applicable
Melting point/freezing point : no data available
Boiling point : no data available
Flash point :
SAFETY DATA SHEET
This Safety Data Sheet (SDS) complies with the requirements of the U.S.
Federal Occupational Safety and Health Administration Hazard
Communication Standard (29 CFR 1910.1200, as updated in 2012) and
equivalent state Standards. It has also been developed in accordance with
the United Nations Globally Harmonized System of Classification of
Chemicals (GHS) and the Canadian Workplace Hazardous Materials
Information System (WHMIS). Refer to Section 16 of this document for the
definition of terms and abbreviations
WAXIE GUM AWAY II 1070451 A00183
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no data available
Evaporation rate : no data available
Flammability (solid, gas) : Extremely flammable aerosol.
Upper explosion limit : no data available
Lower explosion limit : no data available
Vapor pressure : no data available
Relative vapor density : no data available
Density : no data available
Solubility(ies)
Water solubility : negligible
Partition coefficient: n-
octanol/water
: no data available
Auto-ignition temperature : not determined
Thermal decomposition : no data available
Viscosity
Viscosity, kinematic : no data available
Heat of combustion : 49.35 kJ/g
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Stable
Chemical stability : Stable under normal conditions.
Possibility of hazardous
reactions
: No decomposition if stored and applied as directed.
Vapors may form explosive mixture with air.
Conditions to avoid : Heat, flames and sparks.
Extremes of temperature and direct sunlight.
Incompatible materials : Strong oxidizing agents
Hazardous decomposition
products
: Carbon oxides
SAFETY DATA SHEET
This Safety Data Sheet (SDS) complies with the requirements of the U.S.
Federal Occupational Safety and Health Administration Hazard
Communication Standard (29 CFR 1910.1200, as updated in 2012) and
equivalent state Standards. It has also been developed in accordance with
the United Nations Globally Harmonized System of Classification of
Chemicals (GHS) and the Canadian Workplace Hazardous Materials
Information System (WHMIS). Refer to Section 16 of this document for the
definition of terms and abbreviations
WAXIE GUM AWAY II 1070451 A00183
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SECTION 11. TOXICOLOGICAL INFORMATION
Acute toxicity
Components:
butane:
Acute inhalation toxicity : LC50 mouse: 1,237 mg/l
Exposure time: 2 h
LC50 rat: 1,355 mg/l
propane:
Acute inhalation toxicity : LC50 mouse: 1,237 mg/l
Exposure time: 2 h
LC50 rat: 658 mg/l
Exposure time: 4 h
LC50 rat: 1,355 mg/l
Skin corrosion/irritation
no data available
Serious eye damage/eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
no data available
Reproductive toxicity
no data available
butane:
propane:
STOT - single exposure
no data available
STOT - repeated exposure
no data available
SAFETY DATA SHEET
This Safety Data Sheet (SDS) complies with the requirements of the U.S.
Federal Occupational Safety and Health Administration Hazard
Communication Standard (29 CFR 1910.1200, as updated in 2012) and
equivalent state Standards. It has also been developed in accordance with
the United Nations Globally Harmonized System of Classification of
Chemicals (GHS) and the Canadian Workplace Hazardous Materials
Information System (WHMIS). Refer to Section 16 of this document for the
definition of terms and abbreviations
WAXIE GUM AWAY II 1070451 A00183
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Aspiration toxicity
no data available
Further information
Product:
Remarks: no data available
SECTION 12. ECOLOGICAL INFORMATION
Ecotoxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
Product:
Partition coefficient: n-
octanol/water
: Remarks: no data available
Components:
butane :
Partition coefficient: n-
octanol/water
: Pow: 2.89
Mobility in soil
no data available
Other adverse effects
no data available
Product:
Regulation 40 CFR Protection of Environment; Part 82 Protection of
Stratospheric Ozone - CAA Section 602 Class I
Substances
Remarks This product neither contains, nor was manufactured
with a Class I or Class II ODS as defined by the U.S.
Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A
+ B).
Additional ecological
information
: no data available
SAFETY DATA SHEET
This Safety Data Sheet (SDS) complies with the requirements of the U.S.
Federal Occupational Safety and Health Administration Hazard
Communication Standard (29 CFR 1910.1200, as updated in 2012) and
equivalent state Standards. It has also been developed in accordance with
the United Nations Globally Harmonized System of Classification of
Chemicals (GHS) and the Canadian Workplace Hazardous Materials
Information System (WHMIS). Refer to Section 16 of this document for the
definition of terms and abbreviations
WAXIE GUM AWAY II 1070451 A00183
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SECTION 13. DISPOSAL CONSIDERATIONS
Disposal methods
Waste from residues : Dispose of in accordance with local regulations.
Do not dispose of waste into sewer.
Do not contaminate ponds, waterways or ditches with
chemical or used container.
Contaminated packaging : Empty remaining contents.
Dispose of as unused product.
Do not re-use empty containers.
Do not burn, or use a cutting torch on, the empty drum.
SECTION 14. TRANSPORT INFORMATION
Transportation Regulation: 49 CFR (USA):
ORM-D, CONSUMER COMMODITY
Transportation Regulation: IMDG (Vessel):
UN1950, AEROSOLS, 2.1, - Limited quantity
Transportation Regulation: IATA (Cargo Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: IATA (Passenger Air):
UN1950, Aerosols, flammable, 2.1, - Limited quantity
Transportation Regulation: TDG (Canada):
UN1950, AEROSOLS, 2.1, - Limited quantity
SECTION 15. REGULATORY INFORMATION
EPCRA - Emergency Planning and Community Right-to-Know Act
CERCLA Reportable Quantity
This material does not contain any components with a CERCLA RQ.
SARA 304 Extremely Hazardous Substances Reportable Quantity
This material does not contain any components with a section 304 EHS RQ.
SAFETY DATA SHEET
This Safety Data Sheet (SDS) complies with the requirements of the U.S.
Federal Occupational Safety and Health Administration Hazard
Communication Standard (29 CFR 1910.1200, as updated in 2012) and
equivalent state Standards. It has also been developed in accordance with
the United Nations Globally Harmonized System of Classification of
Chemicals (GHS) and the Canadian Workplace Hazardous Materials
Information System (WHMIS). Refer to Section 16 of this document for the
definition of terms and abbreviations
WAXIE GUM AWAY II 1070451 A00183
Version 1.0 Revision Date 04/27/2015 Print Date 05/18/2015
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SARA 311/312 Hazards : Sudden Release of Pressure Hazard
Fire Hazard
SARA 302 : SARA 302: No chemicals in this material are subject to the
reporting requirements of SARA Title III, Section 302.
SARA 313 : SARA 313: This material does not contain any chemical
components with known CAS numbers that exceed the
threshold (De Minimis) reporting levels established by SARA
Title III, Section 313.
California Prop 65 This product does not contain any chemicals known to State of
California to cause cancer, birth defects, or any other
reproductive harm.
The components of this product are reported in the following inventories:
TSCA On TSCA Inventory
DSL All components of this product are on the Canadian DSL.
AICS On the inventory, or in compliance with the inventory
NZIoC On the inventory, or in compliance with the inventory
PICCS On the inventory, or in compliance with the inventory
IECSC On the inventory, or in compliance with the inventory
Inventory Acronym and Validity Area Legend:
AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan),
ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA)
SECTION 16. OTHER INFORMATION
SAFETY DATA SHEET
This Safety Data Sheet (SDS) complies with the requirements of the U.S.
Federal Occupational Safety and Health Administration Hazard
Communication Standard (29 CFR 1910.1200, as updated in 2012) and
equivalent state Standards. It has also been developed in accordance with
the United Nations Globally Harmonized System of Classification of
Chemicals (GHS) and the Canadian Workplace Hazardous Materials
Information System (WHMIS). Refer to Section 16 of this document for the
definition of terms and abbreviations
WAXIE GUM AWAY II 1070451 A00183
Version 1.0 Revision Date 04/27/2015 Print Date 05/18/2015
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Further information
NFPA: HMIS III:
OSHA GHS Label Information:
Hazard pictograms :
Signal word : Danger:
Hazard statements : Extremely flammable aerosol. Contains gas under pressure; may explode if heated.
Precautionary statements :
Prevention: Keep away from heat, hot surfaces, sparks, open flames and other ignition
sources. No smoking. Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
Storage: Protect from sunlight. Do not expose to temperatures exceeding 50 °C/ 122
°F.
We believe the statements, technical information and recommendations contained herein are
reliable, but they are given without warranty or guarantee of any kind. The information in this
document applies to this specific material as supplied. It may not be valid for this material if it
is used in combination with any other materials. Users should make their own investigations
to determine the suitability and applicability of the information for their particular purposes.
This SDS has been prepared by the Compliance Services organization supporting this
manufacturer, supplier or distributor.
Flammability
Health Instability
3
4
0
Special hazard.
FLAMMABILITY
PHYSICAL HAZARD
HEALTH
4
2
3
0 = not significant, 1 =Slight,
2 = Moderate, 3 = High
4 = Extreme, * = Chronic