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HomeMy WebLinkAboutPuranic MSDS 75%Alcohol SASDS Report No.:CANEC2002613503 Date:02 Apr 2020 Page 1 of 1 ZHEJIANG SHUNAN INDUSTRY&TRADE CO.,LTD NO.8 XINYUAN ROAD,DONGYANG CITY,ZHEJIANG PROVINCE,CHINA This report is to supersede report CANEC2002613502 SGS Job No.20683293 Sample Name :Hand Sanitizer End Uses :Hand Washing and sterilizing Composition/Ingredient of sample(as per client submission):See section 3 Composition/information on ingredients on the SDS report Job Receiving Date :11 Mar 2020 SDS Preparation Period :11 Mar 2020-17 Mar 2020 Service Requested :Safety Data Sheet (SDS)for the sample with submitted composition. Summary :As per request,the contents and formats of the SDS are prepared inaccordancewithUSRegulationsRelatingtoLabor29CFR1910.1200,andisprovidedperattached. Remark: The SDS is prepared based on the information provided by client. This report updates Transport information,Flash point. Signed for and on behalf ofSGS-CSTC Standards Technical Services Co.,Ltd.Guangzhou Branch Zm guanApproved Signatory Page 1/8SafetyDataSheet29CFR1910.1200 Version number 1Printingdate04/02/2020 Reviewed on 04/02/2020 49.4.20 ·Product identifier ·Trade name:Hand Sanitizer ·Recommended use of the chemical and restrictions on use:·Application of the substance /the preparation:Hand Washing and sterilizing ·Details of the supplier of the safety data sheet·Manufacturer/Supplier:ZHEJIANG SHUNAN INDUSTRY&TRADE CO.,LTD ·Full address:NO.8 XINYUAN ROAD,DONGYANG CITY,ZHEJIANG PROVINCE,CHINA·Phone number:0579-89903102·Email:sales4@yiwushunan.com ·Other U.S.contact point:Not available ·Further information obtainable from:ZHEJIANG SHUNAN INDUSTRY&TRADE CO.,LTD ·Emergency telephone number:Poison CenterTel:+1 800 222 1222 ·Reference Number:CANEC2002613503,20683293 1 Identification 2 Hazard(s)identification ·Classification of the substance or mixtureClassificationaccordingtoOSHAHazardCommunication Standard (29 CFR 1910.1200) GHS02 Flame Flam.Liq.2 H225 Highly flammable liquid and vapor. ·Information concerning particular hazards for human and environment:The product has to be labeled due to the calculation procedure of OSHA Hazard Communication Standard(29 CFR 1910.1200). ·Classification system:The classification is according to the latest edition of OSHA Hazard Communication Standard (29 CFR 1910.1200),and extended by company and literature data. ·Label elements·Labelling according to OSHA Hazard Communication Standard (29 CFR 1910.1200)·Hazard pictograms GHS02 ·Signal word Danger·Hazard statementsH225Highlyflammable liquid and vapor.·Precautionary statementsP210Keepaway from heat/sparks/open flames/hot surfaces.-No smoking.P233 Keep container tightly closed.P240 Ground/bond container and receiving equipment.P241 Use explosion-proof electrical/ventilating/lighting/equipment.P242 Use only non-sparking tools.P243 Take precautionary measures against static discharge. P280 Wear protective gloves/protective clothing/eye protection/face protection.P303+P361+P353 If on skin (or hair):Take off immediately all contaminated clothing.Rinse skin with water/shower.(Contd.on page 2) USA Page 2/8SafetyDataSheet29CFR1910.1200 Version number 1Printingdate04/02/2020 Reviewed on 04/02/2020 Trade name:Sanitizer 49.4.20 ·Chemical characterization:Mixtures·Description:Mixture of the substances listed below with nonhazardous additions. For the wording of the listed hazard statements refer to Section 16. ·Description of first aid measures·General description:Immediately remove any clothing soiled by the product.·After inhalation:Supply fresh air;consult doctor in case of complaints.·After skin contact:Immediately rinse with water. ·After eye contact:Rinse opened eye for several minutes under running water.·After swallowing:If symptoms persist consult doctor. ·Most important symptoms and effects,both acute and delayed No further relevant information available. ·Indication of any immediate medical attention and special treatment neededNofurtherrelevantinformationavailable. ·Suitable extinguishing agents: CO₂,extinguishing powder or water spray.Fight larger fires with water spray or alcohol resistant foam.·For safety reasons unsuitable extinguishing agents:Water with full jet ·Special hazards arising from the substance or mixture:No further relevant information available. ·Special protective equipment and precautions for firefighters·Protective equipment:No special measures required. USA ·Hazards not otherwise classified (HNOC)No further relevant information available. In case of fire:Use for extinction:CO2,powder or water spray.Store in a well-ventilated place.Keep cool.Dispose of contents/container in accordance with local/regional/national/internationalregulations. P370+P378P403+P235P501 (Contd.of page1) 3 Composition/information on ingredients ·Composition: 64-17-5 ethanol Flam.Liq.2,H225 75% 7732-18-5 Water 24.8972% 54182-57-9 Carbomer 0.028% 85507-69-3 Aloe Barbadensis Leaf Juice 0.012% 1406-18-4 Tocopheryl Acetate (Vitamin E)0.015% 56-81-5 Glycerin 0.0058% 57-55-6 Propylene Glycol 0.012% 102-71-6 Triethanolamine 0.03% 4 First-aid measures 5 Fire-fighting measures (Contd.on page 3) Page 3/8SafetyDataSheet29CFR1910.1200 Version number 1Printingdate04/02/2020 Reviewed on 04/02/2020 Trade name:Sanitizer 49.4.20 ·Personal precautions,protective equipment and emergency procedures:Wear protective equipment.Keep unprotected persons away. ·Environmental precautions:Do not allow to enter sewers/surface or ground water. ·Methods and material for containment and cleaning up:Absorb with liquid-binding material (sand,diatomite,acid binders,universal binders,sawdust).Dispose contaminated material as waste according to section 13. Ensure adequate ventilation. ·Precautions for safe handling:For the general occupational hygienic measures refer to Section 8.·Information about protection against explosions and fires: Keep ignition sources away -Do not smoke.Protect against electrostatic charges. ·Conditions for safe storage,including any incompatibilities·Requirements to be met by storerooms and receptacles:Store in a cool location.·Information about storage in one common storage facility:Not required.·Further information about storage conditions:Keep receptacle tightly sealed. Store in cool,dry conditions in well sealed receptacles. ·Regulatory informationPEL(USA):Guide to Occupational Exposure Values (OSHA PELs)REL (USA):Guide to Occupational Exposure Values (NIOSH RELs)TLV (USA):Guide to Occupational Exposure Values (ACGIH) ·Additional information:The lists that were valid during the creation were used as basis. ·Based on the composition shown in Section 3,the following measures are suggested for occupationalsafetymeasure.·Appropriate engineering controls:Immediately remove all soiled and contaminated clothing.Wash hands before breaks and at the end of work.(Contd.on page 4) USA (Contd.of page 2) 6 Accidental release measures 7 Handling and storage 8 Exposure controls/personal protection ·Components with limit values that require monitoring at the workplace: 64-17-5 ethanol (75%) PEL (USA) REL (USA) TLV (USA) Long-term value:1900 mg/m³,1000 ppm Long-term value:1900 mg/m³,1000 ppm Short-term value:1880 mg/m³,1000 ppm 56-81-5 Glycerol (0.0045%) PEL (USA) TLV (USA) Long-term value:15*5**mg/m³ mist;*total dust **respirable fraction TLV withdrawn-insufficient data human occup.exp. 9004-34-6 Cellulose (0.003%) PEL (USA) REL (USA) TLV (USA) Long-term value:15*5**mg/m³ *total dust **respirable fraction Long-term value:10*5**mg/m³ *total dust **respirable fraction Long-term value:10 mg/m³ Page 4/8SafetyDataSheet29CFR1910.1200 Version number 1Printingdate04/02/2020 Reviewed on 04/02/2020 Trade name:Sanitizer (Contd.ofpage 3) 49.4.20 (Contd.on page 5) USA See Section 7 for information about design of technical facilities. ·Personal protective equipment: ·Breathing equipment:Not required.·Protection of hands: Protective gloves The glove material has to be impermeable and resistant to the product/the substance/the preparation.Due to missing tests no recommendation to the glove material can be given for the product/the preparation/ the chemical mixture.Selection of the glove material on consideration of the penetration times,rates of diffusion and the degradation·Material of gloves The selection of the suitable gloves does not only depend on the material,but also on further marks of qualityandvariesfrommanufacturertomanufacturer.As the product is a preparation of several substances,the resistance of the glove material can not be calculated in advance and has therefore to be checked prior to theapplication. ·Penetration time of glove material:The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.·Eye protection: Tightly sealed goggles 9 Physical and chemical properties ·General Information·Appearance:Form:LiquidColor:Transparent ·Odor:Alcohol taste·Odor threshold:Not available ·pH-value:Not available ·Change in conditionMeltingpoint/Freezing point:Not availableInitialboilingpointandboilingrange:Not available ·Flash point:22.5 °C (72.5 °F) ·Flammability (solid,gaseous):Not available ·Auto-Ignition temperature:Not available ·Decomposition temperature:Not available ·Explosion limits:Lower:Not available Upper:Not available ·Vapor pressure:Not available ·Density:Not available ·Relative density:Not available·Vapor density:Not available Page 5/8SafetyDataSheet29CFR1910.1200 Version number 1Printingdate04/02/2020 Reviewed on 04/02/2020 Trade name:Sanitizer (Contd.ofpage 4) 49.4.20 ·Reactivity:Data not available ·Chemical stability:Data not available ·Possibility of hazardous reactions:No dangerous reactions known. ·Conditions to avoid:No further relevant information available. ·Incompatible materials:No further relevant information available. ·Hazardous decomposition products:No dangerous decomposition products known. ·Acute toxicity: ·Skin corrosion/irritation:Irritating effect possible. ·Serious eye damage/irritation:Irritating effect possible.·Respiratory or skin sensitization:Sensitization possible. ·Additional toxicological information: ·Carcinogenic categories USA ·Evaporation rate:Not available ·Solubility in /Miscibility withWater:Not available ·Partition coefficient (n-octanol/water):Not available ·Viscosity:Dynamic: Kinematic: Not available Not available ·Other information No further relevant information available. 10 Stability and reactivity 11 Toxicological information ·LD/LC50 values that are relevant for classification: 64-17-5 ethanol Oral Inhalative LD50 LC50/4 h 7,060 mg/kg (rat) 20,000 mg/l (rat) 56-81-5 Glycerol Oral LD50 12,600 mg/kg (rat) 9004-34-6 Cellulose Oral LD50 >5,000 mg/kg (rat) ·IARC (International Agency for Research on Cancer) None of the ingredients is listed. ·NTP (National Toxicology Program) None of the ingredients is listed. ·OSHA-Ca (Occupational Safety &Health Administration) None of the ingredients is listed. (Contd.on page 6) Page 6/8SafetyDataSheet29CFR1910.1200 Version number 1Printingdate04/02/2020 Reviewed on 04/02/2020 Trade name:Sanitizer (Contd.ofpage 5) 49.4.20 ·Toxicity·Aquatic toxicity:No further relevant information available. ·Persistence and degradability:No further relevant information available. ·Bioaccumulative potential:No further relevant information available. ·Mobility in soil:No further relevant information available. ·Other adverse effects No further relevant information available. ·Waste treatment methods·Recommendation: Must not be disposed of together with household garbage.Do not allow product to reach sewage system. ·Uncleaned packagings:·Recommendation:Disposal must be made according to official regulations. (Contd.on page 7) USA 12 Ecological information 13 Disposal considerations 14 Transport information ·UN-Number·DOT,IMDG,IATA UN1170 ·UN proper shipping name·DOT Ethanol mixture·IMDG ETHANOL (ETHYL ALCOHOL)mixture·IATA ETHANOL mixture ·Transport hazard class(es) ·DOT ·Class 3 Flammable liquids·Label 3 ·IMDG,IATA ·Class·Label 3 Flammable liquids3 ·Packing group·DOT,IMDG,IATA II ·Environmental hazards:Not applicable ·Special precautions for user·EMS Number:·Stowage Category Warning:Flammable liquidsF-E,S-DA Page 7/8SafetyDataSheet29CFR1910.1200 Version number 1Printingdate04/02/2020 Reviewed on 04/02/2020 Trade name:Sanitizer (Contd.ofpage 6) 49.4.20 ·Safety,health and environmental regulations/legislation specific for the substance or mixture ·Sara ·Proposition 65 (Contd.on page 8) USA ·Transport in bulk according to Annex II ofMARPOL73/78 and the IBC Code Not applicable ·Transport/Additional information: ·DOT ·Quantity limitations On passenger aircraft/rail:5 LOncargoaircraftonly:60 L ·IMDG·Limited quantities (LQ)1L·Excepted quantities (EQ)Code:E2 Maximum net quantity per inner packaging:30 mlMaximumnetquantityperouterpackaging:500 ml ·UN "Model Regulation":UN 1170 ETHANOL (ETHYL ALCOHOL)MIXTURE,3,II 15 Regulatory information ·Section 355 (extremely hazardous substances): None of the ingredients is listed. ·Section 313 (Specific toxic chemical listings): None of the ingredients is listed. ·TSCA (Toxic Substances Control Act): 64-17-5 ethanol ACTIVE 63-42-3 Lactose ACTIVE 1406-18-4 Vitamin E ACTIVE 97-59-6 allantoin ACTIVE 56-81-5 Glycerol ACTIVE 11138-66-2 Xanthan gum ACTIVE 9004-34-6 Cellulose ACTIVE 7732-18-5 Water ACTIVE ·Chemicals known to cause cancer: None of the ingredients is listed. ·Chemicals known to cause reproductive toxicity for females: None of the ingredients is listed. ·Chemicals known to cause reproductive toxicity for males: None of the ingredients is listed. ·Chemicals known to cause developmental toxicity: 64-17-5 ethanol ·New Jersey Right-to-Know List: 64-17-5 ethanol 56-81-5 Glycerol 9004-34-6 Cellulose ·New Jersey Special Hazardous Substance List: 64-17-5 ethanol CA,MU,TE,F3 Page 8/8SafetyDataSheet29CFR1910.1200 Version number 1Printingdate04/02/2020 Reviewed on 04/02/2020 Trade name:Sanitizer (Contd.ofpage 7) 49.4.20 ·Cancerogenity categories ·Pennsylvania Right-to-Know List: 64-17-5 ethanol 56-81-5 Glycerol 9004-34-6 Cellulose ·Pennsylvania Special Hazardous Substance List: None of the ingredients is listed. ·EPA (Environmental Protection Agency) None of the ingredients is listed. ·TLV (Threshold Limit Value established by ACGIH) 64-17-5 ethanol A3 ·NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients is listed. 16 Other information ·Relevant hazard statementsH225Highlyflammableliquid and vapor. ·***************************************************************************************The contents and format of this SDS are in accordance with 29 CFR 1910.1200. DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable.However,theinformationisprovidedwithoutanywarranty,express or implied,regarding its correctness.The conditions or methods of handling,storage,use or disposal of the product are beyond our control and may be beyondourknowledge.For this and other reasons,we do not assume responsibility and expressly disclaim liability for loss,damage or expense arising out of or in any way connected with the handling,storage,use ordisposaloftheproduct.This SDS was prepared and is to be used only for this product.If the product is used as a component in another product,this SDS information may not be applicable. ·Date of preparation /last revision 04/02/2020 /- ·Abbreviations and acronyms: IMDG:International Maritime Code for Dangerous GoodsDOT:US Department of TransportationIATA:International Air Transport AssociationACGIH:American Conference of Governmental Industrial HygienistsEINECS:European Inventory of Existing Commercial Chemical SubstancesELINCS:European List of Notified Chemical SubstancesCAS:Chemical Abstracts Service (division of the American Chemical Society)LC50:Lethal concentration,50 percentLD50:Lethal dose,50 percentNIOSH:National Institute for Occupational SafetyOSHA:Occupational Safety &HealthFlam.Liq.2:Flammable liquids –Category 2·*************************************************************************************** End of document USA