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HomeMy WebLinkAboutDistilled Resources Hand Sanitizer SDS (10.28.20) (2) SAFETY DATA SHEET Issuing Date 30-Mar-2020 Revision Date 28-OCT-2020 Revision Number 3 NGHS / English _____________________________________________________________________________________________ The supplier identified below generated this SDS using the UL SDS template. UL did not test, certify, or approve the substance described in this SDS, and all information in this SDS was provided by the supplier or was reproduced from publicly available regulatory data sources. UL makes no representations or warranties regarding the completeness or accuracy of the information in this SDS and disclaims all liability in connection with the use of this information or the substance described in this SDS. The layout, appearance and format of this SDS is © 2014 UL LLC. All rights reserved. _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 1 / 12 1. IDENTIFICATION Product identifier Product Name Hand Sanitizer Other means of identification Product Code(s) 1114-B605, 1114-D55, 1114-P05, 1114-P06 Recommended use of the chemical and restrictions on use Recommended Use Hand sanitizer Restrictions on use No information available Details of the supplier of the safety data sheet Supplier Identification Distilled Resources, Inc Address 134 North 3300 East Rigby ID 83442 US Telephone Phone:208-754-0042 E-mail sang@distilledresources.com Emergency telephone numbers Chemical Emergency Phone Number Chemtrec 1-800-424-9300 Company Emergency Phone Number 1-208-754-0042 2. HAZARDS IDENTIFICATION Classification Flammable liquids Category 2 1567974 - Hand Sanitizer Revision Date 28-OCT-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 2 / 12 Appearance Colorless Physical state Liquid Odor Alcohol GHS Label elements, including precautionary statements Danger Hazard statements Highly flammable liquid and vapor Precautionary Statements - Prevention Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking Keep container tightly closed Ground/bond container and receiving equipment Use explosion-proof electrical/ ventilating/ lighting/ equipment Use only non-sparking tools Take precautionary measures against static discharge Wear protective gloves/eye protection/face protection Precautionary Statements - Response Skin In the case of skin irritation or allergic reactions see a physician. Fire In case of fire: Use CO2, dry chemical, or foam to extinguish Precautionary Statements - Storage Store in a well-ventilated place. Keep cool Precautionary Statements - Disposal Dispose of contents/container to an approved waste disposal plant Other information Toxic to aquatic life. Unknown acute toxicity 81.45 % of the mixture consists of ingredient(s) of unknown toxicity 0 % of the mixture consists of ingredient(s) of unknown acute oral toxicity 81.45 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity 81.45 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas) 81.45 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor) 1.45 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist) 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance 1567974 - Hand Sanitizer Revision Date 28-OCT-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 3 / 12 Not applicable. Mixture Chemical name CAS No. Weight-% Hazardous Material Information Review Act registry number (HMIRA registry #) Date HMIRA filed and date exemption granted (if applicable) Ethanol 64-17-5 80 - - Glycerin 56-81-5 1.45 - - 4. FIRST AID MEASURES Description of first aid measures Inhalation Remove to fresh air. Get medical attention immediately if symptoms occur. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Keep eye wide open while rinsing. Do not rub affected area. Get medical attention immediately if symptoms occur. Skin contact In the case of skin irritation or allergic reactions see a physician. Ingestion Clean mouth with water and drink afterwards plenty of water. Get medical attention immediately if symptoms occur. Self-protection of the first aider Remove all sources of ignition. Ensure that medical personnel are aware of the material(s) involved, take precautions to protect themselves and prevent spread of contamination. Use personal protective equipment as required. See section 8 for more information. Most important symptoms and effects, both acute and delayed Symptoms No information available. Indication of any immediate medical attention and special treatment needed Note to physicians Treat symptomatically. 5. FIRE-FIGHTING MEASURES Suitable Extinguishing Media Dry chemical. Carbon dioxide (CO2). Water spray. Alcohol resistant foam. Large Fire CAUTION: Use of water spray when fighting fire may be inefficient. Unsuitable extinguishing media Do not scatter spilled material with high pressure water streams. Specific hazards arising from the chemical Risk of ignition. Keep product and empty container away from heat and sources of ignition. In the event of fire, cool tanks with water spray. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Hazardous Combustion Products Carbon oxides. 1567974 - Hand Sanitizer Revision Date 28-OCT-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 4 / 12 Explosion Data Sensitivity to Mechanical Impact NONE. Sensitivity to Static Discharge Yes. Special protective equipment for fire- fighters Firefighters should wear self-contained breathing apparatus and full firefighting turnout gear. Use personal protection equipment. 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures Personal precautions Evacuate personnel to safe areas. Use personal protective equipment as required. See section 8 for more information. Avoid contact with skin, eyes or clothing. Ensure adequate ventilation. Keep people away from and upwind of spill/leak. ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Pay attention to flashback. Take precautionary measures against static discharges. All equipment used when handling the product must be grounded. Do not touch or walk through spilled material. Other Information Ventilate the area. Methods and material for containment and cleaning up Methods for containment Stop leak if you can do it without risk. Do not touch or walk through spilled material. A vapor suppressing foam may be used to reduce vapors. Dike far ahead of spill to collect runoff water. Keep out of drains, sewers, ditches and waterways. Absorb with earth, sand or other non-combustible material and transfer to containers for later disposal. Methods for cleaning up Take precautionary measures against static discharges. Dam up. Soak up with inert absorbent material. Pick up and transfer to properly labeled containers. 7. HANDLING AND STORAGE Precautions for safe handling Advice on safe handling Use personal protection equipment. Avoid contact with skin and eyes. Avoid breathing vapors or mists. Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Use grounding and bonding connection when transferring this material to prevent static discharge, fire or explosion. Use with local exhaust ventilation. Use spark-proof tools and explosion-proof equipment. Keep in an area equipped with sprinklers. Use according to package label instructions. Conditions for safe storage, including any incompatibilities Storage Conditions Keep containers tightly closed in a dry, cool and well-ventilated place. Keep away from heat, sparks, flame and other sources of ignition (i.e., pilot lights, electric motors and static electricity). Keep in properly labeled containers. Do not store near combustible materials. Keep in an area equipped with sprinklers. Store in accordance with the particular national regulations. Store in accordance with local regulations. 1567974 - Hand Sanitizer Revision Date 28-OCT-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 5 / 12 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Exposure Limits . Chemical name ACGIH TLV OSHA PEL NIOSH IDLH Ethanol 64-17-5 STEL: 1000 ppm TWA: 1000 ppm TWA: 1900 mg/m3 (vacated) TWA: 1000 ppm (vacated) TWA: 1900 mg/m3 IDLH: 3300 ppm 10% LEL TWA: 1000 ppm TWA: 1900 mg/m3 Glycerin 56-81-5 TWA: 10 mg/m3 mist TWA: 15 mg/m3 mist, total particulate TWA: 5 mg/m3 mist, respirable fraction (vacated) TWA: 10 mg/m3 mist, total particulate (vacated) TWA: 5 mg/m3 mist, respirable fraction Chemical name Alberta British Columbia Ontario TWAEV Quebec Ethanol 64-17-5 TWA: 1000 ppm TWA: 1880 mg/m3 STEL: 1000 ppm STEL: 1000 ppm TWA: 1000 ppm TWA: 1880 mg/m3 Glycerin 56-81-5 TWA: 10 mg/m3 TWA: 10 mg/m3 TWA: 3 mg/m3 TWA: 10 mg/m3 Other Exposure Guidelines Vacated limits revoked by the Court of Appeals decision in AFL-CIO v. OSHA, 965 F.2d 962 (11th Cir., 1992). See section 15 for national exposure control parameters. Appropriate engineering controls Engineering controls Showers Eyewash stations Ventilation systems. Individual protection measures, such as personal protective equipment Eye/face protection Tight sealing safety goggles. Hand protection Wear suitable gloves. Impervious gloves. Skin and body protection Wear suitable protective clothing. Long sleeved clothing. Chemical resistant apron. Antistatic boots. Respiratory protection No protective equipment is needed under normal use conditions. If exposure limits are exceeded or irritation is experienced, ventilation and evacuation may be required. General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. Do not eat, drink or smoke when using this product. Contaminated work clothing should not be allowed out of the workplace. Regular cleaning of equipment, work area and clothing is recommended. Wash hands before breaks and immediately after handling the product. 9. PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties Physical state Liquid Appearance Colorless 1567974 - Hand Sanitizer Revision Date 28-OCT-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 6 / 12 Odor Alcohol Color No information available Odor Threshold No data available Property Values Remarks Method pH 7 Melting / freezing point No data available None known Boiling point / boiling range No data available None known Flash Point 20 C / 68 F Evaporation Rate No data available None known Flammability (solid, gas) No data available None known Flammability Limit in Air None known Upper flammability limit No data available Lower flammability limit No data available Vapor pressure No data available None known Vapor density No data available None known Relative density 0.861 Water Solubility Soluble in water Solubility(ies) No data available None known Partition coefficient: n-octanol/water No data available Autoignition temperature No data available None known Decomposition temperature No data available None known Kinematic viscosity No data available None known Dynamic viscosity No data available None known Other Information Explosive properties No information available Oxidizing properties No information available Softening Point No information available Molecular Weight No information available VOC Content (%) No information available Liquid Density No information available Bulk Density No information available Particle Size No information available Particle Size Distribution No information available 10. STABILITY AND REACTIVITY Reactivity No information available. Chemical stability Stable under normal conditions. Possibility of Hazardous Reactions None under normal processing. Hazardous Polymerization Hazardous polymerization does not occur. Conditions to avoid Heat, flames and sparks. Incompatible materials None known based on information supplied. Hazardous Decomposition Products Carbon oxides. 11. TOXICOLOGICAL INFORMATION Information on likely routes of exposure 1567974 - Hand Sanitizer Revision Date 28-OCT-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 7 / 12 Product Information Inhalation Specific test data for the substance or mixture is not available. Eye contact Specific test data for the substance or mixture is not available. Skin contact Specific test data for the substance or mixture is not available. Ingestion Specific test data for the substance or mixture is not available. Symptoms related to the physical, chemical and toxicological characteristics Symptoms No information available. Numerical measures of toxicity Acute Toxicity The following values are calculated based on chapter 3.1 of the GHS document . ATEmix (oral) 8,736.30 mg/kg ATEmix (inhalation-dust/mist) 155.90 mg/L Unknown acute toxicity 81.45 % of the mixture consists of ingredient(s) of unknown toxicity 0 % of the mixture consists of ingredient(s) of unknown acute oral toxicity 81.45 % of the mixture consists of ingredient(s) of unknown acute dermal toxicity 81.45 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (gas) 81.45 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (vapor) 1.45 % of the mixture consists of ingredient(s) of unknown acute inhalation toxicity (dust/mist) Component Information Chemical name Oral LD50 Dermal LD50 Inhalation LC50 Ethanol = 7060 mg/kg ( Rat ) - = 124.7 mg/L ( Rat ) 4 h Glycerin = 12600 mg/kg ( Rat ) > 10 g/kg ( Rabbit ) > 570 mg/m3 ( Rat ) 1 h Delayed and immediate effects as well as chronic effects from short and long-term exposure Skin corrosion/irritation No information available. Serious eye damage/eye irritation No information available. Respiratory or skin sensitization No information available. Germ cell mutagenicity No information available. Carcinogenicity Ethanol has been shown to be carcinogenic in long-term studies only when consumed as alcoholic beverage. The table below indicates whether each agency has listed any ingredient as a carcinogen. Chemical name ACGIH IARC NTP OSHA Ethanol 64-17-5 A3 Group 1 Known X Legend ACGIH (American Conference of Governmental Industrial Hygienists) A3 - Animal Carcinogen 1567974 - Hand Sanitizer Revision Date 28-OCT-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 8 / 12 IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to Humans NTP (National Toxicology Program) Known - Known Carcinogen OSHA (Occupational Safety and Health Administration of the US Department of Labor) X - Present Reproductive toxicity No information available. STOT - single exposure No information available. STOT - repeated exposure No information available. Aspiration hazard No information available. 12. ECOLOGICAL INFORMATION Ecotoxicity Toxic to aquatic life. Chemical name Toxicity to Algae Toxicity to Fish Toxicity to Microorganisms Daphnia Magna (Water Flea) Ethanol - 96h LC50: 12.0 - 16.0 mL/L (Oncorhynchus mykiss) 96h LC50: 13400 - 15100 mg/L (Pimephales promelas) 96h LC50: > 100 mg/L (Pimephales promelas) EC50 = 34634 mg/L 30 min EC50 = 35470 mg/L 5 min 24h EC50: = 10800 mg/L (Daphnia magna) 48h EC50: = 2 mg/L (Daphnia magna) 48h LC50: 9268 - 14221 mg/L (Daphnia magna) Glycerin - 96h LC50: 51 - 57 mL/L (Oncorhynchus mykiss) - 24h EC50: > 500 mg/L (Daphnia magna) Persistence and Degradability No information available. Bioaccumulation . Component Information Chemical name Log Pow Ethanol -0.32 Glycerin -1.76 Mobility No information available. Other adverse effects No information available. 13. DISPOSAL CONSIDERATIONS Waste treatment methods Waste from residues/unused products Should not be released into the environment. Dispose of in accordance with local regulations. Dispose of waste in accordance with environmental legislation. Contaminated packaging Empty containers pose a potential fire and explosion hazard. Do not cut, puncture of weld containers. US EPA Waste Number D001 1567974 - Hand Sanitizer Revision Date 28-OCT-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 9 / 12 California Waste Codes 311 This product contains one or more substances that are listed with the State of California as a hazardous waste. Chemical name California Hazardous Waste Ethanol 64-17-5 Toxic Ignitable 14. TRANSPORT INFORMATION DOT UN-No. UN1170 Proper Shipping Name ETHANOL Hazard Class 3 Packing Group II Description UN1170, ETHANOL, 3, II Emergency Response Guide Number 127 TDG UN-No. UN1170 Proper Shipping Name ETHANOL SOLUTION Hazard Class 3 Packing Group II Description UN1170, ETHANOL SOLUTION, 3, II MEX UN-No. UN1170 Proper Shipping Name ETHANOL IN SOLUTION Hazard Class 3 Packing Group II Description UN1170, ETHANOL IN SOLUTION, 3, II ICAO UN-No. UN1170 Proper Shipping Name ETHANOL Hazard Class 3 Packing Group II Description UN1170, ETHANOL, 3, II IATA UN-No. UN1170 Proper Shipping Name ETHANOL Hazard Class 3 Packing Group II ERG Code 3L Description UN1170, ETHANOL, 3, II IMDG/IMO UN-No. UN1170 Proper Shipping Name ETHANOL SOLUTION 1567974 - Hand Sanitizer Revision Date 28-OCT-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 10 / 12 Hazard Class 3 Packing Group II EmS-No. F-E, S-D Description UN1170, ETHANOL SOLUTION, 3, II, (20°C C.C.) RID UN-No. UN1170 Proper Shipping Name ETHANOL SOLUTION Hazard Class 3 Packing Group II Classification code F1 Description UN1170, ETHANOL SOLUTION, 3, II ADR/RID-Labels 3 ADR UN-No. 1170 Proper Shipping Name ETHANOL SOLUTION Hazard Class 3 Packing Group II Classification code F1 Tunnel restriction code (D/E) Description 1170, ETHANOL SOLUTION, 3, II, (D/E) ADN UN-No. UN1170 Proper Shipping Name ETHANOL SOLUTION Hazard Class 3 Packing Group II Classification code F1 Special Provisions 144, 601 Description UN1170, ETHANOL SOLUTION, 3, II Hazard Labels 3 Limited Quantity 1 L Ventilation VE01 15. REGULATORY INFORMATION Safety, health and environmental regulations/legislation specific for the substance or mixture International Regulations The Montreal Protocol on Substances that Deplete the Ozone Layer Not applicable The Stockholm Convention on Persistent Organic Pollutants Not applicable The Rotterdam Convention Not applicable International Inventories TSCA Contact supplier for inventory compliance status. DSL/NDSL Contact supplier for inventory compliance status. EINECS/ELINCS Contact supplier for inventory compliance status. ENCS Contact supplier for inventory compliance status. KECL Contact supplier for inventory compliance status. PICCS Contact supplier for inventory compliance status. AICS Contact supplier for inventory compliance status. 1567974 - Hand Sanitizer Revision Date 28-OCT-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 11 / 12 Legend TSCA - United States Toxic Substances Control Act Section 8(b) Inventory DSL/NDSL - Canadian Domestic Substances List/Non-Domestic Substances List EINECS/ELINCS - European Inventory of Existing Chemical Substances/European List of Notified Chemical Substances ENCS - Japan Existing and New Chemical Substances KECL - Korean Existing and Evaluated Chemical Substances PICCS - Philippines Inventory of Chemicals and Chemical Substances AICS - Australian Inventory of Chemical Substances US Federal Regulations SARA 313 Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 (SARA). This product does not contain any chemicals which are subject to the reporting requirements of the Act and Title 40 of the Code of Federal Regulations, Part 372 SARA 311/312 Hazard Categories Should this product meet EPCRA 311/312 Tier reporting criteria at 40 CFR 370, refer to Section 2 of this SDS for appropriate classifications. Under the amended regulations at 40 CFR 370, EPCRA 311/312 Tier II reporting for the 2017 calendar year will need to be consistent with updated hazard classifications. CWA (Clean Water Act) This product does not contain any substances regulated as pollutants pursuant to the Clean Water Act (40 CFR 122.21 and 40 CFR 122.42) CERCLA This material, as supplied, does not contain any substances regulated as hazardous substances under the Comprehensive Environmental Response Compensation and Liability Act (CERCLA) (40 CFR 302) or the Superfund Amendments and Reauthorization Act (SARA) (40 CFR 355). There may be specific reporting requirements at the local, regional, or state level pertaining to releases of this material US State Regulations California Proposition 65 This product contains the following Proposition 65 chemicals. Ethyl alcohol is only a considered a Proposition 65 developmental hazard when it is ingested as an alcoholic beverage. Chemical name California Proposition 65 Ethanol - 64-17-5 Carcinogen Developmental U.S. State Right-to-Know Regulations This product may contain substances regulated by state right-to-know regulations. Chemical name New Jersey Massachusetts Pennsylvania Rhode Island Illinois Ethanol 64-17-5 X X X X Glycerin 56-81-5 X X X X 16. OTHER INFORMATION NFPA Health hazards 1 Flammability 3 Instability 0 Physical and Chemical Properties - 1567974 - Hand Sanitizer Revision Date 28-OCT-2020 _____________________________________________________________________________________________ _____________________________________________________________________________________________ Page 12 / 12 HMIS Health hazards 1 Flammability 3 Physical hazards 0 Personal Protection X Prepared By Product Stewardship 23 British American Blvd. Latham, NY 12110 1-800-572-6501 Issuing Date 30-Mar-2020 Revision Date 28-Oct-2020 Revision Note No information available Disclaimer The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text End of Safety Data Sheet